• Journal of the Korean institute of surface engineering
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• v.55 no.6
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• pp.460-468
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• 2022

Due to its high electrical conductivity, low contact resistance, good weldability and high corrosion resi-stance, gold is widely used in electronic components such as connectors and printed circuit boards (PCB). Gold ion salts currently used in gold plating are largely cyan-based salts and non-cyanic salts. The cya-nide bath can be used for both high and low hardness, but the non-cyanide bath can be used for low hardness plating. Potassium gold cyanide (KAu(CN)₂) as a cyanide type and sodium gold sulfite (Na₃[Au(SO)₃]₂) salt as a non-cyanide type are most widely used. Although the cyan bath has excellent performance in plating, potassium gold cyanide (KAu(CN)₂) used in the cyan bath is classified as a poison and a toxic substance and has strong toxicity, which tends to damage the positive photoresist film and make it difficult to form a straight side-wall. There is a need to supplement this. Therefore, it is intended to supplement this with an eco-friendly process using sodium sulfite sodium salt that does not contain cyan. Therefore, the main goal is to form a gold plating layer with a controllable hardness using a non-cyanide gold plating solution. In this study, the composition of a non-cyanide gold plating solution that maintains hardness even after annealing is generated through gold-palladium alloying by adding thallium, a crystal regulator among electrolysis factors affecting the structure and hardness, and changes in plating layer structure and crystallinity before and after annealing the correlation with the hardness.

• Corrosion Science and Technology
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• v.17 no.2
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• pp.74-80
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• 2018

The electronic industries require environmentally-friendly and highly functional materials to enhance the quality of human life. Home appliances require insect repellent steels that work to protect household microwave ovens from incurring damage by insects such as fire ants and cockroaches in tropical regions. Thus, POSCO has developed new types of functional steels, coated with an array of organic-inorganic hybrid composites on the steel surface, to cover panels in microwave ovens and refrigerators. The composite solution uses a fine dispersion of hybrid solution with polymeric resin, inorganic and a pyrethroid additive in aqueous media. The hybrid composite solution coats the steel surface, by using a roll coater and is cured using an induction curing furnace on both the continuous galvanizing line and the electro-galvanizing line. The new steels were evaluated for quality performances, salt spray test for corrosion resistance and biological performance for both insect repellent and antimicrobial activity. The new steels with organic-inorganic composite coating exhibit extraordinarily biological functionalities, for both insect repellent and antimicrobial activities for short and long term tests. The composite-coating solution and experimental results are discussed and suggest that the molecular level dispersion of insecticide on the coating layer is key to biological functional performances.

• Proceedings of the KSR Conference
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• 2005.11a
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• pp.1184-1189
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• 2005

Durability of concrete has been currently issued in the engineering societies and a large number of studies on the concrete corrosion in salty environment have been performed. The reinforcement corrosion, which is the primary reason of deterioration of the concrete structure exposed to chloride environment. is caused by the chloride ions infiltration owing to underground water seeping into the concrete. In this study. the endurance periods using the diffusion equation of the concrete specification have been evaluated on the concrete structures with different addictives for the brand new R/C subway structure exposed to seashore underground water. Furthermore. the guidance for proper use of the addictives and the reasonable thickness of concrete cover are derived for concrete mixing. From the result of the evaluation corresponding to salt damage for Inchon subway line I, the endurance periods of the ordinary Portlandcement concretes are represented as $42\~75$ years and fail to achieve the objective period of 100 years. However, the lower water-cement ratio expands the endurance periods and the blast furnace slag concrete with small quantity of the silica fume, which shows the best performance of corrosion resistance in this study, represents more than 170 years of the endurance period. Moreover, the case of use of blast furnace slag and fly ash together shows the endurance period of $134\~171$ years and it means that the result very satisfies the objective endurance period.

