• 한국농림기상학회지
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• 제22권3호
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• pp.171-175
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• 2020

대기오염의 사회경제적 효과에 대한 연구에는 측정된 대기오염 물질, 기상 자료, 그리고 사회경제적 데이터의 병합이 필요하다. 이들 자료들의 시간적·공간적 범위와 단위가 상이하기 때문에 분석에 필요한 데이터 가공에 많은 시간과 노력이 요구된다. 본 데이터의 구축은 사회과학 분야에서 널리 사용되는 대표적인 대기오염 및 기상 변수를 시군구 단위로 제공하는 것을 목표로 한다. 2020년 8월 기준 배포 버전 데이터의 시간적 범위는 2001년부터 2018년이며, 공간적 범위는 250개 시군구로서 패널 형태의 자료를 제공한다. 본 데이터의 기상 변수들은 대기오염 관련 분석뿐만 아니라 다양한 사회과학의 연구에서 사용할 수 있는 주요 변수들을 포함하고 있다.

• 폴리머
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• 제38권5호
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• pp.602-612
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• 2014

폴리(디메틸 실록산)(PDMS) 성분을 포함하는 폴리우레탄(PU-Si)을 합성하고 이들의 열적 특성과 형상기억 특성을 분석하였다. 이를 위하여 메틸렌디페닐 디이소시아네이트와 1,4-부탄디올을 하드세그먼트(HS) 성분으로 하고, 소프트세그먼트(SS) 성분으로 PDMS 디올과 폴리(테트라메틸렌 에테르 글리콜)(PTMEG) 혼합폴리올을 사용하여 HS 함량이 각각 23%와 32%이면서 PDMS 함량이 다른 PU-Si를 용액중합법으로 합성하였다. HS 함량이 23%인 PU-Si의 경우 PDMS 함량 증가에 따라 SS의 냉결정화온도($T_{cc}$)와 용융결정화온도는 증가하였으나 용융온도($T_m$)에는 변화가 없었다. HS 함량이 32%인 시료들의 경우 PTMEG의 $T_m$이 HS 함량 23%인 시료들보다 약간 높은 온도에서 나타났으며 $T_{cc}$는 관찰되지 않았다. PDMS 성분이 포함된 PU-Si 필름들은 PU에 비해 형태고정성은 약간 좋지 않지만 형상기억 효과는 더 우수하였다.

• Bulletin of the Korean Chemical Society
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• 제19권3호
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• pp.328-332
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• 1998

Anionic ring-opening polymerization of 3,4-[(dimethylsilyl)isopropyl]benzo-1,1-dimethyl-1-silacyclopentene in the presence of n-butyllithium and HMPA in THF at - 78 ℃ afforded poly[3,4-(dimethylsilylisopropyl)benzo-1,1-dimethyl-1-silapentene]. The characteristic Si-H stretching frequency in the IR is observed at 2100 cm-1. The polycarbosilane has been modified by chloroplatinic acid catalyzed addition of styrene to the polycarbosilane SiH units. Molecular weights and thermal properties of the polymers were compared. The sol-gel polymerization of 3,4-[(dimethoxysilyl)isopropyl]benzo-1,1-dimethoxy-1-silacyclopentene in the presence of aqueous HCl or NaOH in THF resulted in a cross-linked polysiloxane. The xerogel has a low surface area of 13-14 m2/g and is stable up to about 400 ℃ with only 5% weight loss under a nitrogen atmosphere.

• 한국산학기술학회논문지
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• 제3권2호
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• pp.74-79
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• 2002

80년대 반도체 산업의 급격한 성장으로 오늘날 반도체 산업은 반도체소자의 초고집접화, 웨이퍼의 대구경화로 발전이 거듭났으며, 소자의 성능과 생산 수율의 향상을 위하여 실리콘 웨이퍼의 세정하는 기술 및 연구를 계속 진행하고 있다. 기존의 반도체 세정은 과다한 화학약품의 사용으로 비 환경친화적이며, 이에 본 연구에서는 기존의 세정방법을 대체하기 위한 방법으로 환경친화적인 전리수를 이용한 반도체 세정법을 하였다. 이때 실리콘 웨이퍼 표면의 원자적 상태의 변화가 발생하여 다양한 방법으로 확인할 수 있다. 본 연구에 서는 이러한 분석을 하기 위하여 기존세정의 화학약품과 전리수로 세정한 웨이퍼의 표면을 비교하였으며, 또한 온도 및 시간별 표면상태변화를 분석하였다. 특히 접촉각 변하에 중점을 두어 변화를 관찰하였으며, 음극수의 경우 17.28°, 양극수의 경우 34.1°의 낮은 접촉각을 얻을 수 있었다.

