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Rheological behavior and wall slip of dilute and semidilute CPyCl/NaSal surfactant solutions

  • Kibum Sung;Han, Min-Soo;Kim, Chongyoup
    • Korea-Australia Rheology Journal
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    • v.15 no.3
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    • pp.151-156
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    • 2003
  • In this research, experimental studies were performed to examine the rheological behavior of equimolar solutions of cetylpyridinium chloride (CPyCl) and sodium salicylate (NaSal) solutions with concentration. The surfactant solutions were prepared by dissolving 2 mM/2 mM - 80 mM/80 mM of surfactant/counterion in double-distilled water. It has been observed that the zero shear viscosity shows abrupt changes at two critical values of C^*$ and C^{**}$. These changes are caused by the switching of relaxation mechanism with concentration of CPyCl/NaSal solutions at those concentrations. The wall slip velocities of dilute and semidilute CPyCl/NaSal solutions show a dramatic increase with shear rate where the shear viscosity exhibits shear thickening behavior for dilute solutions and shear thinning behavior for semi-dilute solutions, respectively. Considering that the dramatic increase in wall slip velocity should be related to the formation of shear-induced structure (SIS) in the surfactant solution, the shear thickening behavior of semi-dilute solutions is caused by elastic instability unlike the case of dilute solutions.

(TlPbBi)-(SrBa)-Ca-Cu-O superconducting films obtained by electrodeposition process

  • 백상민;이준호;김봉준;박기곤;김영철;정대영;심윤보
    • Progress in Superconductivity
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    • v.4 no.2
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    • pp.157-161
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    • 2003
  • We have performed the electrochemical method to fabricate high temperature superconducting (TlPbBi) -(SrBa)-Ca-Cu-O films. The precursors of the superconducting sample were codeposited at a periodic pulsed-potential cycle (1 second at -4V and 1 second at -1V) on a silver substrate. The variation of structure, microstructure and element were analysed by ICP and SEM techniques. The specimens were consisted predominantly of the Tl-1212 phase and have a transition temperature of 80~87 K in low magnetic field. It was showed that each grain has the stoichiometric ratio of $T1_{0.7}$Pb_$Bi_{0.3}$ $_Sr{0.1}$ $Ba_{2.4}$ $Ca_{0.2}$ $Cu_{1.2}$ $2.5/O_{x}$ by EDX analysis.sis.

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Mechanical Reliability(Life-time) Estimation for 25.8kV Solid Insulated Switchgear (25.8kV 고체절연차단기(Solid Insulated Switchgear)에 대한 기계적 신뢰성(수명) 평가)

  • Lee, Do-Hoon;Kang, Won-Jong;Lee, Seog-Won;Shin, Chul-Ho;Kim, Young-Geun;Lee, Kyu-Chul;Lee, Seung-Yeup;Kim, Ho-Keun
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.2007_2008
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    • 2009
  • 본 논문은 $SF_6$ 가스졀연차단기를 대체할 고체절연차단기(Solid Insulated Switchgear:SIS)의 기계적 신뢰성 평가에 대한 연구 결과이다. 최근 제정된 "25.8kV 가스 및 고체절연 친환경 개폐장치" 한전 구매규격에는 "Epoxy 고체절연물에 대한 기계적 신뢰성(수명)이 25년 이상"임을 보증할 수 있는 신뢰성 데이터를 제출해야 한다는 조항이 포함되어있다. 이에 개발된 고제절연차단기의 Epoxy 고체절연물에 대한 기계적 신뢰성(수명)이 25년 이상임을 보증할 수 있는 신뢰성 시험과 분석 기법에 대한 연구가 진행되었다.