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.3
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• pp.171-177
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• 2010

As concrete structures are exposed to chemical substances, damaged from salt, or progressed to the neutralization, the surface damage of the structures is generated timely fashion, resulting shortened service life. Especially, the sulfate erosion causes rapid surface defects, and the steel skeleton becomes corroded due to the water infiltration, generating stability deterioration of the concrete structure. In this study, the physical characteristics of the acid-resistant mortar with aluminosilicates was investigated in order to resolve problems of the acid resistance, one of the most serious problems of the cement type repair material. As the result of the experiment, the test specimen turned to exhibit almost equivalent physical characteristics with those of concrete sectional repair materials in terms of compressive and bending strengths. As both the cement sectional repair material and the test specimen were immerged in sulfuric acid solution to examine weight changes, the test specimens exhibited only 4% loss of their weights while the cement sectional repair materials reached at the level of 80% or above, proving the excellence acid resistant characteristics of the test specimens. Consequently, the physical characteristics of acid resistant mortar with aluminosilicates were revealed to be superior than those of concrete sectional repair materials. It can be utilized as a sectional repair material where the acidic erosion is anticipated.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.49 no.4
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• pp.349-354
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• 2023

Sunscreen is a product that protects against ultraviolet rays by blocking and scattering ultraviolet rays, and has now become a daily necessity beyond cosmetics. Applying sunscreen is a common and easy way to prevent skin damage caused by ultraviolet rays. Due to its significance, the evaluation of sunscreen has evolved since its regulation by the FDA in 1978, progressing to standardized methods established by ISO. Additionally, to assess the loss of sunscreen due to activities such as water exposure or sweating, the Ministry of Food and Drug Safety in Korea and ISO have established protocols for evaluating the water-resistant sun protection factor (SPF). However, existing evaluations of water resistance have been mainly confined to test methods involving plain water, and methods accounting for the impact of seawater during activities like beach leisure, sports, and recreation are yet to be established. Based on the existing guidelines for testing the water-resistant UV protection index, this study compared the water-resistant UV protection index in water, artificial seawater (salt water) and natural seawater (sea water) to evaluate the UV protection index in real-world situations such as marine leisure, sports, and leisure activities. Through these results, we were able to compare the differences between water resistance sun protection index tests in ordinary water, artificial seawater, and natural seawater, and suggest a method for water resistance sun protection index tests using natural seawater.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.5
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• pp.1-8
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• 2014

Structures requiring chemical resistance are usually coated with surface protecting agents, but the cost for maintenance and re-construction is incurred due to the low durability. Therefore, in this study, sulfur was polymerized and the performance was examined so that it could be used as the concrete surface protecting agents for structures requiring chemical resistance. The evaluation results indicated that for the spray of the sulfur polymer surface coating agents, the application of the gravity type was appropriate; and for the number of coating times, about 3 cycle spray gave the best results. For the surface condition of the concrete to be coated with the surface protecting agents, outstanding quality was obtained above room temperature ($20{\sim}30^{\circ}C$), and the bond strength increased as the temperature increased. The evaluation results of the strength characteristics depending on the filler content of the surface protecting agents indicated that about 20~40% filler mixing contributed to the strength improvement as it reduced the shrinkage of the sulfur polymer. Also, the mixing of silica showed larger increase in the bond strength than the mixing of fly ash, and the most outstanding bond strength characteristics could be obtained by the mixing of both silica and fly ash. In the case of the chemical resistance, the strength reduction was minimized and outstanding chemical resistance was obtained when the fly ash and silica were substituted by 20%, respectively. The performance evaluation of the chloride ion penetration indicated that for the specimens coated with the sulfur polymer surface protecting agents, the chloride ion penetration resistance increased by 29~48% compared to the specimen without the coating of the surface protecting agent. The examination of the coating condition of the surface protecting agents, compressive strength, bond strength, chemical resistance, and salt damage resistance indicated that in the range of this study, the optimal level was when the silica and fly ash were substituted by 20%, respectively, as the filler for the sulfur polymer.

