• Title/Summary/Keyword: SOx Scrubber

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Study on purification and extraction of nitrate salts from waste scrubbing liquid of de-SOx/de-NOx (탈질/탈황 폐 세정액으로부터 질산염 추출 및 정제 연구)

  • Kim, Woo-Ram;Jo, Young-Min;Lee, Heon-Seok;Oh, Soo-Kwan
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.48-55
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    • 2015
  • IMO to issue some restricted maritime legislation for reducing the adverse environmental impacts arising from such ship exhaust emissions. According to the IMO policy, every ship entering the Baltic SECAs has to equip the gas cleaning scrubber. The discharged waste solution by gas cleaning scrubber contains many types of salts, which to recover some valuable materials before disposal. This study try to achieve valuable salts including AN and AS throughout a few process such as selective organic solvents salting out, low temperature extraction and thermal evaporation. Amongst them, Thermal evaporation with repetition extraction using inorganic solvent was the most optimum to purify the extracted AN. This valuable salt was evaluated by Elemental analysis and Differential scanning calorimetry.

Extraction of nitrate salts from de-NOx waste scrubbing solution (탈질 스크러버의 폐세정액으로부터 질산염 추출 연구)

  • Kim, Wooram;Ha, Taeyoung;Park, Yeonsoo;Lee, Hyunsuk;Jo, Youngmin
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.2
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    • pp.210-216
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    • 2017
  • Recovery of low level nitric acid and sulfuric acid ions, which were contained in wastewater of a wet scrubber for de-NOx and de-SOx from ship engines, was attempted as fertilizing materials. This study utilized a selective extraction method using four organic solvents to precipitate the solid salts of ammonium nitrate and ammonium sulfate. The IR analysis showed almost same composition of the extracted ammonium salts with a commercial product, and recovery rate of nitrogen and sulfuric ions was 89% and 80% respectively. It was found that the selectivity and solubility consequently could be the crucial factors to recover the low level ions from the waste scrubbing water.

Numerical Analysis on Energy Consumption of an Exhaust Air Heat Recovery Type Outdoor Air Conditioning System for Semiconductor Manufacturing Clean Rooms (반도체 클린룸용 배기 열회수식 외기공조시스템의 에너지소비 수치해석)

  • Song, Gen-Soo;Yoo, Kyung-Hoon;Kim, Hyoung-Tae
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.1306-1311
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    • 2009
  • In recent semiconductor manufacturing clean rooms, in order to improve clean room air quality, air washers are used to remove airborne gaseous contaminants such as $NH_3$, SOx and organic gases from the outdoor air introduced into clean room. Meanwhile, there is a large amount of exhaust air from a clean room. From an energy conservation point of view, heat recovery is therefore useful for reducing the outdoor air conditioning load for a clean room. Therefore it is desirable to recover heat from the exhaust air and use it to reheat the outdoor air. In the present study, numerical analysis and experiment was conducted to simulate the amount of energy reduction of exhaust air heat recovery type air washer system. The present numerical results showed good agreement with the results of the experimental data.

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Selective Nitrate Removal Performance Analysis of Ion Exchange Resin in Shipboard Waste Washwater by Air Pollution Prevention Facility (선박용 대기오염장치 폐세정수 내 질산염의 선택적 제거를 위한 이온교환수지 공정 성능 평가)

  • Kim, Bong-Chul;Yeo, In-Seol;Park, Chan-Gyu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.4
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    • pp.399-404
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    • 2021
  • From 1 January 2020, the limit for Sulphur in fuel oil used on board ships operating outside designated emission control areas will be reduced to 0.5 %. This regulation by international maritime organization (IMO) is able to significantly reduce the amount of Sulphur oxides (SOx) discharging from ships and should have environmental advantages and health for all over the world. To meet the regulation, in these days, wet scrubber system is being actively developed. However, this process leads to make washing wastewater. In this study, we evaluated ion exchange resin system in accordance with scrubber wastewater discharge regulation by IMO. Theoretical wastewater used as feed solution of lab scale water treatment systems. The results revealed that nitrate ion was removed selectively in spite of high TDS wash wastewater solution depending on ion exchange resin property. Moreover, it was possible to improve efficiency of the system by optimizing operating conditions.

Vitrification of Simulated Combustible Dry Active Wastes in a Pilot Facility

  • Yang, Kyung-Hwa;Park, Seung-Chul;Lee, Kyung-Ho;Hwang, Tae-Won;Maeng, Sung-Jun;Shin, Sang-Woon
    • Nuclear Engineering and Technology
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    • v.33 no.4
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    • pp.355-364
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    • 2001
  • In order to evaluate and finally optimize the vitrification condition for combustible dry active waste (DAW), dust and gas generation characteristics were investigated for PE, cellulose, and mixed waste Tests were conducted by varying the operation variables such as melter configuration, excess oxygen amount, and waste feeding rate. Results showed that dust generation characteristics were affected by the operation parameters and the melter's configuration is the dominant one. For all tested DAWs, dust generation was reduced by increasing the waste feeding rate and the excessive oxygen amount in the melter. Among waste types, dust amount was decreased by the order of mixed wastes, PE, and cellulose. Other parameters such as temperature variation and operation time have also affected the dust generation. The optimum condition for the DAW vitrification was determined as the melter's configuration equipped for minimizing the waste dispersion with 20 kg/h of waste feeding rate and 100% of excessive oxygen supply. CO gas concentration in the off-gas was immediately influenced by the combustion state in the melter, but showed similar trend as the dust generation. For the NOx production during the vitrification process, thermal NOx, which is generated from the Post Combustion Chamber (PCC), rather than fuel NOx was assumed to be dominant. The gas cleaning of efficiencies of the PCC, wet scrubber, and Selective Catalytic Reduction system (SCR) were found to be high enough to keep the concentration of pollutants (CO, NOx, SOx, HCI) in the stack below their relevant emission limits.

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