• Journal of the Korean Applied Science and Technology
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• v.22 no.2
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• pp.96-105
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• 2005

Core-shell polymers of methyl methacrylate-styrene system were prepared by sequential emulsion polymerization in the presence of sodium dodecyl benzene sulfonate(SDBS) as an emulsifier using ammonium persulfate(APS) in an initiator and the characteristics of these core-shell polymers were evaluated. Core-shell composite latex has the both properties of core and shell components in a particle, whereas polymer blends or copolymers show a combined physical properties of two homopolymers. This unique behavior of core-shell composite latex can be used in various industrial fields. However, in preparation of core-shell composite latex, several unexpected matters are observed, for examples, particle coagulation, low degree of polymerization, and formation of new particles during shell polymerization. To solve this matters, we study the effects of surfactant concentrations, initiator concentrations, and reaction temperature on the core-shell structure of PMMA-PSt and PSt-PMMA. Particle size and particles distribution were measured by using particle size analyzer, and the morphology of the core-shell composite latex was observed by using transmission electron microscope. Glass temperature was also measured by using differential scanning calorimeter. To identify the core-shell structure, pH of the composite latex solutions was measured.

• Smart Structures and Systems
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• v.25 no.1
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• pp.57-64
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• 2020

The nonlinear dynamics of a directly forced clamped-clamped-free-free magneto-rheological elastomer (MRE) sandwich shell has been experimentally investigated. Experiments have been conducted on an aluminium shallow shell (shell A) and an MRE-aluminium sandwich shallow shell with single curvature (shell B). An electrodynamic shaker has been used to directly force shells A and B in the vicinity of their fundamental resonance frequency; a laser displacement sensor has been used to measure the vibration amplitude to construct the frequency-response curves. It was observed that for an aluminium shell (shell A), that at small forcing amplitudes, a weak softening-type nonlinear behaviour was observed, however, at higher forcing amplitudes the nonlinear dynamical behaviour shifted and a strong hardening-type response occurred. For the MRE shell (shell B), the effect of forcing amplitude showed softening at low magnetic fields and hardening for medium magnetic fields; it was also observed the mono-curved MRE sandwich shell changed dynamics to quasiperiodic displacement at some frequencies, from a periodic displacement. The presence of a magnetic field, initial curvature, and forcing amplitude has significant qualitative and quantitative effects on the nonlinear dynamical response of a mono curved MRE sandwich shell.

• Journal of the Korean Geotechnical Society
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• v.24 no.7
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• pp.51-60
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• 2008

In this paper, the behaviour of shell foundation was studied. In the theoretical program, the general shallow foundation theories and failure mechanism developed by Terzaghi, Mayerhof and others were reviewed and compared. In the numerical study, the 2 and 3 dimensional FEM simulations were carried out using an uncoupled-analysis approach. The results obtained from the model test show that the bearing capacity of shell foundation was about 25% to 30% larger than that of general foundation. Due to the cases of shell angle, the maximum bearing capacity of shell foundation shows when the shell angle of foundation was $60^{\circ}$. In addition, even if the shell foundation has various advantages compared with the general foundations as described above, the practical verifications in full scale size will be necessary to use in the field and will be helpful in the technical development of other special foundations.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2002.05b
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• pp.281-288
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• 2002

