• Title/Summary/Keyword: Salt alternatives

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AMBIDEBTER Nuclear Complex - A Credible Option for Future Nuclear Energy Applications (AMBIDEXTER 원자력 복합체 - 신뢰성 있는 미래 원자력에너지 이용 방안)

  • 오세기;정근모
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1998.05a
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    • pp.235-242
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    • 1998
  • Aiming at one of decisive alternatives for long term aspect of nuclear power concerns, an integral and closed nuclear system, AMBIDEXTER (Advanced Molten-salt Break-even Inherently-safe Dual-mission Experimental and TEst Reactor) concept is under development. The AMBIDEXTER complex essentially comprises two mutually independent loops of the radiation/material transport and the heat/energy conversion, centered at the integrated reactor assembly, which enables one to utilize maximum benefits of nuclear energy under minimum risks of nuclear radiation. And it provides precious radioisotopes and radiation sources from its waste stream. Also the reactor operates at very low level of fission products inventory throughout its lifetime. The nuclear and thermalhydraulic characteristics of the molten TH/$^{233}$ U fuel salt extend the capability of the self-sustaining AMBIDEXTER fuel cycle to enhance resource security and safeguard transparency. The reactor system is consisted of a single component module of the core, heat exchangers and recirculation pumps with neither pipe connections nor active valves in between, which will significantly improve inherent features of nuclear safety. States of the core technologies associated with designing and developing the AMBIDEXTER concept are mostly available in commercialized form and thus demonstration of integral aspects of the concept should be the prime area in future R&D programs.

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Biodegradation test of the alternatives of perfluorooctanesulfonate (PFOS) and PFOS salts (PFOS salts 및 PFOS 대체물질에 대한 미생물분해시험)

  • Choi, Bong-In;Na, Suk-Hyun;Son, Jun-hyo;Shin, Dong-Soo;Ryu, Byung-taek;Chung, Seon-yong
    • Journal of Environmental Health Sciences
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    • v.42 no.2
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    • pp.112-117
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    • 2016
  • Objectives: In this study, we investigated the biodegradation rates of 8 perfluorooctanesulfonate (PFOS) alternatives synthesized at the at Changwon National University in comparison to those of PFOS potassium salt and PFOS sodium salt. Methods: A biodegradability test was performed for 28 days with microorganisms cultured in the good laboratory practice laboratory at the Korea Environment Corporation following the OECD Guidelines for the testing of chemicals, Test No. 301 C Results: While $C_5H_8F_3SO_3K$, $C_8F_{17}SO_3K$ and $C_8F_{17}SO_3Na$ were not degraded after 28 days, the 3 alternatives were biodegraded at the rates of 31.4% for $C_8H_8F_9SO_3K$, 25.6% for $C_{10}H_8F_{13}SO_3K$, 23.6% for $C_{25}F_{17}H_{32}S_3O_{13}Na_3$, 20.9% for $C_{15}F_9H_{21}S_2O_8Na_2$, 15.5% for $C_{23}F_{18}H_{28}S_2O_8Na_2$, 8.5% for $C_{17}F_9H_{25}S_2O_8Na_2$ and 4.8% for $C_6H_8F_5SO_3K$. When the concentration was the same(500 mg/L), $C_{23}F_{18}H_{28}S_2O_8Na_2$ had the lowest tension with 20.94 mN/m, which was followed by $C_{15}F_9H_{21}S_2O_8Na_2$ (23.36 mN/m), $C_{17}F_9H_{25}S_2O_8Na_2$ (27.31 mN/m), $C_{25}F_{17}H_{32}S_3O_{13}Na_3$ (28.17 mN/m), $C_{10}H_8F_{13}SO_3K$ (29.77 mN/m) and $C_8H_8F_9SO_3K$ (33.89 mN/m). Having higher surface tension of 57.64 mN/m and 67.57 mN/m, respectively, than those of the two types of PFOS salts, $C_6H_8F_5SO_3K$ and $C_5H_8F_3SO_3K$ were found valueless as substitute for PFOS. Conclusion: The biodegradation test suggest that 6 compounds could be used as substitutes for PFOS. $C_{23}F_{18}H_{28}S_2O_8Na_2$ and $C_{15}F_9H_{21}S_2O_8Na_2$ were found to be the best substitutes based on biodegradation rate and surface tension, followed by $C_{25}F_{17}H_{32}S_3O_{13}Na_3$, $C_8H_8F_9SO_3K$ and $C_{10}H_8F_{13}SO_3K$. $C_{17}F_9H_{25}S_2O_8Na_2$ was found to have relatively low value as an alternative but it still had a potential to substitute the conventional PFOS.

