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Production of Foamed Glass by Using Hydrolysis of Waste Glass (I) - Hydrolysis of Waste Glass - (폐 유리의 가수 분해반응에 의한 발포유리의 제조(I) - 폐유리의 가수분해 반응 -)

  • Lee, Chul-Tae;Lee, Hong-Gil
    • Applied Chemistry for Engineering
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    • v.16 no.4
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    • pp.519-526
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    • 2005
  • Hydrolysis of soda-lime waste glass was investigated to test the feasibility for use of waste glass as feed material in the production of foamed glass. The soda-lime glass, such as plate glass and various bottle glasses, was effectively hydrolyzed by steam and water under high pressure. The proper condition for the hydrolysis was found to be reaction temperature of $250^{\circ}C$ and reaction time of 2 h. Under this condition, the water content of hydrated glass through hydrolysis was 7.85~10.04%, allowing successful foaming process for production of foamed glass. Using Na as the modifying agent of glass was effective in the hydrolysis by water. The highest water content of hydrated glass was obtained when weight ratio of NaOH to the glass was 0.04.

Effect of Intercritical Annealing on the Dynamic Strain Aging(DSA) and Toughness of SA106 Gr.C Piping Steel

  • Lee, Joo-Suk;Kim, In-Sup;Park, Chi-Yong;Kim, Jin-Weon
    • Nuclear Engineering and Technology
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    • v.32 no.1
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    • pp.77-87
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    • 2000
  • It is reported that the toughness and safety margins of the SA106 Gr.C main steam line piping steel is reduced due to dynamic strain aging (DSA) at the reactor operating temperature for Leak-Before-Break (LBB) application. In this study, intercritical annealing in two-phase ($\alpha$+${\gamma}$)region was performed to investigate the possibility of improving the toughness and reducing DSA susceptibility. The manifestations of DSA were still observed in the tensile tests of the annealed specimens. However, the ductility loss caused by DSA was smaller than that in the as-received material. Furthermore, the intercritical annealing was able to increase the Charpy impact toughness by 1.5 times compared to as-received. With the heat treatment, we could obtain microstructural changes such as the cleaner retained ferrite, increased ferrite content and somewhat finer grain size. It is considered that the reduced DSA was induced by cleaner retained ferrite, which in turn resulted in higher impact toughness in addition to the general toughening due to finer grain sizes and increased ferrite content.

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Changes in Physicochemical Properties of Packaged Backsulgi during Storage (포장한 백설기의 저장과정 중 이화학적 변화)

  • 이경아;김경자
    • Korean Journal of Human Ecology
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    • v.5 no.2
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    • pp.45-54
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    • 2002
  • Packaged Backsulgi cooked by steam/convection oven and then rapidly chilled was examined by research of microbiological test and sensory evaluation while storing them at the temperatures of 3$^{\circ}C$ and 3$0^{\circ}C$ for 0, 2, 4, 6, 10 days . The pH and reducing sugar content were seemed to change little at 3$^{\circ}C$. However the pH was rapidly reduced until 4 days and then decreased a little at 3$0^{\circ}C$, the reducing sugar content was inclosed little by little. In the microbiological test, any microbial growth in total aerobic, psychrophilic, anaerobic, spore forming bacteria, yeast and molds was not observed until 10 days at 3$^{\circ}C$, but microbial changes of aerobic, psychrophilic and anaerobic bacteria increased to 6 logCFU/g until 10 days at 3$0^{\circ}C$. However microbial changes of them decreased from 6 logCFU/g to 5 logCFU/g. As a result of the sensory evaluation, appearance, taste, color, softness, chewiness and overall Quality were significantly decreased during storage times(p<0.05), but scores of taste and overall quality on 6th days were 7.38${\pm}$1.06, 7.00${\pm}$0.93. Therefore we concluded that there was no problem about stability of storage 6 days at 3$^{\circ}C$.