Crab shell 충진 칼럼을 이용한 수중 중금속의 연속적 제거에 있어서 다른 흡착제 (CER, GAC, Zeolite)와 비교 실험을 통하여 crab shell의 중금속 제거능을 알아보았다. 수중 $Pb^2+/{2+}$ 의 column을 이용한 연속적제거에 있어서 미세침전부분이 외부로 배출됨으로 칼럼 외부에 여과시스템의 도입함으로써 중금속 제거능을 높일 수 있을 것으로 판단된다. 중금속의 연속적 제거에 있어서 CER의 1,000 BVs까지의 전체 제거량은 0.35mmol/g, GAC는 0.17mmo1/g, zeolite는 0.16 mmol/g으로 나타났고 crab shell에 의한 중금속 제거량은 0.61 mmol/g으로 다른 흡착제보다 높은 제거효율을 보였다. 수중 중금속의 연속적 제거에 있어서 여러 흡착제의 제거 순서는 crab shell > CER > GAC > zeolite 로 나타났다. Crab shell의 경우는 파과점이 2,000 BVs에서 나타나므로 일반적인 폐수처리의 화학적 처리 후 잔존하는 저농도의 중금속을 제거를 위해 crab shell 충진 칼럼이 유용 할 것으로 판단된다. Crab shell의 재사용 가능성을 알아보기 위하여 crab shell을 이용한 중금속 제거공정에서 연속적인 중금속제거와 탈착과정을 통하여 보았을 때 1회에서 $Pb^2+/{2+}$제거된 량은 0.71 mmol/g 제거되었고 2회에서는 0.27 mmol/g, 3회에서는 0.02 mmol/g으로 급격하게 crab shell의 제거능이 떨어지는 것을 관찰 할 수 있다. 이는 crab shell이 재사용이 불가능 할 것으로 판단되나 다른 흡착제보다 월등한 제거효율을 보이므로 수중 중금속의 연속적 제거 흡착제 적합할 것으로 판단된다.

• Journal of the Korean Applied Science and Technology
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• v.19 no.4
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• pp.265-272
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• 2002

$CaCO_{3}$ absorbed sodium lauryl sulfate (SLS) surfactant was prepared, Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using styrene(St) as a shell monomer and potasium persulfate (KPS) as an initiator, We found that when $CaCO_{3}$; core prepared by adding 2,0 wt% SLS, $CaCO_{3}$ core/PSt shell polymerization was carried out on the surface of $CaCO_{3}$ particle without forming the new PSt particle during St shell polymerization in the inorganic/organic core-shell polymer preparation, The structure of core-shell polymer were investigated by measuring the degree of decomposition of $CaCO_{3}$ using HCl solution, thermal decomposition of polymer composite using thermogravimetric analyzer and morphology by scanning electron microscope.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.19 no.2
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• pp.47-54
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• 2020

Themo-mechanical analysis was carried out using the finite element method for the steel shell of a cupola furnace. When the outer surface of the shell was cooled with water to within the temperature range of 35-80 ℃ during operation of the cupola, the inner surface of the shell was expected to exhibit a temperature of 65-248 ℃ based on heat transfer analysis. The shell was also expected to have an equivalent stress range of 100-280 MPa in the outer surface over the temperature range examined. Upon cooling the shell to obtain an outer surface temperature <80 ℃, the maximum equivalent stress of the shell did not exceed the yield strength. Although the temperature of the outer surface varied between 35 and 80 ℃ periodically due to the cooling control problem, the fatigue stress at the outer surface of the shell was calculated to be within the fatigue strength. During a non-operational period to examine the system between furnace operations, the thermal stress presented in the shell was sufficiently low to reach the desired yield strength and fatigue limit.

• The Bulletin of The Korean Astronomical Society
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• v.35 no.2
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• pp.73.1-73.1
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• 2010

Using the spectroscopic data secured with the Hamilton Echelle Spectrograph attached to a 3-m telescope at the Lick Observatory, we derived the expansion velocities from various line profiles in the 3600 $\AA$ to 10,000 $\AA$ based on the full width at half maximum and double peak of the high dispersion line profiles. The symmetrical shapes of the permitted line profiles indicate that the permitted line zone is symmetrical e.g., a spherical shell or bipolar + torus structures, which might be evidence of relatively recent ejection from the central star. Most other stronger forbidden lines might be coming from a main shell which appears as a bilateral symmetrical morphology, seen in HST and other ground-based telescopic images. The overall expansion velocities of this main shell structure that are responsible for most lines, seem to show the Hubble type expansion, i.e., accelerating shell. The faster expansion velocities of the permitted OII, NII, NIII and perhaps CII lines that do not suit to the Hubble type expansion, imply the existence of a somewhat smaller inner shell inside the outer main shell. We conclude that the nebular shell consists of a swiftly expanding inner shell and an outer normal shell excited by a central star of about 55,000K. The former compact zone appears to be responsible for the permitted C, N, and O lines while the latter extended shell appears to be responsible for H, He, and forbidden lines. We present some evidence that NGC 6833 be a member of the Galactic halo.

