• 제목/요약/키워드: Salt bridge

검색결과 56건 처리시간 0.022초

남해안 해상 콘크리트 교량의 표면염화물이온농도 및 내구성 평가 (The Estimation of Surface Chloride Content and Durability of the Marine Concrete Bridges in South Coast)

  • 정대진;최익창
    • 해양환경안전학회지
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    • 제20권6호
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    • pp.730-737
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    • 2014
  • 본 연구에서는 남해안에 건설된 사용기간이 5~34년의 해상 콘크리트 교량의 염화물이온농도에 대한 실측데이터로부터 표면염화물이온농도를 추정하고, 기존에 제시된 시방서와 타 연구결과에서 제시한 값들의 타당성을 평가하였다. 그리고 해상 콘크리트 교량의 염해방지도장의 유무, 염화물이온농도, 탄산화 깊이 및 콘크리트 압축강도의 상관관계를 도출하여 상호 작용을 평가하였다. 연구결과에 의하면, 표면염화물이온농도는 간만대에서 KCI 2009, 물보라지역과 해상대기중에서 Cheong et al.(2005)의 제안한 값이 타당한 것으로 판단된다. 또한, 해상 콘크리트 교량의 염해방지도장은 염화물이온의 침투, 탄산화 깊이 및 압축강도 저하 대한 방지효과가 있음을 알 수 있었다. 콘크리트의 압축 강도는 탄산화 깊이와 염화물이온농도의 증가에 따라 감소하였다.

희생양극법을 이용한 레일부식 저감 방안에 관한 연구 (A Study on Mitigation of Rail Corrosion using Sacrificial Anode Cathodic Protection Method)

  • 최정열;김준형;이규용;김영기;박종윤;송봉환;설진웅
    • 한국안전학회지
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    • 제32권6호
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    • pp.54-60
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    • 2017
  • A railway rail will be corroded by the repetitive sea wind and fog in the splash and tidal zone such as Youngjong grand bridge. And these rusts of rail could be increased by increasing service period, and it frequently occurred the safety accidents or disorders in electrical problem. In this study, the sacrificial anode cathodic protection method was proposed as a measures for reducing the corrosion of the railway rails in the oceanic climate conditions. As the results of immersion test using the salt water during four months, the sacrificial anode cathodic protection method using the aluminum anode(Al-anode) was evaluated that a distinct effect on corrosion reduction in the rails. Therefore the sacrificial anode cathodic protection method was experimentally proven that a disorders in aspects electric and signal of railway operation condition such as direct fixation track system in Youngjong grand bridge could be prevented by reducing rust falling from the rail. In addition, the installation conditions of the anodes directly affect the transmission range of corrosion potential, the sectional loss of anode, and the corrosion reduction effect. Therefore, to expect the corrosion reduction effect of rails under the oceanic climate conditions for railway track, it was important to adopted the appropriate spacing of anode installation by considering the actual field conditions.

관교의치용 Au-Ag-Cu-Pt-Zn 합금의 시효경화성과 관련된 상변태와 입계석출 (Phase transformation and grain boundary precipitation related to the age-hardening of an Au-Ag-Cu-Pt-Zn alloy for crown and bridge fabrication)

