• Title/Summary/Keyword: STARCH

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Manufacture and Properties of PMMA Grafted Starch/Carbon Black/NBR Composites (PMMA 그래프트 전분/카본블랙/NBR 복합체의 제조와 물성)

  • Kim, Min-Su;Cho, Ur Ryong
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.764-769
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    • 2013
  • Starch was grafted by poly(methyl methacrylate) through the emulsion polymerization method. Modified starch/(acrylonitrile-butadiene rubber) (NBR) compounds were prepared by a latex blend method. The morphology, thermal properties and mechanical properties of the modified starch/carbon black/NBR composites were investigated with the change of starch concentration. The mechanical properties of the composites were improved by the addition of modified starch. But, when the concentration of modified starch was higher than 40 phr, the mechanical properties were deteriorated due to the poor dispersion of modified starch. At the same ratio of starch to carbon black, the composite showed a synergistic reinforcing effect by the good dispersion and high cross-linking density. In addition, the tensile strength, storage modulus, hardness, swelling and other properties were the best.

Effects of Heating Condition and Additives on Rheology of Squid Meat Paste Products (오징어 연제품의 물성에 미치는 가열조건과 첨가제의 영향)

  • 배태진;김해섭;최옥수
    • Journal of Life Science
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    • v.13 no.4
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    • pp.481-491
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    • 2003
  • A squid meat has not been utilized for gel products because of its lower gel forming ability. The objectives of this study were as followed; 1) the optimum heating condition on squid meat paste products and 2) the optimum added level for jelly strength of squid meat paste products. Optimum heating conditions of squid meat kamaboko were as followed; setting (pre-heating) at 15$^{\circ}C$ or 55$^{\circ}C$ for 2 hours and heating at 90$^{\circ}C$ for 60 minutes. Effect for jelly strength of starch additives wheat starch, potato starch and com starch were examined. The jelly strength of heat induced gels differed from the levels of additives. In case of adding starch, potato starch was resulted in the superior jelly strength than the other starchs, wheat starch and corn starch, at any levels. Optimum concentration was 10%(w/w) at every additives. Folding test value was B at added 10% and this value was mean good product. Data of jumbo and flying squid meat paste products added potato starch, corn starch and wheat starch of 10% were shown below, jelly strengths were 858${\pm}$34∼1020${\pm}$37gㆍcm and 966${\pm}$33∼l148${\pm}$45gㆍcm and moisture contents were 72.43∼73.04% and 71.61∼72.78%, respectively. To adding edible agar and sea tangle, showed the highest jelly strength (edible agar>sea tangle, flying squid>jumbo squid) at added 0.5%(w/w) concentration.

Studies on the Components of Korean Panax Ginseng C.A. Mayer -Part. I On the Content of Starch, Size Frequency Distribution of Starch Granules, Amylose Content and Blue Value- (한국인삼 성분에 관한 연구 -제1보 전분함량, 전분의 입경분포, amylose함량 및 blue value에 대하여-)

  • Kim, Hai-Jung;Nam, Sung-Hi;Kim, Hyong-Soo;Lee, Suk-Kun
    • Korean Journal of Food Science and Technology
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    • v.9 no.1
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    • pp.19-23
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    • 1977
  • The variation of the amount of starch, size and shape of the starch granules, amylose content, and blue value of the starch in the Korean ginseng roots from one year old to five year old cultivated at Kumsan was studied. The results obtained were as follows; 1) The starch content of the ginseng root(dried) was increased with the age of the root; that is, 9.62% for one-year-old roots, 10.35% for two-year-old root, 15.50% for three-year-old root, 17.05% for four-year-old root, and 18.32% for five-year-old root. 2) The shape of the ginseng starch granules was round or short oval, and in the latter case the ratio of minor axis to major axis was 1 to 1.1. Diameter of the starch granules was in the range of $1.48\;{\mu}\;to\;8.14\;{\mu}$ and the most frequent granule size was $3\;{\mu}\;(32.1{\sim}35.7%)$. The number of big size starch granules was increased during the five years of growing, while, the number of small size granules was decreased. 3) The amylose content in the ginseng starch was varied with the age of the root, in the range of $53.6{\sim}70.5%$. 4. The blue value of the ginseng starch was in the range of 0.60 to 0.71.