• Journal of the Korean Ceramic Society
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• v.45 no.11
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• pp.750-754
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• 2008

The artificial aggregates with dense surface layer (shell) was fabricated and the dependence of water emission rate upon the shell structures was studied. The EAF dust containing many flux components and waste white clay with ignition loss of above 48% were used as for liquid phase and gas forming agents during a sintering process respectively. In addition, the shell structure was modified with various processes and the modification effect on water emission rate was analyzed. The pores under $10{\mu}m$ were found in the sintered artificial light aggregates and disappeared by incorporating to a bigger pore during re-sintering. The water emission rate in an initial step depended on a void content of aggregates filled in a bottle rather than a shell structure. But, after 7 days where the water emission of the aggregate with a shell is above 40%, the shell of aggregates suppressed the water emission. The core of aggregates was exposed and most shell was lost when crushed to smaller size so, the ability for suppressing water emission of the crushed aggregates decreased. The activation energy for the water emission was $3.46{\pm}0.25{\times}10^{-1}$J/mol for the most specimens showing that the activation energy is irrelevant to the pore size distribution and shell structure.

• Journal of Welding and Joining
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• v.34 no.2
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• pp.11-15
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• 2016

FE analyses for weldment of ship structure are required for various reasons such as stress concentration for bead tow, residual stress and distortion after welding, and hydrogen diffusion for prediction of low temperature crack. These analyses should be done by solid element modeling, but most of ship structures are modeled by shell element. If we are able to make solid element in the shell element FE modeling it is easily to solve the requirement for solid elements in weld analysis of large ship structures. As the nodes of solid element cannot take moments from nodes of shell element, these two kinds of element cannot be used in one model by conventional modeling. The PSCM (Perpendicular shell coupling method) can connect shell to solid. This method uses dummy perpendicular shell element for transferring moment from shell to solid. The target of this study is to develop a FE pre-processing system applicable at welding at ship structure by using PSCM. We also suggested glue-contact technique for controlling element numbers and element qualities and applied it between PSCM and solid element in automatic pre-processing system. The FE weldment modeling through developed pre-processing system will have rational stiffness of adjacent regions. Then FE results can be more reliable when turn-over of ship-block with semi-welded state or ECA (Engineering critical assessment) of weldment in a ship-block are analyzed.

• Journal of KSNVE
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• v.4 no.2
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• pp.163-175
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• 1994

An analytical method for nautral frequencies of a partially liquid- filled circular cylindrical shell with various boundary conditions is developed by means of the Stokes's transformation and Fourier series expansion on the basis of Sanders' shell equation. The liquid-shell coupled system is divided into two regions for convenient formulation. One is the empty shell region in which the Sanders' shell equations are formulated without the lipuid effect, the other is wetted shell region in which the shell equations are formulated with consideration of the liquid dynamic effect. The shell equations for each regions are combined by the geometry and the force continuities at the junction of the two regions. For the vibration relevant to the liquid motion, the velocity potential of liquid is assumed as a sum of linear combination of suitable harmonic functions in axial direction. The unknown parameters are selected to satisfy the boundary condition along the wetted shell surface. The natural frequencies of the liquid filled cylindraical shells with the clamped- free and the clamped-clamped boundary conditions examined in the previous works, are obtained by this analytical method. The results are compared with the previous works, and excllent agreement is found for the natural frequencies of the shells.