A Study on the Temporal Correlation of Long-term Exposure Test and Accelerated Corrosion Test of Rebar (장기폭로 시험과 철근 부식 촉진시험의 시간적 상관성에 관한 연구)

  • Lee, Min-Woo;Park, Sang-Soon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.4
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    • pp.307-313
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    • 2014
  • Recent interest in the increased structural performance and durability evaluation of this concrete structure in a salt damage environment is increasing. The most secure and reliable method of accelerated corrosion test is a method to carry out the rebar corrosion monitoring can be exposed directly to the marine test site exposure. However, long-term exposure testinghas the disadvantage that a long period is necessary. So, a lot of research on RC of salt damage environment have beenpromoted as alternatives to replace this. However, accelerated corrosion test, in the short term only is appropriate and is but an accelerated test method to evaluate the critical chlorine concentration, there is a difficult problem that you still get the answer. It is one of the correlation problems accelerated test correspond to a certain period of exposure environment. Therefore, in this study, to clarify the differences rebar corrosion beginning, through the actual corrosion accelerated test in corrosion time and laboratory test chamber of the structure of the marine environment results in both environments, it is an object of correlation coefficient derived.

Evaluation of the Corrosion Resistance of Steel Coated with Zinc Using a Cr-free Coating Solution as a Function of Heat Treatment Time (Cr-free 코팅액에 의한 아연도금강판의 건조시간에 따른 내식특성)

  • Seo, Hyun-Soo;Moon, Hee-Joon;Kim, Jong-Soon;Ahn, Seok-Hwan;Moon, Chang-Kwon;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.24 no.5
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    • pp.67-74
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    • 2010
  • Chromate conversion coating is a coating technique used to passivate aluminum, zinc, cadmium, copper, silver, magnesium, tin, and their alloys to slow corrosion. The process uses various toxic chromium compounds, which may include hexavalent chromium. The industry is developing less toxic alternatives in order to comply with substance restriction legislation, such as RoHS. One alternative is to develop a Cr-free coating solution. In this study, eco-friendly, Cr-free solutions (urethane solution S-700, organic/inorganic solution with Si LRO-317) were used. Test specimens were dried in a drying oven at $190^{\circ}C$ for 3, 5, 7, and 9 minutes. Corrosion resistance was evaluated using a salt spray test for 72 hours. The results show that the optimum corrosion resistance was achieved at $190^{\circ}C$ for five minutes for EGI and three or five minutes for HDGI, respectively. The adhesive properties of the two types of coating solutions were superior regardless of drying time.

Electrochemical properties of metal salts polymer electrolyte for DSSC (금속염을 이용한 염료감응 태양전지의 고체전해질의 전기화학적 특성)

  • Zhao, Xing Guan;Jin, En Mei;Gu, Hal-Bon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.55.1-55.1
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    • 2011
  • Dye-sensitized solar cell(DSSC) have been considered one of the promising alternatives to conventional solar cells, because of their low cost, easy fabrication and relatively high energy conversion efficiency. However, although the cell offers reasonable efficiency at least 11%, the use of a liquid electrolyte placed technological challenges for achieving the desired durability and operational stability of the cell. In order to prevent or reduce electrolyte leakage considerable efforts have been made, such as p-type semiconductor or organic hole-transport material that better mechanical properties and simple fabrication processes. In this work, we synthesized solid-state electrolyte containing LiI and KI metal salt with starting materials of poly ethylene oxide to substitute liquid electrolyte enhance the ionic conductivity and solar conversion efficiency. Li+ leads to faster diffusion and higher efficiency and K+ leading to higher ionic conductivity. The efficiency of poly ethylene oxide/LiI system electrolyte is 1.47% and poly ethylene oxide/potassium electrolyte is 1.21%. An efficiency of 3.24% is achieved using solid-state electrolyte containing LiI and KI concentrations. The increased solar conversion efficiency is attributed to decreased crystallinity in the polymer that leads to enhanced charge transfer.

