• 제목/요약/키워드: SMA-based materials

검색결과 35건 처리시간 0.021초

2-(Perfluorooctyl) Ethyl Acrylate (PFOEA) 및 m-Isopropenyl-α, α-Dimethylbenzyl Isocyanate (TMI)가 함유된 발수체 합성 및 특성연구 (Synthesis and Characterization of Water Repellent Materials Containing 2-(Perfluorooctyl) Ethyl Acrylate and m-Isopropenyl-α, α-Dimethylbenzyl Isocyanate)

  • 강영택;곽은미;정일두
    • 접착 및 계면
    • /
    • 제15권4호
    • /
    • pp.151-160
    • /
    • 2014
  • 이상적인 내발수 특성을 얻기 위해 유화중합을 이용하여 n-methyol acrylamide (n-MAM)와 stearyl methacrylate (SMA)의 단량체에 기능성 단량체인 PFOEA의 함량(0-8 wt%)에 따른 공중합체를 합성하였고, 추가적으로 2-(perfluorooctyl) ethyl acrylate (PFOEA) 함량이 4 wt%인 조성에 m-isopropenyl-${\alpha}$,${\alpha}^{\prime}$-dimethylbenzyl isocyanate (TMI)의 함량(1~4 wt%)을 첨가한 공중합체를 합성하였다. 유화중합을 위해 비이온 유화제인 tridecyl alcohol (TDA-7), 양이온유화제인 alkyl dimethyl amine derivatives(ADAD)를 사용하였고 개시제로는 2,2'-azobis (2-amidinopropane dihydrochoride) (AAPDL)을 사용하였다. 합성된 공중합체에 대해서 FT-IR spectra를 이용하여 구조분석을 하였고 표면특성 분석을 위해 접촉각, 표면에너지, 발수도 그리고 SEM을 측정하였으며, TGA와 DSC를 사용하여 열적 특성을 확인하였다. PFOEA와 TMI의 특정 함량에서 우수한 발수도와 높은 열적 특성을 보이는 공중합체가 합성됨을 알 수 있었다.

Seismic behavior of steel column-base-connection equipped by NiTi shape memory alloy

  • Jamalpour, Reza;Nekooei, Masoud;Moghadam, Abdolreza Sarvghad
    • Structural Engineering and Mechanics
    • /
    • 제64권1호
    • /
    • pp.109-120
    • /
    • 2017
  • The behavior of moment resistant steel structures depends on both the beam-column connections and columns foundations connections. Obviously, if the connections can meet the adequate ductility and resistance against lateral loads, the seismic capacity of these structures will be linked practically to the performance of these connections. The shape memory alloys (SMAs) have been most recently used as a means of energy dissipation in buildings. The main approach adopted by researchers in the use of such alloys is firstly bracing, and secondly connecting the beams to columns. Additionally, the behavior of these alloys is modeled in software applications rarely involving equivalent torsional springs and column-foundation connections. This paper attempts to introduce the shape memory alloys and their applications in steel structural connections, proposing a new steel column-foundation connection, not merely a theoretical model but practically a realistic and applicable model in structures. Moreover, it entails the same functionality as macro modeling software based on real behavior, which can use different materials to establish a connection between the columns and foundations. In this paper, the suggested steel column-foundation connection was introduced. Moreover, exploring the seismic dynamic behavior under cyclic loading protocols and the famous earthquake records with different materials such as steel and interconnection equipment by superelastic shape memory alloys have been investigated. Then, the results were compared to demonstrate that such connections are ideal against the seismic behavior and energy dissipation.

Nonlinear earthquake capacity of slender old masonry structures prestressed with steel, FRP and NiTi SMA tendons

  • Preciado, Adolfo;Ramirez-Gaytan, Alejandro;Gutierrez, Nayar;Vargas, David;Falcon, Jose Manuel;Ochoa, Gil
    • Steel and Composite Structures
    • /
    • 제26권2호
    • /
    • pp.213-226
    • /
    • 2018
  • This paper focuses on the seismic protection of slender old masonry structures by the implementation of prestressing devices at key locations. The devices are vertically and externally located inside the towers in order to be reversible and calibrated. An extensive parametric study on a selected slender tower is carried out based on more than 100 nonlinear static simulations aimed at investigating the impact of different parameters on the seismic performance: (i) different prestressing levels; (ii) shape memory alloy superelasticity and (iii) changes in prestressing-forces in all the stages of the analysis until failure and masonry toe crushing. The tendon materials under analysis are conventional prestressing steel, fiber-reinforced polymers of different fibers and shape memory alloys. The parametric study serves to select the most suitable prestressing device and optimal prestressing level able to dissipate more earthquake energy. The seismic energy dissipation is evaluated by comparing the structural capacity curves in original state and retrofitted.

