• Title/Summary/Keyword: Sacrificial anode

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Electrochemical Evaluation of Corrosion Properties of Aluminum Alloy as a Sacrificial Anode for Offshore Structure Protection (해양구조물의 방식을 위한 알루미늄 합금의 희생양극적 부식 특성의 전기화학적 평가)

  • Rhee, Jin-Ho;Lee, Jae-Ho
    • Journal of the Korean institute of surface engineering
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    • v.48 no.2
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    • pp.68-72
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    • 2015
  • The corrosion behavior of metals and alloys for the safety of offshore structures in seawater was investigated for the application of sacrificial anodes. The experiments were focused on the polarization behaviors and the surface morphology of each metal after experiments. Pure Zn, pure Al (Al1050), Al alloys (Al5052, Al6061), Mg alloys (AZ31, AZ91D) and steel (SCM440) were assessed in 3.5% sodium chloride solution by means of potentiodynamic polarization to verify the galvanic corrosion potential ($E_{couple}$). Potentiostat plots were plotted to compare the surface and corrosion current density ($i_{couple}$) of metals as sacrificial anodes in seawater to protect steel alloy as a cathode. Al alloys showed the best performance as a sacrificial anode, on the other hand, Mg alloys showed overprotection behavior. The surface morphologies of sacrificial anodes were observed by FESEM and compared.

CORROSION BEHAVIOR OF Al-Zn ALLOY AS A SACRIFICIAL ANODE OF ORV TUBES

  • Jin, Huh;Lee, Ho-Kyun;Lee, Jae-Ho
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.452-455
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    • 1999
  • ORV which vaporizes LNG to NG is consisted of tube and header whose substrate is aluminum alloy. The corrosion of the tube is very severe because of sea water being used as the heating source. In this research to protect ORV substrate material, the corrosion behavior of aluminum alloys was investigated for the sacrificial role of Al-Zn alloy for ORV tubes. The electrochemical behavior of aluminum alloys in sea water was investigated. The corrosion behavior of thermally-sprayed and cladded samples were compared through salt spray tests. Al-Zn alloy can act as a sacrificial anode and cladded Al-Zn alloy has a better corrosion resistance than that of thermally sprayed one. The galvanic effect of Al-Zn to substrate material was conformed from scratched sample tests.

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An Experimental Study on the Steel Corrosion Control in Concrete by using the Sacrificial Anode System (희생양극법을 응용한 콘크리트중의 철근부식 억제에 대한 실험적 연구)

  • 문한영;김성수;류재석;김홍삼;김성섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.04a
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    • pp.191-196
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    • 1997
  • Steel is the most used as materials for construction and corrosion expansion of steel due to outdoor corrosive environmental factor bring serious problem on the durability of concrete structures time after time. It is the purpose of this study to see whether it is effective of not, when sacrificial anode method is adapted. Indoor accelerated corrosion testing was carried out to see its effective in a short term. From the mid result, potential of steel in concrete in case of adapting sacrifice anode method satisfacts protection standard value (less than-850mV vs CSE), therefore sacrificial anode method is considered as a proper protection steps against corrosion of steel.

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Cathodic Protection of Onshore Buried Pipelines Considering Economic Feasibility and Maintenance