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Effect of Reclaimed Sewage Irrigation on Paddy Rice Culture and Soil Characteristics (오수처리수의 관개가 벼 생육 및 토양 특성에 미치는 효과)

  • 윤춘경
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.42 no.3
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    • pp.66-75
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    • 2000
  • Effect of reclaimed sewage on the paddy rice culture was examined by field experiment for two consecutive years. The domestic sewage was treated by the constructed wetland and the effluent of the treatment wetland was used for irrigation water. The reclaimed sewage was diluted before irrigation in the first year and it was used without dilution in the second year experiment. Growth components and yields were compared against the control plot where conventional method was applied. And also soil characteristics of the plots before and after reclaimed sewage irrigation were analyzed Generally addition of the reclaimed sewage irrigation didn't affect paddy rice culture adversely and even enhancement was observed. Fertilization was thought to be important factor for rice culture rather than irrigation water quality. Conventional fertilization and reclaimed sewage irrigation which contained high nutrient concentration resulted in better growth and more yield. Unlike widespread concern lodging did not happen even in the case of irrigation with average 90mg/L of T-N and conventional fertilization. Soil characteristics changed after irrigation and significant EC increasing was observed for the reclaimed sewage irrigation plots. From soil analyses salt accumulation could be a more potential problem than nutrients like nitrogen and phosphorus in the use of reclaimed sewage irrigation. Overall reclaimed sewage irrigation was thought to be one of practical alternatives for the ultimate disposal of sewage in rural area.

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Landscape Planning for Shiwha Migratory Birds Habitat

  • Joo Shin-Ha;Ahn Se-Hyon
    • Journal of the Korean Institute of Landscape Architecture International Edition
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    • no.2
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    • pp.130-139
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    • 2004
  • Shiwha Lake is an excellent example of a body of water restored from a state of heavy pollution to a cleaner and more ecological state. This paper will explore techniques and methods available to landscape planning for the creation of new migratory birds habitats in Shiwha Lake. Because Shiwha lake is located adjacent to a new industrial site on reclaimed land, any planning effort aimed at restoring bird habitats must carefully consider the existing context. This plan had 3 goals; (1) to restore the coastal environment, (2) to create a habitat for migratory birds, and (3) to administer environmental education programs. To achieve these goals, several objectives were determined and planning criteria were proposed for topology, water environment(fresh, brackish and salt water swamps), zoning(for experts and general visitors), circulations, planting and mounding. The flora and fauna of the site was surveyed, and 5 alternatives were suggested and compared in several aspects. Planting species were carefully selected considering target birds and habitat requirements. In order to increase bio-diversity of the site, the plan proposed multi-staired mounds and extensive drainage systems. Bird watching facilities with natural materials, and the remote observing system using CCTV and the internet were some of the ecological techniques recommended by the plan. The bird watching trails are divided into two different zones for experts and general visitors.

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An updated review on probiotics as an alternative of antibiotics in poultry - A review

  • Yaqoob, Muhammad Umar;Wang, Geng;Wang, Minqi
    • Animal Bioscience
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    • v.35 no.8
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    • pp.1109-1120
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    • 2022
  • Antibiotics used to be supplemented to animal feeds as growth promoter and as an effective strategy to reduce the burden of pathogenic bacteria present in the gastro-intestinal tract. However, in-feed antibiotics also kill bacteria that may be beneficial to the animal. Secondly, unrestricted use of antibiotics enhanced the antibiotic resistance in pathogenic bacteria. To overcome above problems, scientists are taking a great deal of measures to develop alternatives of antibiotics. There is convincing evidence that probiotics could replace in-feed antibiotics in poultry production. Because they have beneficial effects on growth performance, meat quality, bone health and eggshell quality in poultry. Better immune responses, healthier intestinal microflora and morphology which help the birds to resist against disease attack were also identified with the supplementation of probiotics. Probiotics establish cross-feeding between different bacterial strains of gut ecosystem and reduce the blood cholesterol level via bile salt hydrolase activity. The action mode of probiotics was also updated according to recently published literatures, i.e antimicrobial substances generation or toxin reduction. This comprehensive review of probiotics is aimed to highlight the beneficial effects of probiotics as a potential alternative strategy to replace the antibiotics in poultry.