  • 조미향
    • 대한치과기공학회지
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    • 제34권4호
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    • pp.345-352
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    • 2012
  • Purpose: The age-hardening mechanism of an Au-Ag-Cu-Pt-Zn alloy for crown and bridge fabrication was investigated by means of hardness test, X-ray diffraction study and field emission scanning electron microscopic observation. Methods: Before hardness testing, the specimens were solution treated and then were rapidly quenched into ice brine, and were subsequently aged isothermally at $400-450^{\circ}C$ for various periods of time in a molten salt bath and then quenched into ice brain. Hardness measurements were made using a Vickers microhardness tester. The specimens were examined at 15 kV using a field emission scanning electron microscope. Results: By the isothermal aging of the solution-treated specimen at $450^{\circ}C$, the hardness increased rapidly in the early stage of aging process and reached a maximum hardness value. After that, the hardness decreased slowly with prolonged aging. However, the relatively high hardness value was obtained even with 20,000 min aging. By aging the solution-treated specimen, the f.c.c. Au-Ag-rich ${\alpha}_0$ phase was transformed into the Au-Ag-rich ${\alpha}_1$ phase and the AuCu I ordered phase. Conclusion: The hardness increase in the early stage of aging process was attributed to the formation of lattice strains by the precipitation of the Cu-rich phase and then subsequent ordering into the AuCu I-type phase. The decrease in hardness in the later stage of aging process was due to the release of coherency strains by the coarsening of tweed structure in the grain interior and by the growth and coarsening of the lamellar structure in the grain boundary. The increase of inter-lamellar space contributed slightly to the softening compared to the growth of lamellar structure toward the grain interior.

Electrochemical Characteristics of Zn-mesh Cathodic Protection Systems in Concrete in Natural Seawater at Elevated Temperature

  • Kim, Ki-Joon;Jung, Jin-A;Lee, Woo-Cheol;Jang, Tae-Seub
    • Corrosion Science and Technology
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    • 제6권6호
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    • pp.269-274
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    • 2007
  • The corrosion of steel in concrete is significant in marine environment. Salt damage is one of the most detrimental causes to concrete bridges and port structures. Especially, the splash and tidal zones around water line are comparatively important in terms of safety and life-time point of view. During the last several decades, cathodic protection (cp) has been commonly accepted as an effective technique for corrosion control in concrete structures. Zn-mesh sacrificial anode has been recently developed and started to apply to the bridge column cp in marine condition. The detailed parameters regarding Zn-mesh cp technique, however, have not well understood so far. This study is to investigate how much Zn-mesh cp influences along the concrete column at elevated temperature. About 100 cm column specimens with eight of 10 cm segment rebars have been used to measure the variation of cp potential with the distance from Zn-mesh anode at both $10^{\circ}C$ and $40^{\circ}C$ in natural seawater. The cp potential change and current diminishment along the column specimens have been discussed for the optimum design of cp by Zn-mesh sacrificial anode.

Rationalization of allosteric pathway in Thermus sp. GH5 methylglyoxal synthase

  • Zareian, Shekufeh;Khajeh, Khosro;Pazhang, Mohammad;Ranjbar, Bijan
    • BMB Reports
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    • 제45권12호
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    • pp.748-753
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    • 2012
  • A sequence of 10 amino acids at the C-terminus region of methylglyoxal synthase from Escherichia coli (EMGS) provides an arginine, which plays a crucial role in forming a salt bridge with a proximal aspartate residue in the neighboring subunit, consequently transferring the allosteric signal between subunits. In order to verify the role of arginine, the gene encoding MGS from a thermophile species, Thermus sp. GH5 (TMGS) lacking this arginine was cloned with an additional 30 bp sequence at the 3'-end and then expressed in form of a fusion TMGS with a 10 residual segment at the C-terminus ($TMGS^+$). The resulting recombinant enzyme showed a significant increase in cooperativity towards phosphate, reflected by a change in the Hill coefficient (nH) from 1.5 to 1.99. Experiments including site directed mutagenesis for Asp-10 in TMGS and $TMGS^+$, two dimentional structural survey, fluorescence and irreversible thermoinactivation were carried out to confirm this pathway.

