• Title/Summary/Keyword: S-doping

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Electrochemical doping of poly(3-alkylthiophene) and their electrical and optical properties (Poly(3-alkylthiophene)의 전기화학적 도-핑과 그의 전기적, 광학적 성질)

  • 구할본;김태성
    • Electrical & Electronic Materials
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    • v.5 no.3
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    • pp.337-343
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    • 1992
  • FeCl$_{3}$등 천이금속 halides를 촉매로 이용하여 poly(3-hexylthiophene) 등의 가용성 polythiophene 유도체를 합성하였다. casting에 의해 작성한 필림은 전해중합 법에 의한 polythiophene 필림과 같은 특성을 나타낸다. Poly(3-hexylthiophene)의 용액 상태의 에너지 밴드 갭은 2.42(eV)이며 이것은 필림상태 보다 고분자 쇄간의 상호작용이 약하므로 밴드 갭이 더 크다. 또한 I$_{2}$를 도우프하면 고차 구조가 달라지므로 poly(3-hexylthiophene)은 polythiophene 보다 도핑속도가 더욱 빠르다.

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EFFECTS OF Co-DOPING LEVEL ON THE MICROSTRUCTURAL AND FERROMAGNETIC PROPERTIES OF LIQUID-DELIVERY METALORGANIC-CHEMICAL-VAPOR-DEPOSITED $Ti_{1-x}Co_xO_2$ THIN FILMS

  • Seong, N.J.;Seong, S.G.
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.42-43
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    • 2002
  • Spintronics is a rapidly expanding research area because of recent developments in the physics of spin-dependent phenomena. For use as spintronic materials, dilute magnetic semiconductors (DMS) are of considerable interest as spin injectors for spintronic devices.$^{[1]}$ Many researchers have studied DMS, in which transition metal atoms are introduced into the lattice, thus inserting local magnetic moments into the lattice. (omitted)

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Aqueous-deposited CdS Thin Films for Photovoltaic Application (용액증착법에 의한 광전성 CdS 박막제조)

  • 신재혁
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.10a
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    • pp.161-164
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    • 1997
  • Thin films of CdS were prepared from an aqueous solution containing Cd(Ac)$_2$, NH$_4$OH, NH$_4$Ac and (NH$_2$)$_2$CS for photovoltaic application. Growth rate of CdS films was increased with increasing temperature of reactive solution and with decreasing concentration of NH$_4$OH. Optical transmittances were more than 60%, independent with temperature and concentrations, and were changed with thickness of CdS films. Growth films mostly showed the presence of polycrystallines with mixed cubic and condition. The resistivities of CdS were decreased by doping boron and criticial amount of dopant was determined.

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Analysis of Transport Characteristics for FinFET Using Three Dimension Poisson's Equation

  • Jung, Hak-Kee;Han, Ji-Hyeong
    • Journal of information and communication convergence engineering
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    • v.7 no.3
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    • pp.361-365
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    • 2009
  • This paper has been presented the transport characteristics of FinFET using the analytical potential model based on the Poisson's equation in subthreshold and threshold region. The threshold voltage is the most important factor of device design since threshold voltage decides ON/OFF of transistor. We have investigated the variations of threshold voltage and drain induced barrier lowing according to the variation of geometry such as the length, width and thickness of channel. The analytical potential model derived from the three dimensional Poisson's equation has been used since the channel electrostatics under threshold and subthreshold region is governed by the Poisson's equation. The appropriate boundary conditions for source/drain and gates has been also used to solve analytically the three dimensional Poisson's equation. Since the model is validated by comparing with the three dimensional numerical simulation, the subthreshold current is derived from this potential model. The threshold voltage is obtained from calculating the front gate bias when the drain current is $10^{-6}A$.

Electrical and Optical Properties of CdS Films Sintered with CdCl2 and InCl3 (CdCl2 와 InCl3 를 첨가한 CdS 소결막의 전기적 광학적 성질)

  • 김형수;임호빈
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.39 no.2
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    • pp.183-191
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    • 1990
  • Polycrystalline CdS film have been prepared by coating a slurry constiting of CdS, CdCl2, various amount of InCl3 and propylene glycol on glass substrate and by sintering in a nitrogen atmosphere, and their sintering behaviors, electrical properties and optical properties have been investigated. As the amount of InCl3 increases, the enhancing effect of CdCl2 on sistering decreses resulting in a sharp decrease in optical transmittance and an increase in electrical resistivity. The carrier concentration is almost independent of InCl3 added due to the occurrence of chlorine doping and to the compensating effect of indium dopant. Microstructure an optical properties of CdS film, which contain CdCl2 and InCl3 before sintering, can be improved by sintering in a sealed boat.

Electrochemical Study of Poly(aniline N-alkylsulfonate)s

  • Kim, Eunkyoung;Rhee, Suh Bong
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.631-636
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    • 1995
  • Electrochemical properties of self-dopable poly(aniline N-butylsulfonate)s in various acidic medium were investigated by spectroelectrochemical techniques. Cyclic voltammetric study showed more than two reversible process of one electron transfer, the potential and peak intensity of which were dependent on the acid concentration and dopant ion. Spectroscopic study at different oxidation level indicated that the electrochromic switching of the poly(aniline N-alkylsulfonate)s film involves structural changes from benzenoid ring to quinoid ring. Spectrocyclic voltammetry together with impedance spectra of the PANBUS film in 0.1 M $LiClO_4$ solution of acetonitrile containing 0.46 M of perchloric acid showed two types of highly conductive states at the intermediate oxidation levels, which can be related to the metallic polaron states doped by two different process.

