• Title/Summary/Keyword: Salt separation

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Preparation of Polyketone Micro/nanofiber Membrane based on Electrospinning Condition and Its Application in Oil-Water Separation (전기방사법의 제조 조건에 따른 폴리케톤 마이크로/나노섬유 분리막 제조 및 유수 분리 적용)

  • Hou, Jian;Yun, Jaehan;Park, Chanju;Choi, Jinwon;Jeon, Sungil;Lee, Chang Hyun;Byun, Hongsik
    • Membrane Journal
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    • v.31 no.6
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    • pp.426-433
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    • 2021
  • In this study, a novel material polyketone (PK) was chosen and PK micro/nano fiber membranes were fabricated via electrospinning method under various conditions. After that, the potential application in oil-water separation was thoroughly investigated. The surface of microfiber membrane formed under high humidity especially became much rougher than that formed under low humidity. When salt was added to the spinning solution, the diameter of fibers was reduced up to 90% and the nanofiber membranes could be formed. The oil/water emulsions were prepared and separated under gravity condition using the manufactured rPK-LNC and PK-H membranes. The separation characteristics was evaluated by measuring total organic carbon (TOC) and turbidity. Meanwhile, the changes in the physical properties of fiber membranes under various conditions and with or without salt, as well as the changes in oil water separation characteristics were also studied.

Production of Cyclodextrin Homologues Using Aqueous Two-Phase System

  • Chang, Woo-Jin;Koo, Yoon-Mo;Park, Sung-Sik
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.2 no.2
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    • pp.97-100
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    • 1997
  • Cyclodxtrin homologues(CDs), produced by cyclodextrin glycosyltransferase(CGTase), were simultaneously partitioned in aqueous two-phase system(ATPS). Partition coefficients of CDs were measured in PEG/dextran systems. Phosphate, citrate, sulfate were tested as salt. ATPS of PEG/salt and PEG/dextran had the partition coefficients of the CDs, larger than unity. However, PEG/dextran system was observed better than PEG/salt as CGTase activity decreased sharply with salt concentration. Enzymatic rection occurred mainly in PEG-rich bottom phase because of the low partition coefficient of CGTase. The resulting CDs transferred to the PEG-rich top phase, obeying the diffusional partition. In the ATPS of 7% PEG(M.W.40, 000), 7mg/ml of CDs were obtained in top phase at 4.5 hours.

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Separation of Neodymium from NdEeB Permanent Magnetic Scrap (NdFeB계 영구자석 스크랩으로부터 네오디뮴의 분리회수)

  • Yoon Ho-Sung;Kim Chul-Joo;Lee Jin-Yeung;Kim Sung-Don;Kim Joon-Soo;Lee Jae-Chun
    • Resources Recycling
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    • v.12 no.6
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    • pp.57-63
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    • 2003
  • In this study, the separation of neodymium was investigated from NdFeB permanent magnet scrap. Decomposition and leach-ing process of NdFeB permanent magnet scrap by oxidation roasting and sulfuric arid leaching were examined. Neodymium could be separated from iron by double salt precipitation using sodium sulfate. The optimum conditions established for decom-position and leaching are as follows: oxidation roasting temperature is $500^{\circ}C$ for sintered scrap and $700^{\circ}C$ for bonded scrap, concentration of sulfuric acid in leaching solution is 2.0 M, leaching temperature and time is $50^{\circ}C$ and 2 hrs, and pulp density is 15%. The leaching yield of neodymium and iron was 99.4% and 95.7% respectively. The optimum condition for separation of neodymium by double-salt precipitation was 2 equivalents of sodium sulfate and $50^{\circ}C$ The yield of neodymium was above 99.9%.