• Macromolecular Research
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• 제12권1호
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• pp.22-25
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• 2004

We have synthesized aniline oligomer composites by using heteropoly acid (H$_4$SiW$_{12}$O$_{40}$ ) as a dopant. The doping and dedoping processes of the aniline oligomer composites were investigated with the aid of UV- Vis spectra. The bands of the aniline oligomer at 572 nm weakened or disappeared, and the bands at 268, 412, and 771 nm appeared, after the aniline oligomer was doped. When the solution of the aniline oligomer doped with H$_4$SiW$_{12}$O$_{40}$ was kept at lower values of pH, the aniline oligomer could not be dedoped by dilution. The turning point of doping and dedoping occurred at pH 5.5. The band at 771 nm shifted towards longer wavelengths when the aniline oligomer composites were synthesized using acetone as the solvent. This observation indicates that the molecular chain became stretched. In addition, we also investigated the change of the electronic absorption spectra of the composites with respect to the time laid up.id up.

• Environmental Engineering Research
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• 제19권3호
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• pp.205-214
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• 2014

Petroleum a vital commodity affecting every aspect of 21st century. Toxicity and adverse effects of sulphur as catalyst in petroleum products is of great concern required development of techniques for desulphurization in compliance with the International standards. Installation of desulphurizing units costs over $200 million per unit placing economic burden on developing countries like Pakistan. Present study analysis of commercial fuels (station petrol and jet fuel JP8) on gas chromatography-mass spectrometry (GC-MS) identified sulphur concentration of 19.94 mg/L and 21.75 mg/L, respectively. This scenario urged the researcher to attempt synthesis of material that is likely to offer good adsorption capacity for sulphur. Following protocol of sol-gel method, transition metals (Ni, Cu, Zn) solution is gelated with tetraethoxysilane (TEOS; silica precursor) using glycerol. Fourier transform infrared spectroscopy (FTIR) spectra revealed bonding of Zn-O, Cu-O, and Ni-O by stretching vibrations at $468cm^{-1}$, $617cm^{-1}$, and $468cm^{-1}$, respectively. Thiophene and Benzothiophene mixed in n-heptane and benzene (4:1) for preparation of Model Fuels I and II, respectively. Each of silica based metal was applied as adsorbent in batch mode to assess the removal efficiency. Results demonstrated optimal desulphurization of more than 90% following efficacy order as Si-Ni > Si-Zn > Si-Cu based adsorbents. Proposed multilayered (Freundlich) adsorption mechanism follows ${\pi}$-complexation with pseudo secnd order kinetics.

• 한국HCI학회:학술대회논문집
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• 한국HCI학회 2009년도 학술대회
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• pp.94-98
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• 2009

메이저리그 야구 중계 등 해외 스포츠 중계제작에서 해결해야 할 문제 중 하나는 MPH(miles per hour)와 같이 영미식 단위로 표시된 자막을 국내 실정에 맞게 km/h 등으로 변환하는 것이다. 이를 위해 중계화면에 표시된 자막영역의 변화로부터 해당 자막이 표시되었음을 감지하고 숫자 정보를 인식하여 이를 국내실정에 맞는 SI 단위로 변환하는 스포츠 자막 인식 시스템을 개발하였다. 변환된 자막은 후단의 문자발생기 (CG) 시스템으로 전달되어 최종적으로 TV 화면에 표시된다. 일반적으로 문자 인식에 주로 사용되는 신경망(neural networks) 기반 방식은 사전에 유사 데이터를 이용한 신경망의 학습(training) 과정이 필수적으로 요구되며, 또한 학습에 사용된 데이터와 다른 모양의 자막이 예고 없이 사용되었을 경우 대처할 수 없다는 단점이 있다. 생방송이라는 사용 환경을 고려하여 새로운 폰트로 제작된 자막에도 신속하게 대처할 수 있는 템플릿 매칭(template matching) 방식을 사용하였다. 여러 가지 실험 영상으로 테스트한 결과 97% 이상의 정확한 인식 결과를 얻었으며, 정확성을 요하는 생방송의 특성상 매칭의 확신도(confidence)가 높지 않은 경우에는 작업자가 판단한 후 핫키를 이용하여 정확한 자막을 출력할 수 있게 하였다.