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High control Alkali & Alkaline-earth Metal Sources for OLED devices

  • Bonucci, Antonio;Bertolo, Johnny Mio;Riva, Mauro;Carretti, Corrado;Tominetti, Stefano;Kim, Sung-Hyun;Lee, Jun-Yeob
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.332-335
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    • 2007
  • Electron injection improvement in OLED organic layers can be obtained by their doping or using alkaline-earth or alkali metals as electron injection layers (EIL). Common handling problems can be solved by an innovative metal dispensing technology to ensure controlled and reliable metal layers for OLED. Thickness and deposition rate of EIL during the process have been explored to optimize device performances.

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Synthesis and Characterization of Soluble Polypyrrole with High Conductivity (높은 전기 전도성을 갖는 가용성 폴리피롤 합성 및 특성)

  • Hong, Jang-Hoo;Jang, Kwan-Sik
    • Applied Chemistry for Engineering
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    • v.18 no.3
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    • pp.234-238
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    • 2007
  • Highly conducting Polypyrroles soluble in organic solvents were synthesized using functional doping agents, such as mixed dopants [sodium di(2-ethylhexyl)sulfosuccinate (DEHSNa) Naphthalenesulfonic acid (NSA), DEHSNa Toluenesulfonic acid (TSA), DEHSNa Dodecylbenzensulfonic acid (DBSA)] and mixed oxidants [$(NH_4)_2S_2O_8{\cdot}FeCl_3$, $(NH_4)_2S_2O_8{\cdot}Fe_2(SO_4)_3$]. Ppy-DEHS powder using an oxidant, such as $(NH_4)_2S_2O_8$ (10 wt%/vol.) showed higher solubility than the mixed dopant (DEHSNa NSA, 3 wt%/vol.) and mixed oxidant [$(NH_4)_2S_2O_8{\cdot}Fe_2(SO_4)_3$, 4 wt%/vol.] in DMF solvent. But Ppy-DEHS free standing film using a mixed dopant, such as DEHSNa NSA (16 S/cm) and a mixed oxidant, such as $(NH_4)_2S_2O_8{\cdot}Fe_2(SO_4)_3$ (13 S/cm) cast from DMF solvent showed higher electrical conductivity than $(NH_4)_2S_2O_8$ (2 S/cm). For the Ppy-DEHS films using various condition cast from DMF solvent, three dimensional various range hopping model (3D VRH ; $\{{\sigma}_{dc}(T)={\sigma}_oexp[-(T_o/T)^{1/4}]\}$) provided fit to the results of temperature dependence of electrical conductivity measurement.

Electrical conductivity of olivine type LiFe0.965Cr0.03B0.005PO4 and LiFe0.965Cr0.03Al0.005PO4 powders (올리빈형 LiFe0.965Cr0.03B0.005PO4 and LiFe0.965Cr0.03Al0.005PO4 분말의 전기전도도)

  • Kim, Chang-Sam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.3
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    • pp.141-146
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    • 2010
  • $LiFePO_4$ doped with Cr showed improved electrochemical properties as a cathode material of lithium-ion batteries compared to the undoped. The improvement was thought that the doping would raise the electronic conductivity of the compounds. The electrical conductivity of $LiFe_{0.965}Cr_{0.03}B_{0.005}PO_4$ and $LiFe_{0.965}Cr_{0.03}Al_{0.005}PO_4$ powder was measured in the temperature range from 30 to $80^{\circ}C$. The doped powders were synthesized via mechanochemical milling and subsequent heat treatment at 675~$750^{\circ}C$ for 5~10h. The doping enhanced grain growth and electrical conductivity. The electrical conductivity of the $LiFe_{0.965}Cr_{0.03}Al_{0.005}PO_4$ powder at $30^{\circ}C$ was $1{\times}10^{-8}S/cm$, which was higher two orders of magnitude than that of the undoped.

Bioequivalence Evaluation of the Tiropramide Formulation by GC/MS (티로프라미드 주사제의 생물학적 동등성 평가를 위한 GC/MS 방법)

  • Myung, Seung-Woon;Kim, Myungsoo;Kim, Hye-Young;Kwak, Hyun-Tae;Min, Hye-Ki;Sohn, Dong-Ryul;Hong, Young-Hun
    • Analytical Science and Technology
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    • v.14 no.3
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    • pp.221-229
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    • 2001
  • The bioequivalence study of two tiropramide products was evaluated in 16 health male volunteers following intra-muscular injection. Test product was Tiram$^{(R)}$ injection (S Pharm. Co, Ltd.) and reference product was Tiropa$^{(R)}$ injection(D Pharm. Co., Ltd.). The drug concentration in plasma was determined by GC/MS for over a period of 8 hours after injection. Analysis of variance reveal that there are no differences in AUC (area under the plasma concentration-time curve from time zero to infinity), Cmax (maximum plasma concentration) and Tmax (time to reach Cmax). The differences of mean AUC, Cmax and Tmax between two products were 0.73, -1.385 and -12.994%, respectively. Minimum detectable differences (%) at ${\alpha}=0.05$ were all less than 20% given as a guideline (10.05, 17.90 and 19.01% for AUC, Cmax and Tmax, respectively). From these results, the two formulations of tiropramide are bioequivalent and thus, may be prescribed interchangeably.

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