Fe-X%Mn-5Cr-5Co-4Si 합금 리본의 변태특성 및 형상기억능에 미치는 열처리 영향 (Influence of Heat Treatment on Transformation Characteristics and Shape Recovery in Fe-X%/Mn-5Cr-5Co-4Si Alloy Ribbons)

  • 강후원;지광구;장우양;강조원
    • 열처리공학회지
    • /
    • 제14권3호
    • /
    • pp.160-166
    • /
    • 2001
  • The change of ribbon geometry, microstructure and shape recovery with Mn contents, wheel speed and various annealing temperature have been studied in Fe-X%Mn-5Cr-5Co-4Si (X%=15, 20, 24) shape memory alloy (SMA) ribbons rapidly solidfied by single roll chill-block melt-spinning process. The thickness and width of melt-spun ribbons are reduced, results in refining and uniformalizing grains with increasing wheel speed. In the ribbons melt-spun at a wheel speed of 15m/sec, both ${\varepsilon}$ and ${\alpha}^{\prime}$martensites are formed in ribbon 1 (15.5wt%Mn), while only ${\varepsilon}$ martensite is revealed in ribbon 2 (20.2wt%Mn) and ribbon 3 (23.5wt%Mn). The volume fraction of ${\varepsilon}$ martensite is decreased with increasing Mn contents, and those of ${\varepsilon}$ as well ${\alpha}^{\prime}$martensites are increased due to thermal stress relief and grain growth with increasing annealing temperature. Ms temperatures of the ribbons 1, 2 and 3 are fallen with increasing Mn contents. $M_s$ temperatures of the ribbons 1, 2 and 3 annealed at $300^{\circ}C$ for 3 min are risen abruptly, but are nearly constant even at higher annealing temperature, i.e., 400, 500 and $600^{\circ}C$ for 3 min. Shape recovery of the ribbons 1, 2 and 3 increased 30%, 52% and 69% with Mn contents, respectively. Shape recovery of ribbon 1 (15.5wt%Mn) formed ${\varepsilon}$ and ${\alpha}^{\prime}$martensites decreased because of the presence of ${\alpha}^{\prime}$martensite but those of ribbon 2 (20.2wt%Mn) and ribbon 3 (23.5wt%Mn) formed ${\varepsilon}$ martensite increased with increasing annealing temperature.

  • PDF

아스팔트 바인더의 노화특성을 고려한 동탄성계수 평가 (Evaluation of Dynamic Modulus based on Aged Asphalt Binder)

  • 이관호;조경래;이병식;송용선
    • 한국방재학회 논문집
    • /
    • 제8권3호
    • /
    • pp.51-58
    • /
    • 2008
  • 최근 국내외에서 도로포장설계법에 경험적/역학적 개념을 적용한 설계법의 개발 및 이의 활용을 위한 연구가 매우 활발하게 진행 중에 있다. 미국의 경우 AASHTO 2002 설계법, 우리나라의 경우 한국형 도로포장설계법의 개발이 진행 중에 있고, 개발되는 설계법에 도로포장재료의 역학적 물성치 평가가 상당히 중요한 역할을 하게 구성되어 있다. 따라서 설계법에 이용될 국내 아스팔트 혼합물의 재료물성의 평가가 매우 시급한 실정이다. 이 재료의 물성치를 평가하는 방법 중 최근에 많이 적용되는 방법이 동탄성계수시험이다. 본 연구에서는 아스팔트 포장체의 시간에 따른 노화특성을 고려한 아스팔트 포장체의 동탄성계수를 평가하였고, 이를 이용하여 동탄성계수 예측방정식을 제안하였다. 시험에 이용된 아스팔트 혼합물은 KS 표준규격에 사용되는 9종(SMA 및 SBS 포함)과 3종류의 아스팔트 바인더를 이용하였다. 보통 공장에서 배합, 생산되어 현장으로 이동하고 다짐이 완료되기까지 걸리는 시간을 고려하면 단기노화조건은 $135^{\circ}C$ 4시간이 적절할 것으로 판단되며, 공정이 빠르고 관리가 잘되는 조건을 반영 한다면 $135^{\circ}C$ 2시간이 적절할 것이다. 장기노화 시험은 공용단계의 아스팔트 바인더의 노화를 시험하였다. 전체적으로 노화가 진행되면서 동탄성계수가 높아짐을 알 수 있다. 최대입경이 클수록 그 정도는 작아지는데 그 이유는 아스팔트 바인더의 효과 보다 골재의 효과가 그 비중이 증가함에 따른 것이다.