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Characteristics of non-waxy rice starch/gum mixture gels (멥쌀 전분과 검물질 혼합물 겔의 특성)

  • Shin Malshick;Kwon Ji-Young;Song Ji-Young
    • Korean journal of food and cookery science
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    • v.21 no.6 s.90
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    • pp.942-949
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    • 2005
  • To improve the textural properties and stabilize the structure and gel matrix of non-waxy rice starch gels, non-waxy rice starch/gum mixture gels were prepared from various food gums, gum arabic, guar, algin, deacyl gellan, xanthan and gellan gums. The morphological and textural properties and freeze-thaw stability of their gels were compared. Rice starch/gum mixture gels with various gums formed a more homogeneous gel matrix with smaller particle size than rice starch gel without Em, but the trends differed depending on the gum types. The textural properties of rice starch/gum mixture gels were changed with the gum types. The shape of the rice starch/gum mixture gel matrix was desirable when mixed with gellan and algin. The textural properties of gels hardened in the rice starch/algin mixture gel and softened in the rice starch/algin mixture gel. The rice starch gels showed V-type crystallinity by x-ray diffractometer, but the peak at $2\theta$ = $20^{o}$ was decreased with increasing gum addition. The freeze-thaw stability increased with increasing gum addition. Gellan and algin were especially effective.

Effect of Saccharides on Texture and Retrogradation of Acorn Starch gels (도토리 전분 겔의 텍스쳐와 노화에 미치는 당류의 영향)

  • Lee, Hyang-Aee;Kim, Nam-Hee
    • Korean Journal of Food Science and Technology
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    • v.30 no.4
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    • pp.803-810
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    • 1998
  • The mechanical and thermal properties of solutions of acorn starch were investigated, to determine the effect of sucrose on the retrogradation. The contents of moisture and amylose of purified acorn starch was 9.35, 27% respectively. From the moecular weight distribution, Mw and Mn of acorn starch were 1,220,432 and 137,201 relatively and the polydispersity of acorn starch was 8.8952. The creep compliance of acorn starch with and without sucrose were decreased with increasing sucrose concentration in the short term. The temperatures of DSC curve of 15% acorn starch solution containg sucrose shifted slightly to higher temperatures with increasing sucrose content. The enthalpy change associated with the gelatinization was increased with increasing sucrose content. After 7 days storage, the creep compliance of acorn starch gel with sucrose were shown higher than acorn starch gel. Regelatinization enthalpy of acorn starch/sucrose/water system was decreased with increasing sucrose content and increased with storage time. In addition, the characteristic temperatures such as onset temperature, peak temperature and conclusion temperature was increased by sucrose addition. Retrogradation ratio decreased with increasing sucrose content, thus sucrose inhibit retrogradation in the long term. Sucrose acts as an antistaling reagents and retatards the retrogradation.

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The Effects of Annealing on Resistant Starch Contents of Cross-linked Maize Starches (Annealing 처리가 가교결합 옥수수전분의 저항전분 수율에 미치는 영향)

  • Mun, Sae-Hun;Shin, Mal-Shick
    • Korean Journal of Food Science and Technology
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    • v.34 no.3
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    • pp.431-436
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    • 2002
  • To develop a method for increasing RS level in maize starch, cross-linked resistant starches treated with annealing were prepared. Maize starch and amylomaize VII were used in the study and annealed at $40{\sim}60^{\circ}C$ before cross-linking modification. To compare effect of annealing below gelatinization temperature, starches were heat treated at 70 and $100^{\circ}C$. RS contents were assayed by pancreatin-gravimetric (P/G) method. When maize starch and amylomaize VII were cross-linked at $45^{\circ}C$ and pH 11.0 by slurrying the starch on a solution of STMP(sodium trimetaphosphate), STPP(sodium tripolyphosphate), and sodium sulfate, RS content was 14.7% and 45.3%, respectively. Annealing below gelatinization temperature before cross-linking increased RS contents of prepared cross-linked starches but did not affect the swelling power. Heat treatment above gelatinization temperature increased the swelling power of cross-linked starch prepared from maize starch. The characteristics by X-ray diffractometry and scanning electron microscopy of cross-linked resistant starch were not changed by annealing.