  • Choi, Byoung-Yeol;Lee, Sang-Gil;Kim, Jin-Kwang;Oh, Jin-Soo
    • Journal of Advanced Research in Ocean Engineering
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    • v.2 no.4
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    • pp.158-168
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    • 2016
  • During the installation of crude oil or gas pipelines, which pass through onshore buried pipelines or onshore pipeline from subsea pipeline to onshore plant, countermeasures need to be implemented so as to ensure a sufficient design life by protecting the steel pipes against corrosion. This can be achieved through impressed current cathodic protection method for onshore pipelines and through galvanic sacrificial anode corrosion protection method for offshore pipelines. In particular, in the case of impressed current cathodic protection, isolation joint flanges should be used. However, this makes maintenance control difficult with its installation having a negative impact on price. Therefore, in this study, the most suitable methodology for onshore pipeline protection between galvanic sacrificial anode corrosion protection and impressed current cathodic protection method will be introduced. In oil and gas transportation facilities, the media can be carried to the end users via onshore buried and/or offshore pipeline. It is imperative for the field operators, pipeline engineers, and designers to be corrosion conscious as the pipelines would undergo material degradations due to corrosion. The mitigation can be achieved with the introduction of an impressed current cathodic protection method for onshore buried pipelines and a galvanic sacrificial anode corrosion protection method for offshore pipelines. In the case of impressed current cathodic protection, isolation joint flanges should be used to discontinuity. However, this makes maintenance control to be difficult when its installation has a negative impact on the price. In this study, the most suitable corrosion protection technique between galvanic sacrificial anode corrosion protection and impressed current cathodic protection is introduced for (economic life of) onshore buried pipeline.

A Study on Monitoring of Mitigation of Rail Corrosion using Sacrificial Anode Cathodic Protection Method (희생양극법을 적용한 철도 레일의 방식효과 모니터링 연구)

  • Choi, Jung-Youl;Park, Jong-Yoon;Lee, Kyu-Yong;Chung, Jee-Seung
    • The Journal of the Convergence on Culture Technology
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    • v.5 no.4
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    • pp.367-371
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    • 2019
  • In this study, we proposed the sacrificial anode cathodic protection method as a countermeasure to reduce the corrosion of railway rails under oceanic climatic conditions and proved the anticorrosive effect experimentally. In addition, the proposed sacrificial anode cathodic protection method were tested on site to examine long-term rail corrosion monitoring and field applicability for more than 26 months and to prove the effectiveness of rail corrosion. As a result of monitoring the corrosion state using the cellophane tape method, the appearance of the applied sections with sacrificial anode cathodic protection method was good at the present time about 26 months after the field test laying, and no abnormalities and other abnormalities of the rail welded section and the rail web were found. Hence, in places where no sacrificial anodes were installed, rust progressed rapidly. In addition, the proper spacing of sacrificial anodes was found to form the most stable corrosion coating at 1.0 ~ 1.5m. After about 26 months of monitoring, the installation of sacrificial anodes could help stabilize the overall rail corrosion level, even if the spacing was somewhat wider.

The effect of cathodic protection system by means of zinc sacrificial anode on pier in Korea

  • Jeong, Jin-A;Jin, Chung-Kuk
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.10
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    • pp.1206-1211
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    • 2014
  • This study has been conducted to confirm the effect of sacrificial anode cathodic protection system for 90 days to protect corrosion on pier that is located in Korea. The cathodically protected structure was a slab and a pile cap. Before the construction of cathodic protection system, the macrography was carried out. As a result of the macrography, many corrosion traces were confirmed in this structure. The trace was mainly focused on joint and zones that concrete cover was eliminated. To apply the cathodic protection system, many onsite techniques have been adopted. In addition, to confirm the inner state of steel in concrete properly, a corrosion monitoring sensor (DMS-100, Conclinic Co. Ltd) has been applied. Test factors were corrosion & cathodic protection potential, 4 hour depolarization potential, resistivity and current density. After 90 days from the installation of cathodic protection system, it could confirm that proper corrosion protection effect was obtained by considering the result of tests.

Study on the Corrosionproofing in Concrete by Cathodic Protection (전위변화에 의한 콘크리트내의 철근방식에 관한 연구)

  • Lim, Seo-Hyung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.3 no.2
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    • pp.213-220
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    • 1999
  • The purpose of this study is to apply cathodic protection to reinforced concrete structure and provide fundamental data to prevent the corrosion. The theory of cathodic protection of steel in concrete is to apply sufficient direct current so that corroding anodes on the steel are prevented from discharging ions. Two methods are used to supply the external current. In one, the protected metal is the cathode by connecting it to a more active metal. In the second, an external direct current power source supplies the current. The first is the sacrificial-anode system and the second the impressed-current system. The study results showed that the corrosion of the reinforcing steel in concrete could be enormously decreased by using protective current. The sacrificial anode and concrete nave to be adhered closely each in order to prevent the corrosion of reinforcing steel.