광바이오 수소제조 시스템에서의 쏠라셀 및 나노여과 멤브레인 활용 (Use of Solar Cell and Nanofiltration Membrane for System of Enzymatic $H_2$ Production Through Light-Sensitized Photoanode)

  • 심은정;배상현;윤재경;주현규
    • 한국수소및신에너지학회논문집
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    • 제18권2호
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    • pp.151-156
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    • 2007
  • Solar cell and nanofiltration membrane were utilized in a system of enzymatic hydrogen production through light-sensitized photoanode, which resembles photoelectrochemical(PEC) configuration. Solar cell uses no additional light energy to increase energy for electrons to reduce protons and for holes to oxidize water to oxygen, and nanofiltration membrane replaces a salt bridge successfully with increased ion transport capability. With this system configuration, optimized amount of enzyme(10.98 unit), and an anodized tubular $TiO_2$ electrode($5^{\circ}C$/1 hr in 0.5 wt% HF-$650^{\circ}C$/5 hr) hydrogen evolved at a rate of ca. $43\;{\mu}mol/(cm^2{\times}hr)$ in a cathodic compartment and oxygen generated at a rate of ca. $20\;{\mu}mol/(cm^2{\times}hr)$ in an anodic compartment. The stoichiometric evolution of gases indicated that water was splitted in the system.

Effective Strategies to Reduce Sodium Intake among Consumers: Pork Cutlet Sauce as a Model Food System

  • Lee, Hyun;Lee, Mi Young;Kim, Eui-Su;Chung, Seo-Jin
    • 한국식생활문화학회지
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    • 제33권5호
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    • pp.426-436
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    • 2018
  • This study assessed effective strategies to reduce the sodium intake among consumers using pork cutlet sauce as a model food system. Original pork cutlet sauce and sodium-reduced sauce (29% reduced by a salt substitute) were analyzed to characterize the sensory properties using descriptive analysis. The effects of sodium-reduction of the sauce, consumer type (nutrition teachers vs. general consumers), information related to the sodium content, serving method, and consumer's health, taste and sodium-related attitudes on the consumer's preference, perception, and intake of the sauce were analyzed using a consumer test. In descriptive analysis, the original and sodium-reduced sauce showed similar sensory characteristics but did not differ in saltiness. In the consumer test, there were no significant differences in the overall preference levels between the two sauces. On the other hand, there were significant differences in preference and perception between nutrition teachers and general consumer groups, which were due largely to their age as well as the health and sodium-related attitudes and nutritional knowledge differences. Sodium-reduced information decreased the perceived saltiness intensity. In addition, reducing sodium intake by serving pork cutlet sauce in a bottle can be an effective strategy because this serving method increased the acceptance and induced the smaller intake of sauce.

창녕·함안보 방류량에 따른 하류지역 및 하구역의 수리환경특성에 관한 연구(1) (Study on Water Level and Salinity Characteristics of Nakdong River Estuary Area by Discharge Variations at Changnyeong-Haman Weir(1))

  • 김태우;양현수;박병우;윤종성
    • 한국해양공학회지
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    • 제32권5호
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    • pp.361-366
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    • 2018
  • The present study analyzed the variation factors in inducing a salinity change using the existing observation network in the section between the Nakdong River Estuary Barrage and Changnyeong-Haman Weir, and also examined the seasonal changes in precipitation, salinity, and discharge. Furthermore, this study analyzed the causes of a salinity increase by collecting observational data during a period when abnormal salinity occurred, and further investigated the salinity transfer time in a section of approximately 5.3 km from the Nakdong River Estuary Barrage to Nakdong River Bridge to understand the behavioral characteristics of the salinity moving upstream. The study results would make it possible to control the increase in salinity and block salt water from moving upstream by understanding the salinity variation characteristics according to the discharge amount. This will provide stability in collecting water from various residential, agricultural, and industrial sources through water intake facilities scattered near the Nakdong River Estuary Barrage.