Separation of Glutathione by Ion Exchange Chromatography (이온교환 크로마토그래픽을 이용한 Glutathione 분리)

  • 김정훈;손영종;구윤모
    • KSBB Journal
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    • v.13 no.1
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    • pp.77-82
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    • 1998
  • Glutathione(L-$\gamma$ -glutamyl-L-cysteinylglycine, GSH) produced by microbial enzymes was separated by a liquid chromatography. In order to select a resin which would bind GSH efficiently, a batch adsorption experiment was carried out with GSH solution and various resins at pH 8.0 GSH bound to Q-sepharose and QAE-sephadex among anion exchange resins, but the latter was found not to be suitable because of the reduction of resin volume at high salt concentration. Preliminary experiments using a standard solution were carried out to separate GSH. GSH and $\gamma$ -glutamylcysteine were separated from the other constituents by applying step gradient of salt(NaCl) concentration. GSH was successfully separated from $\gamma$ -glutamylcysteine by applying Tris buffer containing 35mM NaCl. Chromatographic separation behaviors for the enzymatic product was similar to that for the standard solution. Separation yields of GSH from the standard solution and enzymatic product solution were 72.6% and 84.4%, respectively.

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Effect of Rare Earth Elements on Uranium Electrodeposition in LiCl-KCl Eutectic Salt (LiCl-KCl 공융염에서 우라늄 전착거동에 대한 희토류 원소들의 영향)

  • Park, Sungbin;Kang, Young-Ho;Hwang, Sung Chan;Lee, Hansoo;Paek, Seungwoo;Ahn, Do-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.4
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    • pp.263-269
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    • 2015
  • It is necessary to investigate the electrodeposition behavior of uranium and other elements on the cathode in the electrorefining process to recover the uranium selectively from the reduced metals of the electrolytic reduction process since transuranic elements and rare earth elements is dissolved in the LiCl-KCl eutectic salt. Study on separation factors of U, Ce, Y and Nd based on U and Ce was performed to investigate the deposition behavior of the cathode with respect to the concentration of rare earth elements in LiCl-KCl eutectic salt. After electrorefining with constant current mode by using Ce metal as a sacrifice anode, the contents of U, Ce, Y and Nd in the salt phase and the deposit phase of the cathode were analyzed, and separation factors of the elements were obtained from the analyses. Securing conditions of pure uranium recovery in the elctrorefining process was investigated by considering the separation factors with respect to $UCl_3$ and $CeCl_3/UCl_3$ ratio.

Nonlinear optical behavior of binary mixture protein and water near the phase separation temperature (상분리 온도 근방에서 섞임체 단백질-물의 비선형 광학적 특성)

  • 조창호;김태균;서영석
    • Korean Journal of Optics and Photonics
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    • v.8 no.6
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    • pp.461-465
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    • 1997
  • The 3rd order nonlinear optical susceptibility was measured through the self-induced ellipse rotation. The phase separation temperature increases with the increase of salt and it decreases with the increase of glycerol.

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Application of response surface methodology in pes/speek blend NF membrane for dyeing solution treatment

  • Lau, W.J.;Ismail, A.F.
    • Membrane and Water Treatment
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    • v.1 no.1
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    • pp.49-60
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    • 2010
  • In this study, response surface methodology (RSM) was performed in NF membrane process to evaluate the separation efficiency of membrane in the removal of salt and reactive dye by varying different variables such as pressure, temperature, pH, dye concentration and salt concentration. The significant level of both the main effects and the interaction were observed by analysis of variance (ANOVA) approach. Based on the statistical analysis, the results have provided valuable information on the relationship between these variables and the performances of membrane. The rejection of salt was found to be greatly influenced by pressure, pH and salt concentration whereas the dye rejection was relatively constant in between 96.22 and 99.43% regardless of the changes in the variables. The water flux on the other hand was found to be affected by the pressure and salt concentration. It is also found that the model predictions were in good agreement with the experimental data, indicating the validity of these models in predicting membrane performances prior to the real filtration process.

Post Process Associated with the Electrochemical Reduction Process - Smelting of a Metal Product and Solidification of a Molten Salt (전해환원공정 관련 후처리공정 - 금속전환체 Smelting 및 용융염 고화)

  • 허진목;정명수;이원경;조수행;서중석;박성원
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.278-284
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    • 2004
  • The processes for the smelting of a metal product and the solidification of a molten salt were developed respectively to treat the products from the electrochemical reduction process. The method for the separation of a metal product in a magnesia container from the residual. salt and consequent smelting of it to a metal ingot by the multi step heating in vacuum was proposed. The new concept using a dual vessel and a salt valve was also suggested for the solidification of a molten salt into a regular size and shape which is suitable for the transport and measurement. The results obtained in the study will be applied to the design of the hot cell demonstration system of the Advanced Spent Fuel Conditioning Process of KAERI.

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