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Sulforaphane Content and Antioxidative Effect of Cooked Broccoli (조리된 브로콜리의 항산화 효과 및 Sulforaphane 함량 분석)

  • Kim, Ji-Young;Park, Sang-Hyun;Lee, Ki-Teak
    • Journal of the East Asian Society of Dietary Life
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    • v.19 no.4
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    • pp.564-569
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    • 2009
  • Antioxidative activities, total phenolic compounds and the sulforaphane contents of cooked broccoli extracts were studied. Total phenolic compounds were determined to be 0.96 mg/g(flower) and 0.76 mg/g(stem) in fresh broccoli extracts. The total phenolic compounds of cooked broccoli extracts showed 0.92 (1 min), 0.79 (3 min), 0.67 (10 min) mg/g when a boiling process was used and 1.27 (1 min) mg/g when a steaming process was used. In the DPPH assay, the steam process showed the highest free radical scavenging capacities. Sulforaphane has been of increasing interest in the nutraceutical and phamaceutical industries due to its anti-cancer effect. Sulforaphane was isolated from fresh and boiled, steamed broccoli using dichloromethane as an extract solvent. The sulforaphane contents of fresh broccoli were higher in the flower (14.78 mg/kg) than in the stem (6.16 mg/kg). The sulforaphane content dramatically decreased after the boiling ($100{\pm}2^{\circ}C$) or steaming ($100{\pm}2^{\circ}C$) processes were used.

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Effect of Sn Addition on Corrosion Behavior of Zr-1.0 Nb-xSn Alloy System (Zr-1.0Nb-xSn 합금의 부식거동에 대한 Sn첨가의 영향)

  • Lee, Myeong-Ho;Choe, Byeong-Gwon;Jeong, Yong-Hwan
    • Korean Journal of Materials Research
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    • v.12 no.5
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    • pp.369-374
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    • 2002
  • To investigate the corrosion behavior of Zr-1.0Nb-xSn (x=1.0, 1.5, 2.0 and 2.5wt. %)alloy system, the corrosion tests of Zr-1.0Nb-xSn alloys were carried out in steam at $400^{\circ}C$ for 125 days and in 70ppm LiOH solution at $360^{\circ}C$ for 180 days. The matrix microstructures of the test specimens were analyzed using TEM and the oxide structures on the test specimens were analyzed using XRD. It was found from the analyses that the more Sn content the alloy had, the faster it was corroded and with the increase of Sn content in the alloy the fraction of $t-ZrO_2$ to $m-ZrO_2$ was decreased. It was also found that the alloys having more Sn showed more dislocation density than those having less.

Control of Grade Change Operations in Paper Plants Using Model Predictive Control Method (모델예측제어 기법을 이용한 제지공정에서의 지종교체 제어)

  • Kim, Do-Hoon;Yeo, Young-Gu;Park, Si-Han;Kang, Hong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.4
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    • pp.48-56
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    • 2003
  • In this work an integrated model for paper plants combining wet-end and dry section is developed and a model predictive control scheme based on the plant model is proposed. Closed-loop process identification method is employed to produce a state-space model. Thick stock, filler flow, machine speed and steam pressure are selected as input variables and basis weight, ash content and moisture content are considered as output variables. The desired output trajectory is constructed in the form of 1st-order dynamics. Results of simulations for control of grade change operations are compared with plant operation data collected during the grade change operations under the same conditions as in simulations. From the comparison, we can see that the proposed model predictive control scheme reduces the grade change time and achieves stable steady-state.

Effect of Cooling Rates on Mechanical Properties and Microstructure of Inconel Alloys (인코넬 합금의 미세조직과 기계적 특성에 미치는 냉각속도 영향)

  • Park, No-Kyeong;Lee, Ho-Seong;Chai, Young-Suck
    • Korean Journal of Materials Research
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    • v.17 no.10
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    • pp.555-559
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    • 2007
  • The mechanical properties and microstructure of Inconel 690 and 600 alloys with various cooling rates were investigated. Optical microscopy and scanning electron microscopy observations indicated that in case of the cooling rate of $0.5^{\circ}C/min$, discontinuous carbides along the grain boundaries were formed and when the cooling rate was $10^{\circ}C/min$, continuous carbides were formed in Inconel 690 and 600 alloys. For the annealed Inconel 690 alloy with high Cr content, a lot of annealing twins, which led the preferential growth of (111) planes, were observed. However, the annealed Inconel 600 alloy with low Cr content showed a few annealing twins and the preferential growth of (200) planes. Inconel 600 alloy had a larger value of ultimate tensile strength (UTS) than Inconel 690 alloy.