감천항 수산물 도매시장 조경설계 (Landscape Design of Gamcheon Wholesale Fish Market)

  • 권영휴;민권식;황용득
    • 한국조경학회지
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    • 제30권2호
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    • pp.70-78
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    • 2002
  • The landscape disign of Gamcheon wholesale fish Market was designed around a turnkey base to promote the economy of Busan Metropolitan City, to establish a fishery marketing center and to modernize existing facilities. The objectives of the project were to promote the mood of an old market, while preserving its functions and efficiency as a market, to design outdoor spaces with natural resources and amenities in balance, and to create attractive tourist spots in connection with the wide area development plan. The project was oriented, fast, to enhance the functions of the market. For this purpose, a multi-dimensional space layout was designed in consideration of functions as a wholesale market. The safety of pedestrians was secured by separating lathes for vehicles and for pedestrians. Tree planting with various functions such as sheltering, wind breaking and guiding was planned. Secondly, nature-friendly and human-friendly landscaping design was attempted. For this, the beautiful natural resources of Amnam Park were utilized, and green spaces such as green bridges linking buildings in the wholesale market, and rooftop gardens were to be arranged. In addition, environment-friendly facilities such as roads paved with natural materials(i.e. gravel, shells) and program parking lots were to be planned. Thirdly, landscape design was considered to create attractive tourist spots. For example, a fish farm was created as a theme street for pedestrians and various water-friendly spaces such as pedestrian ramps, observatories and seaside streets were to be secured. The main contents are as follows. First, a green bridge to Ahnnam Park was introduced for a tour source and flower garden, an event plan and viewing deck open to the sea were planned on the bridge's axis. Secondly, for the effective land use plan concerning open space and convenience to visitors, a promenade was planned, which is connected with the theme plaza and small plazas by environmental sculptures in front of the market hall and at the gate. As well, an observatory and a roof garden help create three dimensional multi leveled space, with a good view of the natural landscape of the sea, sky and park Thirdly, landscape materials, such as trees and those for facilities, strengthened for protection against the seawind and salt damage were selected. The commercial market area was intended to be transformed a traditional functional area of efficiency and economy into an attractive marine leisure area where both tourists and neighbors can make use of it.

고로슬래그 미분말 콘크리트의 염화물 침투 저항성에 관한 연구 (A Study on Resistance of Chloride Ion Penetration in Ground Granulated Blast-Furnace Slag Concrete)

  • 송하원;권성준;이석원;변근주
    • 콘크리트학회논문집
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    • 제15권3호
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    • pp.400-408
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    • 2003
  • 염화물 이온은 철근의 부동태 피막을 파괴하여 부식을 촉진시키는 요인이며 철근의 부식은 콘크리트 구조물의 내구성뿐만 아니라 안전성에 가장 큰 영향을 주는 것으로 알려져 있다. 이러한 염해에 대해 적극적으로 대처하기 위하여 최근에는 공극률 슬래그 미분말의 사용이 본격화 되고 있다. 본 논문에서는 염해, 특히 보통 포틀랜트 시멘트 콘크리트 보다 우수한 염화물 이온의 침투저항성을 보유한 것으로 알려져 있는 공극률 슬래그 미분말 콘크리트에 대해 염화물 이온의 확산특성을 분석하였고, 염화물 이온의 거동을 해석할 수 있는 모델을 기존의 보통콘크리트 확산모델을 수정하여 제안하였다. 제안된 공극률슬래그 미분말 콘크리트의 염화물 이온 확산모델은 공극률슬래그 미분말 콘크리트에 대한 촉진염화물 분무실험 결과와 실제 RC 교량 교각부의 현장 염화물 실험결과와의 비교를 통하여 타당성을 검증하였으며, 검증된 모델을 이용한 해석과 실험을 통하여 고로슬래그 미분말 콘크리트의 염화물 이온의 침투에 따른 치환율 및 분말도에 따른 최적조건을 도출하였다. 고로슬래그 미분말 콘크리트의 염화물 이온 침투저항성은 고로슬래그 미분말을 사용함에 따라 보통 콘크리트에 비하여 우수하게 개선되었으며, 사용한 고로슬래그 미분말의 분말도보다 치환율에 영향을 더 받는 것으로 분석되었다.