Preliminary screening of leafy vegetable New Zealand spinaches (Tetragonia tetragonioides) native to Korea (국내 자생 엽채류 번행초의 우수 유전자원 기초 선발)

  • Kim, In-Kyung;Lee, Ka Yeon;Kim, Sung-Ki;Kim, Byung-Woon;Choi, Weon-Young;Lee, Geung-Joo
    • Korean Journal of Agricultural Science
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    • v.39 no.4
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    • pp.515-523
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    • 2012
  • Recent development and enlargement of reclaimed lands along the sea shores required to explore alternatives to existing crops, which are suitable to grow well and to declare higher profits. The objectives of this study were to investigate yield-related parameters for development of new leafy vegetables, and to screen some candidates among New Zealand spinach genotypes which were collected in Korea. Initially all the collected genotypes were grown for 7 weeks in a greenhouse of the experiment field in Chungnam National University, and then transplanted into the field to measure morphological or physiological parameters (plant height, branch number, stem diameter, chlorophyll content, and maximum canopy diameter), and yield-related parameters (leaf number, leaf length, leaf width, fresh weight and dry weight). Those parameters were quantitatively measured at 1, 5 or 9 weeks after transplanting (WAT). Parameters exhibiting statistically significant difference among the accessions were plant height, branch number, maximum canopy diameter, chlorophyll content, and leaf length. In contrast to highly correlated parameters with fresh and dry weight obtained in salt-affected soil in the earlier report, fresh weight was correlated significantly with leaf length (r=0.72), leaf width (r=0.64), and canopy diameter(r=0.66), while dry weight was correlated significantly with plant height (r=0.46), leaf length (r=0.72), leaf width (r=0.73), fresh weight (r=0.79), chlorophyll content (r=0.47), and canopy diameter (r=0.87). Based on the significantly correlated with yield parameters, the candidate accessions which were ranked in top statistical groups include CNU06A01, CNU06A13, CNU06A26, CNU06A35, CNU06A38, and CNU06A55. In order to be cultivated in reclaimed lands, it is necessary to screen out salt tolerant accessions among the above high-yielding genotypes.

Stabilization/Solidification of Radioactive LiCl-KCl Waste Salt by Using SiO2-Al2O3-P2O5 (SAP) inorganic composite: Part 1. Dechlorination Behavior of LiCl-KCl and Characteristics of Consolidation (SiO2-Al2O3-P2O5 무기복합체를 이용한 LiCl-KCl 방사성 폐기물의 안정화/고형화: Part 1. LiCl-KCl의 탈염화 반응거동 및 고형화특성)

  • Cho, In-Hak;Park, Hwan-Seo;Ahn, Soo-Na;Kim, In-Tae;Cho, Yong-Zun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.1
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    • pp.45-53
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    • 2012
  • The metal chloride wastes from a pyrochemical process to recover uranium and transuranic elements has been considered as a problematic waste difficult to apply to a conventional solidification method due to the high volatility and low compatibility with silicate glass. In this study, a dechlorination approach to treat LiCl-KCl waste for final disposal was adapted. In this study, a $SiO_2-Al_2O_3-P_2O_5$ (SAP) inorganic composite as a dechlorination agent was prepared by a conventional sol-gel process. By using a series of SAPs, the dechlorination behavior and consolidation of reaction products were investigated. Different from LiCl waste, the dechlorination reaction occurred mainly at two temperature ranges. The thermogravimetric test indicated that the first reaction range was about $400^{\circ}C$ for LiCl and the second was about $700^{\circ}C$ for KCl. The SAP 1071 (Si/Al/P=1/0.75/1 in molar) was found to be the most favorable SAP as a dechlorination agent under given conditions. The consolidation test revealed that the bulk shape and the densification of consolidated forms depended on the SAP/Salt ratios. The leaching test by PCT-A method was performed to evaluate the durability of consolidated forms. This study provided the basic information on the dechlorination approach. Based on the experimental results, the dechlorination method using a $SiO_2-Al_2O_3-P_2O_5$ (SAP) could be considered as one of alternatives for the immobilization of waste salt.