• Composites Research
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• v.33 no.5
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• pp.256-261
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• 2020

In this study, the ignition temperature of the Al-Ti-C reaction system, the microstructure and the mechanical properties of the TiC/Mg composite which produced by the self-propagating high-temperature synthesis (SHS) followed by stir casting process were investigated. Mg based composite with uniformly dispersed 0, 10, 20, and 30 vol.% TiC were fabricated, and higher volume fraction of TiC reinforced composite showed superior compressive strength and wear resistance as compared with Mg matrix. It is attributed to the less contamination, defects, impurities in TiC/Mg composite by the in-situ SHS yield effective load transfer from the matrix to the reinforcement.

• Cement
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• s.119
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• pp.7-13
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• 1990

• Journal of the Korean Ceramic Society
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• v.31 no.5
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• pp.552-560
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• 1994

A composite of TiB2-Al2O3 system was successfully prepared from a mixture of TiO2, B2O3, and Al by self-propagating high temperature synthesis (SHS) with a novel characteristic, utilizing the internal oxidation heat of aluminium metal of the mixture, instead of by a conventional technique, externally heating a mixture of Ti, B and Al2O3. From a mixture with B/Ti molar ratio of =2.0, pure two phases of TiB2 and $\alpha$-Al2O3 with good crystallinity and small, uniform sizes were formed. However, when the B/Ti molar ratio of the mixture goes to a value less than 2.0, in addition to the above main minerals, a small smounts of metastable phases such as TiB and Ti3B4 were formed. It was found that about 60%, the optimum green density of compacts gave their highest reaction rate and temperature during SHS process. TiB2-Al2O3 system composite with B/Ti molar ratio of =2.0 could be pressurelessly sintered even at 190$0^{\circ}C$ under Ar gas flows without any addition of sintering aids, showing their good properties such as 91.2% in relative density, 2750 kgf/$\textrm{mm}^2$ in Vickers hardness and 2620 kgf/$\textrm{cm}^2$ in flexural strength.

• Journal of the Korean Ceramic Society
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• v.29 no.3
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• pp.202-210
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• 1992

• Journal of the Korean Ceramic Society
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• v.31 no.3
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• pp.265-274
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• 1994

Intermetallic Ti-Si system ceramics were synthesized from stochiometric mixtures of titanium and silicone powders in vacuum by Self-propagating High-temperature Synthesis(SHS). In each cases of Ti5Si3, Ti5Si4 and TiSi, and TiSi2 synthesis, 20wt% product dilution, direct ignition and SHS chemical furnace method were employed. The combustion modes, which were observed during the synthesis process by using the high speed camera, of Ti5Si3, Ti5Si4, TiSi, and TiSi2 exhibit spin, osciallatory, steady-state, and spin combustion, respectively. With increasing Ti/Si molar ratio an decrease of combustion velocities was found. From the results on the measurement of the flexural strength, the specimen hot pressed at 135$0^{\circ}C$ for 30 min using synthesized Ti5Si4 powders showed the highest flexural strength at 215 MPa.

• Journal of the Korean Ceramic Society
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• v.32 no.4
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• pp.413-418
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• 1995

The (B.Si)C composite was prepared form the mixture of metal boron, silicon, and carbon powders in Ar atmosphere by Self-propagating High-temperature Synthesis Chemical Furnace. The characterization of synthesized power and sintered body were investigated. The microstructure of sintered body suggested that SiC boundary was made between B4C grains. The most excellent mechanical properties, the relative density of 95% oftheoretical value, 3 point flexural strength of 360MPa, and fracture toughness of 3.6MN/m3/2 could be obtained in 80wt% B4C-20 wt% SiC composite were obtained.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.11a
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• pp.99-102
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• 2002

The BSCCO superconductor materials of using Self-propagating High-temperature Synthesis (SHS) were studied. Mechano-chemical activation - as a pre-treatment of the reactants mixture - strongly influences the kinetic parameters, the reaction mechanism, and the composition and structure of the final product. In this paper as an effort for fabricating the SHSed BSCCO superconductor powder SHS method was considered to application in the synthesis of superconducting materials.

• Korean Journal of Materials Research
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• v.14 no.12
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• pp.889-892
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• 2004

The synthesis of $Zn_{2}SiO_4:Mn^{2+}$ for PDP green phosphor by SHS(Self-propagating High temperature Synthesis method) was studied. The precursors were well mixed and cold compacted. And then, the green pellet was synthesized at high temperature through self-propagating high temperature zone. Because this reaction uses the heat resulted from the oxidation of Zn metal powder in this system, Zn/ZnO mole ratio is one of the most important reaction variable. Throughout several experiments, the optimal condition of Zn/ZnO mole ratio and Mn concentration are 1.2/0.8 and 0.05mo1e, respectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.666-669
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• 2002

The differences of the effects of mechanical substance pre-activation in the mills with divers force effect schemes on the self-propagating high temperature synthesis (SHS) of the $SiO_2$ + 37.5% Al system were investigated. The power saturation of activated material state are estimated referring on the variations of dilatometry curve paths. The effects of activation time on the temperature of sample self-ignited in the furnace, combustion temperature and completeness of the quartz reaction with aluminium were determined. The enhancing effects of organic modifiers of quartz particle surfaces on the further SHS synthesis development were shown.

• Applied Chemistry for Engineering
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• v.5 no.2
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• pp.263-273
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• 1994

Titanium powder prepared by dehydrogenating the titanium hydride which is synthesized by reacting Ti-sponge (99.67%) with hydrogen using the self-propagating high-temperature synthesis method. In the synthesis of titanium hydride, the particle size of the product was found dependent on the amount of hydrogen incorporated into the titanium such that the particle size of titanium hydride decreased with increasing hydrogen pressure and after-burn time. In the dehydrogenation process, as the dehydrogenation time increase, the particle size of titanium powder increased due to partial melting and sintering of titanium particles.