Effects of Si Addition on the Microstructure and Properties of Cr-Al alloy for High Temperature Coating (고온 코팅용 Cr-Al합금의 미세조직 및 특성에 미치는 Si 첨가의 영향)

  • Kim, Jeong-Min;Kim, Il-Hyun;Kim, Hyun-Gil
    • Korean Journal of Materials Research
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    • v.29 no.1
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    • pp.7-10
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    • 2019
  • Cr-Al alloys are attracting attention as oxidation resistant coating materials for high temperature metallic materials due to their excellent high temperature stability. However, the mechanical properties and oxidation resistance of Cr-Al alloys can be further enhanced, and such attempts are made in this study. To improve the properties of Cr-Al alloys, Si is added up to 5 wt%. Casting specimens with different amounts of Si content are prepared by a vacuum arc remelting method and isothermally heated under steam conditions at $1,100^{\circ}C$ for 1 hour. The as-cast microstructure of low Si alloys is mainly composed of only a Cr phase, while $Al_8Cr_5$ and $Cr_3Si$ phases are also observed in the 5 % Si alloy. In the high Si alloy, only Cr and $Cr_3Si$ phases remain after the isothermal heating at $1,100^{\circ}C$. It is found that Si additions slightly decrease the oxidation resistance of the Cr-Al alloy. However, the microhardness of the Cr-Al alloy is observed to increase with an increasing Si content.

Improvement of Paper Strength using Pretreated Precipitated Calcium Carbonate (PCC) (종이의 강도향상을 위한 경질탄산칼슘(PCC) 전처리에 대한 연구)

  • Kim, Chul-Hwan;Lee, Ji-Young;Gwak, Hye-Joeng;Chung, Ho-Kyung;Back, Kyung-Kil;Lee, Hui-Jin;Kim, Sung-Ho;Kang, Ha-Ryoun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.1
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    • pp.41-47
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    • 2010
  • Increasing ash content of the paper is one of the most effective methods for saving raw materials and steam consumption and improving optical properties and better print quality. However, the increase of filler loading or filler content using a conventional wet end system is limited due to severe loss in strength properties, affecting runnability and product quality. This is because the filler has no ability to make bonding with cellulosic fibers. Therefore, if the technology to give filler the bonding ability is developed, the ash content of the paper can be increased more than ever. This study was carried out to modify PCC by coating its surface with starch contributing to better bonding with fibers. To prepare the modified PCC, cationic starch was selected as a polymer and then pretreatment was done by mixing PCC and cationic starch. Consequently, the pretreated PCC contributed to higher tensile strength, stiffness and opacity than the conventional filler, such as GCC and untreated PCC. However, CIE whiteness and ISO brightness decreased slightly compared to conventional fillers.

Characteristics of egg coagulates cooked conventionally or by microwaves (Microwave 처리가 알찜의 품질 특성에 미치는 영향)

  • Oh, Hae-Sook;Myoung, Choon-Ok
    • Korean journal of food and cookery science
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    • v.10 no.4
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    • pp.351-356
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    • 1994
  • Comparisions were made for cooking times, internal temperatures, thiamin contents and textural properties of various portion weights of egg mixture cooked in a microwave oven at high and/or low power levels and in a conventional double boiler. The mean internal temperatures of conventionally cooked egg mixtures were 76.4~80.7$^{\circ}C$. When cooking was made by steaming, the mean internal temperature were comparable among samples. With the microwave cooking, the range of mean temperature was 83.8~96.4$^{\circ}C$, and they were significantly higher than the conventionally cooked egg mixtures. The hardness determination was conducted using universal testing machine and a taste panel. Samples cooked with steam or with larger portion weight had softer texture than samples cooked by microwaves or smaller amount, respectively. Mean internal temperature was significantly(r=0.99, p<0.05) correlated with mechanical hardness determination. Statistical analyses indicated no significant difference in the thiamin content among various treatments.

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