• 분석과학
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• 제30권5호
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• pp.226-233
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• 2017

In general, quantitative chemical analysis in various areas including food, the environment, in vitro diagnostics, etc., requires traceability in order to increase the reliability of the measurements. Measurement traceability is a property of an unbroken chain of comparisons relating an instrument's measurements to SI units. Purity analysis is the first process for establishing traceability to SI units in chemical measurements. The purpose of this study is to develop and validate a method of purity assignment for establishing the traceability of $17{\beta}$-estradiol measurements in an in vitro diagnostics field. The establishment of this method is very important as it can be applied to the development of CRM and to the analysis of the purity of other hormones. The method of assignment of the purity of $17{\beta}$-estradiol was developed using the mass balance method and was validated through participation in an International comparison. In the mass balance method, impurities are categorized into four classes as follows: total related structure impurities, water, residual organic solvents, and nonvolatiles/inorganics. In this study, total related structure impurities were characterized by a gas chromatography-flame ionization detector (GC-FID) and a high-performance liquid chromatography-ultraviolet (HPLC-UV) detector, water content was determined by a Karl-Fisher coulometer, and total residual solvents and nonvolatiles/inorganics were checked simultaneously by thermogravimetric analysis (TGA). The purity of the $17{\beta}$-estradiol was 985.6 mg/g and the expanded uncertainty was 2.1 mg/g at 95% confidence. The developed method can be applied to the development of certified reference materials, which play a critical role in traceability.

• 한국환경과학회지
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• 제25권10호
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• pp.1381-1387
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• 2016

This study aims to establish baseline data for sustainable monitoring by applying the green city index (GCI), which is set up to evaluate the city level, to the city of Gangneung-si, which was designated as a pilot city for the Low-carbon Green Growth City project by the Ministry of Land, Infrastructure, and Transportation. The GCI was applied in the framework of European systems, while considering the social and economic status of Korea. Indicators from 7 areas-$CO_2$, energy, building, transportation, water, waste, and quality of atmosphere were analyzed, except for qualitative indicators. Results indicate that total $CO_2$ emissions were 30.8 tons per capita, or 2.2 tons per one million units of real GDP. The total final energy consumption was 0.231 TOE/capita, or 0.317 TOE per one million units of real GDP. The percentage of total energy derived from renewable resources was 0.41% and energy consumption by the building was $433.5Mwh/1,000m^2$. The total percentage of the working population travelling to work daily by public transportation (limited to bus) was 19%. Further, the total annual water consumption was $99m^3/capita$, and the water lost in the water distribution system was $0.057m^3/capita/day$. The total annual waste collected was 0.0077 ton per capita, The annual mean emission were 0.014 ppm/day for $NO_2$, 0.005 ppm/day for $SO_2$, and 0.019 ppm/day for $O_3$. The annual mean for PM10 emissions was $39{\mu}g/m^3/day$.

• 한국환경복원기술학회지
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• 제22권2호
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• pp.73-92
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• 2019

The purpose of this study is to establish the conservation and restoration areas for sustainable stream management by reflecting the ecological health, cultural characteristics, and the citizens' needs for stream uses. Therefore, we extended spatial ranges of stream evaluation to riparian areas in addition to stream sections. The evaluation indexes are stream naturalness, availability, biota assessment, and riparian characteristics such as land uses and legally protected areas. The grading system was unified with five classes. The spatial evaluation units for stream section are classified as right and left for laterally and 500m for longitudinally. For riparian areas, 30m and 100m of distance from the edge of stream are applied as spatial evaluation units. The six types of stream sections for management are conservation sections(priority/general) and restoration sections(priority/general) for ecological landscape and core and general sections for cultural landscape. The established system for evaluation and designating areas for stream management was applied to Jeonjucheon and Samcheon in Jeonju-si, and the conservation and restoration areas were designated reflecting the characteristics of urban and non-urban areas and left and right of stream sections. The results of this study will provide detailed guidelines for designating stream sections and practical management strategies for sustainable urban stream management.