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Effect of Zinc Addition in Filler Metal on Sacrificial Anode Cathodic Protection of Fin-Tube Aluminum Heat Exchanger

  • Yoon-Sik So;Eun-Ha Park;Jung-Gu Kim
    • Journal of Electrochemical Science and Technology
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    • v.14 no.4
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    • pp.349-360
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    • 2023
  • This study investigated the tri-metallic galvanic coupling of different metals in the tubes, fillers, and fins of a heat exchanger. The goal was to prevent corrosion of the tubes using the fin as a sacrificial anode while ensuring that the filler metal has a more noble potential than the fin, to avoid detachment. The metals were arranged in descending order of corrosion potential, with the noblest potential assigned to the tube, followed by the filler metal and the fin. To address a reduction in protection current of the fin, the filler metal was modified by adding Zn to decrease its corrosion potential. However, increasing the Zn content of filler metal also increases its corrosion current. The study examined three different filler metals, considering their corrosion potential, and kinetics. The results suggest that a filler metal with 1.5 wt.% Zn addition is optimal for providing cathodic protection to the tube while reducing the reaction rate of the sacrificial anode.

A study on the performance of the sacrificial anode used for cathodic protection of a marine bridge after 8 years (해상 교량에 설치된 희생양극식 전기방식의 8년 이후의 성능에 관한 연구)

  • Jeong, Jin-A;Ha, Ji-Myung;Lee, Du-Young;Lee, Sang-Deuk
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.6
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    • pp.510-515
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    • 2016
  • Recently, corrosion occurred on the piles of a marine bridge located on the NamHae expressway in Korea. A sacrificial anode cathodic protection system was installed to prevent corrosion damage in the marine bridge. In the case of the marine bridge in this study, the sacrificial anode cathodic protection system was applied at the tidal and splash zones of the piles because the upper part of the structure was not corroded, and because corrosion occurs at the tidal and splash zones due to sea tides. To verify the performance of the sacrificial anode cathodic protection system 8 years later, cathodic protection (CP) current, CP potential, and degree of depolarization were measured. The experimental results on the performance of the sacrificial anode cathodic protection system from a total of 60 piles were classified into 4 categories: good CP effect results (13 piles), partial CP effect results (27 piles), temporarily erroneous results (5 piles), and need for maintenance because of delamination (15 piles). It was determined that additional repairs are required, such as the application of bulk anodes and jacket casings, for piles where the CP effect is poor.

Electrochemical Characteristics of Zn-mesh Cathodic Protection Systems in Concrete in Natural Seawater at Elevated Temperature

  • Kim, Ki-Joon;Jung, Jin-A;Lee, Woo-Cheol;Jang, Tae-Seub
    • Corrosion Science and Technology
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    • v.6 no.6
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    • pp.269-274
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    • 2007
  • The corrosion of steel in concrete is significant in marine environment. Salt damage is one of the most detrimental causes to concrete bridges and port structures. Especially, the splash and tidal zones around water line are comparatively important in terms of safety and life-time point of view. During the last several decades, cathodic protection (cp) has been commonly accepted as an effective technique for corrosion control in concrete structures. Zn-mesh sacrificial anode has been recently developed and started to apply to the bridge column cp in marine condition. The detailed parameters regarding Zn-mesh cp technique, however, have not well understood so far. This study is to investigate how much Zn-mesh cp influences along the concrete column at elevated temperature. About 100 cm column specimens with eight of 10 cm segment rebars have been used to measure the variation of cp potential with the distance from Zn-mesh anode at both $10^{\circ}C$ and $40^{\circ}C$ in natural seawater. The cp potential change and current diminishment along the column specimens have been discussed for the optimum design of cp by Zn-mesh sacrificial anode.