• Journal of the Korea Concrete Institute
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• v.18 no.3 s.93
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• pp.371-378
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• 2006

Recently sewage facilities mainly consisted of concrete structures are being deteriorated seriously by biodeterioration originated from sulfur-oxidizing bacteria. In this study, to prevent biochemical corrosion of the sewer concrete, antibiotics which prevent growth of sulfur-oxidizing bacteria were developed and antimicrobial performance of it was investigated. After that, to consider applicability of antibiotics to concrete, physical properties of concrete covered with antibiotics were investigated. As a results of the study, it was proved that the antimicrobial performance of antibiotics was available. Also compressive strength and bond strength of concrete didn't closely connected with antibiotics, and resistance to abrasion, water absorption, air permeability, carbonation, salt damage and chemical attack of concrete was improved remarkably by covering with it.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.565-568
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• 2008

Domestic area of most be happened chloride deicer damage. Because daily mean temperature is below 0$^{\circ}C$ from the area of domestic most. Concrete durability influence Air Content. Presently, We used to AE(air-entraining agent) for increase freeze-thaw durability. So, on concrete Air Spacing ratio used $200{\mu}m{\sim}230{\mu}m$ in Canada and under $250{\mu}m$ in Japan institution. Use of Air content has been and will continue to be a major part of concrete durability and scaling. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. The prepared optimum mix concrete in this study show that freeze-thaw and scaling resistance of Non-AE(air content 1.5%) and AE (air content 4.5%, 7.2%). Solution concentrations of deicing agent were good result, and the pore system and change of hydration products is not difference comparing before freeze-thaw test.

• Proceedings of the KIEE Conference
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• 2002.11a
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• pp.102-105
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• 2002

ADSS(All Dielectirc Self-Supporting) cable installed under high voltage power cable line suffers a variety of environmental influence, rain, wind, snow fall, chemical pollution, salt fog and electrical stress. Its lifetime is required to be at least 20 years with this harsh weathering condition. The electrical stress under high voltage power line gives rise to dry band arcing and tracking, the severest damage, on the outer sheath of cable. Finally tracking might penetrate sheath and cause the break-down of ADSS cable. Tracking resistant sheath material, therefore, should be used to protect the core of ADSS from dry band arcing and to be sure long lifetime. In this work, we discuss various commercial tracking resistant material to investigate the way of track resistance and compare their mechanical, electrical, weathering and tracking properties through serial experiments. We found track resistant material is categorized into two main type : polyethylene with metal hydroxide and polyethylene with reduced carbon black. The Liquid contaminant, Inclined plane Tracking and Erosion test says the time to track of tracking resistant material with metal hydroxide has a little longer time to track in the high applied voltage than that with carbon black, but mechanical and weathering properties were inferior to.

• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.4
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• pp.177-186
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• 2005

The latest concrete structure has showed that the deterioration of durability has been increased by the damage from salt, carbonization, freezing & thawing and the others. Therefore, the measures for the concrete which has deteriorated durability have been taken. Among them, it has been often used that surface treatment which cuts off the deterioration factors of durability by protecting the surface of concrete. However, troubles such as fracture and rupture in the repair layer have been reported as time goes by due to the difference between the organic repair material like epoxy and concrete properties. Researchers have been developing the repair material which can cut off the deterioration factors of durability such as $CO_2$ gas, chloride ion and water by making the formation of concrete elaborate through the reaction with calcium ion when the surface improving agent is coated on the concrete. The main ingredient of that is inorganic substance which is the same as the concrete property. This study was evaluated the surface improving agent for permeability, watertightness, air-permeability, chemical resistance and elution resistance. As a result, it has been reported that the surface improving agent improves watertightness and air-permeability by penetration more than 10mm within concrete. Therefore, it is concluded that the surface improving agent developed in this research prevents deterioration of concrete durability when it is coated on the concrete structure.