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A study on the typology of the medical claims review in terms of hospital department (진료과목 관련성을 중심으로 분석한 의학적클레임검토 유형론에 관한 연구)

  • Lee, Sin-Hyung
    • The Journal of the Korean life insurance medical association
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    • v.27 no.1
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    • pp.33-36
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    • 2008
  • BACKGROUND : The medical claims review(MCR) is unique methodology of medical consultation in terms of insurance claim administration in Korean insurance market. The most important practical matter in the MCR is formatted question. In Korea, medical specialty is composed of 26 legally defined hospital departments. It is worth of studying to investigate type of MCR by hospital departments. METHODS : Fifty Cases of the MCR were selected randomly by statistical program SPSS among 1,032 cases which were performed between April 1, 2006 and March 31 2007. All of selected cases were evaluated one insurance doctor and made a score points from 0 to 10 in terms of hospital department. RESULTS : Multidimensional scaling was performed. The MCR types - diagnosis, malignancy and cause of death are located in the same 2-dimensional configuration area. It can be called as verification of benefit. Others are advice. - such as causality, interpretation, translation, independent medical examination, and so on. DISCUSSION : We can conclude the classification of MCR typology are two main subjects, verification and advice. Theses results are same as previous article which was based on experience.

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Development of Transdermal Drug Delivery System for the Combination of Physostigmine and Procyclidine

  • Park, Soon-Cheol;Choi, Hoo-Kyun
    • Journal of Pharmaceutical Investigation
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    • v.31 no.3
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    • pp.181-184
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    • 2001
  • The purpose of this study was to develop transdermal drug delivery system (TDDS) for the combination of physostigmine and procyclidine. The effects of various pressure sensitive adhesives (PSA) on the percutaneous absorption of procyclidine across hairless mouse skin were evaluated to select an appropriate PSA. In addition, the influences of various vehicles on the percutaneous absorption of procyclidine from PSA matrix across hairless mouse skin were evaluated using flow-through diffusion cell system at $37^{\circ}C$. Physostigmine did not have any influence on the permeation rate of procyclidine. The flux of procyclidine was the highest in silicone and PIB and was relatively lower in SIS, Acryl, and SBS adhesive matrices, however, their use was limited by the crystallization of the drug in the matrix. Among acrylic adhesives, the permeability of procyclidine was the highest from poly (ethylene oxide) grafted acrylic adhesive. Some enhancers show different enhancing effect depending on the drug, however, many of the tested enhancers showed enhancing effect for the permeation of both procyclidine and physostigmine to some extent. $Crovol^{\circledR}$ EP 40 showed the highest enhancing effect on the permeation of both compounds. The size of TDDS to provide required permeation rate was estimated to be $35\;cm^2$ based on available information.

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Advanced Design Environmental With Adaptive And Knowledge-Based Finite Elements

  • Haghighi, Kamyar;Jang, Eun
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1993.10a
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    • pp.1222-1229
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    • 1993
  • An advanced design environment , which is based on adaptive and knowledge -based finite elements (INTELMESH), has been developed. Unlike other approaches, INTEMMESH incorporates the information about the object geometry as well as the boundary and loading conditions to generate an ${\alpha}$-priori finite element mesh which is more refined around the critical regions of the problem domain. INTEMMESH is designed for planar domains and axisymmetric 3-D structures of elasticity and heat transfer subjected to mechanical and thermal loading . It intelligently identifies the critical regions/points in the problem domain and utilize the new concepts of substructuring and wave propagation to choose the proper mesh size for them. INTEMMESH generates well-shaped triangular elements by applying trangulartion and Laplacian smoothing procedures. The adaptive analysis involves the intial finite elements analyze and an efficient ${\alpha}$-posteriori error analysis involves the initial finite element anal sis and an efficient ${\alpha}$-posteriori error analysis and estimation . Once a problem is defined , the system automatically builds a finite element model and analyzes the problem though automatic iterative process until the error reaches a desired level. It has been shown that the proposed approach which initiates the process with an ${\alpha}$-priori, and near optimum mesh of the object , converges to the desired accuracy in less time and at less cost. Such an advanced design/analysis environment will provide the capability for rapid product development and reducing the design cycle time and cost.

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Development and experimental study on cable-sliding modular expansion joints

  • Gao, Kang;Yuan, Wan C.;Dang, Xin Z.
    • Structural Engineering and Mechanics
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    • v.61 no.6
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    • pp.795-806
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    • 2017
  • According to the characteristics of continuous beam bridges, the relative displacement is too large to collision or even girder falling under earthquakes. A device named Cable-sliding Modular Expansion Joints(CMEJs) that can control the relative displacement and avoid collision under different ground motions is proposed. Working principle and mechanical model is described. This paper design the CMEJs, establish the restoring force model, verify the force model of this device by the pseudo-static tests, and describe and analyze results of the tests, and then based on a triple continuous beam bridge that has different heights of piers, a 3D model with or without CMEJs were established under Conventional System (CS) and Seismic Isolation System (SIS). The results show that this device can control the relative displacement and avoid collisions. The combination of isolation technology and CMEJs can be more effective to achieve both functions, but it need to take measures to prevent girder falling due to the displacement between pier and beam under large earthquakes.