Synthesis of Environmental-Friendly Starch-acrylic Coating Sols by Emulsion Polymerization (유화중합에 의한 친환경 전분-아크릴 코팅졸의 합성)

  • Li, Mei-Chun;Mun, Yoo-Ju;Cho, Ur-Ryong
    • Elastomers and Composites
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    • v.45 no.4
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    • pp.272-279
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    • 2010
  • Starch is an environmental-friendly natural source, more interests are attracted to use starch for synthesis of composites and coating sols. Starch-acrylic coating sols for architectural materials were synthesized by emulsion polymerization. The structures of synthesized materials were characterized by using Infrared spectra, $^1H$-NMR spectra, and physical characteristics were investigated by X-ray diffraction, foaming test, whiteness test, gloss test and tensile strength test. XRD results showed that starch in starch-acrylic copolymer matrix was in an amorphous state. Starch-acrylic emulsion was compounded with 1%, 3%, 5% foaming agent (n-pentane) and 60% $CaCO_3$ solution. The results showed that starch and foaming agent could increase the foamability. Tensile strength increased with the enhancement of starch and foaming agent concentration. But whiteness and gloss decreased with increase of starch and foaming agent concentration.

Comparison of structure and physicochemical properties of commercial domestic and imported wheat starch (시판 우리밀과 수입밀 전분의 구조 및 이화학적 특성 비교)

  • Jeong, Gyeong A;Park, Jinhee;Kim, Kyeong Hoon;Lee, Chang Joo
    • Korean Journal of Food Science and Technology
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    • v.53 no.5
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    • pp.521-526
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    • 2021
  • This study characterized the chemical structure and physical properties of domestic commercial wheat starch and compared them with those of imported commercial wheat starch. Three varieties of domestic commercial wheat starch (DWS) were compared to three types of imported wheat starch (IWS). The morphology of DWS granules was spherical with diameters 17.0-18.3 ㎛; the IWS granules exhibited various diameter sizes (16.6-17.7 ㎛). The amylose content of both DWS and IWS was between 23.2-23.8%. DWS exhibited smaller gelatinization temperature ranges and gelatinization enthalpies compared to IWS. These results suggest that IWS-PW (plain wheat starch) is a mixture of many types of wheat starch. In conclusion, the quality of domestic wheat flour and imported wheat flour was related to gluten content as well as to the starch properties.

Development of Higher Functional Coating Agents for Pulp Mold (III) Manufacture of starch derivatives for coating - (펄프몰드용 새로운 고기능 코팅제 제조기술개발(제3보) -코팅용 전분유도체 제조-)

  • Kang Jin Ha;Lim Hyun A
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.4 s.107
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    • pp.49-59
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    • 2004
  • This study was carried out to obtain the basic data for producing higher functional coating agents for pulp mold by evaluating various kinds of starch derivatives. At that time, four kinds of starch derivatives were manufactured for making coating agents respectively. Physical properties of coated paperboards were tested. Conclusions obtained from this results were as follows. The water and oil resistance of hydroxypropylated, cyanoethylated and carboxymethy­lated starch were high when degree of molar substitution(DS) of propylene oxide, acrylonitrile and sodium monochloroacetate were 0.18, 0.07 and 0.009, respectively. Also, the those of crosslinked starch were high when degree of crosslinking of epichlorohydrin was 0.02. Consequently, $8\%$ solution of carboxymethylated starch made with DS 0.009 of monochloroacetate was the best among coating agents from starch derivatives men­tioned above.

Kinetic Modiling of Cyclodextrin forming Reactionin a Heterogeneous Enzyme Reaction System using Swollen Extrusion Starch (팽윤 Extrusion 전분을 기질로 한 불균일상 효소 반응계에서 Cyclodextrin 생성반응의 수치적 해석)

  • 조명진;박동찬;이용현
    • Microbiology and Biotechnology Letters
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    • v.23 no.4
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    • pp.425-431
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    • 1995
  • A kinetic model of the cyclodextrin formation in a heterogeneous enzyme reaction system using swollen extrusion starch as substrate was derived emphasing the structural features of extrusion starch. The degree of gelatinization, the ratio of accessible and inaccessible portion of extrusion starch, adsorption of CGTase on swollen starch, the structural transformation during reaction, and product inhibition caused by produced CDs were considered in deriving kinetic model. Various kinetic constants were also evaluated. The derived kinetic equation was numerically simulated, which result showed that the derived kinetic equations can be used to predict the experimental data reasonably well under the various experimental conditions. Kinetic model can be utilized for the optimization of enzyme reactor and the process development for CD production from swollen extrusion starch.

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