A Study for Strategic Congruence Effects of Information System Technology Structure (정보시스템기술 구조의 전략 적합성 효과에 관한 연구)

  • Chung, Lak-Chae
    • The Journal of the Korea Contents Association
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    • v.4 no.1
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    • pp.40-48
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    • 2004
  • In a study involving 52 large organizations in the savings institutions industry, the relationship between information systems technology(IT) structure and competitive strategy was investigated based on structural contingency theory. Two dimensions of IT structure and two types of competitive strategy were employed to test a contingency mood. It was found that enhanced congruence between IT structure and competitive strategy was associated with higher competitive advantage. The structural dimension significantly associated with the "defender" strategic stance was more centralized and more integrated application of IT, while the structural dimension significantly associated with "prospector〃 positioning was more decentralized and less integrated application of IT.lication of IT.

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Enantioselective Pharmacokinetics of Carvedilol in Human Volunteers

  • Phuong, Nuyen-Thi;Lee, Beam-Jin;Choi, Jung-Kap;Kang, Jong-Seong;Kwon, Kwang-il
    • Archives of Pharmacal Research
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    • v.27 no.9
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    • pp.973-977
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    • 2004
  • Carvedilol is administered as a racemic mixture of the R(+)- and S(-)-enantiomers, although they exhibit different pharmacological effects. To investigate the stereoselective pharmacoki-netics, the enantiomeric separation of carvedilol in human plasma was undertaken using capil-lary electrophoresis (CE). Resolution of the enantiomers was achieved using 2-hydoxypropyl-$\beta$-cyclodextrin as the chiral selector. Phosphate buffer (50 mM, pH 4.0) containing 10 mM of 2-hydoxypropropyl-$\beta$-cyclodextrin was used as electrolytic buffer. Achiral separation was carried out with the same electrolytic buffer without chiral selector. Following a single oral administra-tion of 25-mg carvedilol to 11 healthy, male volunteers, stereoselective pharmacokinetic analy-sis was undertaken. The maximum plasma concentrations ( $C_{max}$) were 48.9 and 21.6 ng/mL for (R)-carvedilol and (S)-carvedilol, respectively, determined by the chiral method. The profiles of the plasma concentration of (RS)-carvedilol showed $C_{max}$ of 71.5, 72.2, and 73.5 ng/mL, as determined by the CE, HPLC/FD methods and calculations from the data of the chiral method, respectively.y.y.

AC susceptibility of the $high-T_c$ superconductor $SmBa_2Cu_2O_y$ (고온초전도체 $SmBa_2Cu_2O_y$ 교류자화율)

  • Kim H;Lee B. Y;Lee J. H;Kim Y. C
    • Progress in Superconductivity
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    • v.6 no.1
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    • pp.89-94
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    • 2004
  • The policrystalline$SmBa_2$$Cu_2$$O_{y}$ was synthesized by the solid state reaction method. The dependence of AC susceptibility on temperature and applied ac field was studied. The critical temperature $T_{c}$ is about 92 K. As the ac field is increased, the slope and the value of real part of susceptibility become smaller and the peak position of imaginary part $T_{P}$ was shifted to a lower temperature with peak broadening. Using Bean's model, we determined intergrain critical current density $J_{c}$ and obtained $44 A/{cm}^2$ at 75 K. From the relation of the $J_{c}$ (T)=($1-T/T_{c}$ )$^{\beta}$ we obtained $\beta$=0.8 and found that the Josephson junction type of the $SmBa_2$$Cu_2$$O_{y}$ is SIS junction. The peak of the imaginary part shifts to higher temperature with increasing frequency, f. from Arrhenius plot, we obtained the activation energy of about 0.96 eV.

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