• Title/Summary/Keyword: S-SBR

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A Study on the Properties of Polyvinyl Acetate Emulsion Mixed with SBR, Polyurethane and Epoxy Latex (SBR, 폴리우레탄 및 에폭시 라텍스를 혼합한 폴리초산비닐 에멀젼 수지의 물성에 관한 연구)

  • Suh, Won-Dong
    • Elastomers and Composites
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    • v.33 no.3
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    • pp.149-158
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    • 1998
  • SBR latex, polyurethane latex and epoxy latex were separately mixed with polyvinyl acetate emulsion. The various physical properties were examined for the mixtures. Epoxy mixtures gave a transparent film. Both polyurethane and SBR mixtures showed opaque film with high viscosity. In SBR and polyurethane increase in hardness was dependent on the evaporation rate of water, but in epoxy it was dependent on the degrees of crosslink. Epoxy's showed excellent water-resistance. SBR showed a good flexural strength and impact strength. When vinyl acetate emulsion was mixed with less than 10% latex paper tube showed the ductile fracture, but over latex content 20%, it showed the brittle fracture.

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Biological Nutrient Removal by Enhancing Anoxic Phosphate Uptake (무산소 조건에서의 인섭취를 이용한 생물학적 영양염류 제거)

  • Lee, Dae Sung;Jeon, Che Ok;Park, Jong Moon
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.861-867
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    • 2000
  • The feasibility of simultaneous phosphorus and nitrogen removal by enhancing anoxic phosphorus uptake was investigated in a sequencing batch reactor (SBR). By introducing an anoxic phase into an anaerobic-aerobic SBR (AO SBR), significant amounts of denitrifying phosphorus accumulating organisms (DPAOs) which can utilize nitrate as electron acceptor could be accumulated in the reactor (anaerobic-aerobic- anoxic-aerobic SBR, $(AO)_2$ SBR). A direct comparison of phosphorus uptake rate under anaerobic and aerobic conditions showed that the fraction of DPAOs in P-removing sludge were increased from 10% in the AO SBR to 64% in $(AO)_2$ SBR. The $(AO)_2$ SBR showed stable phosphorus and nitrogen removal efficiency: average removal efficiencies of TOC, total nitrogen, and phosphorus were 92%, 88%, and 100%. respectively. Results of the $(AO)_2$ SBR operation and batch tests showed that nitrite (up to 10 mg-N/L) was not detrimental to anoxic phosphorus uptake and could serve as good electron acceptor like nitrate.

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Performance Evaluation of the MPEG USAC According to the Spectral Band Replication Bandwidth (Spectral Band Replication 대역폭에 따른 MPEG USAC 부호화 성능 평가)

  • An, Kyung-Jun;Jung, Yoo-Sun;Beack, Seung-Kwon;Kang, Kyeong-Ok;Kim, Rin-Chul
    • Journal of Broadcast Engineering
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    • v.16 no.5
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    • pp.705-713
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    • 2011
  • This paper deals with the effect of SBR bandwidth on the overall performance of the MPEG USAC. Here, the SBR bandwidth is termed the frequency region covered by the SBR codec, and is specified by the bs_stop_freq, which is one of the SBR bitstream components. The performance of the USACs with 5 different SBR bandwidths are compared in a subjective manner using the MUSHRA test. In the comparison, the bit rate is confined to 14~24kbps and only the LPD unit is selected for the core codec. From the comparison, it is observed that the SBR bandwidth that stretches up to 18KHz or above gives the better performance than the others.

A Study of the Effect of Degree of Cure on the Physical Properties of Rubber Compounds (가교정도에 따른 고무복합체의 물리적 특성에 관한 연구)

  • Kim, Hyeon-Jae;Kaang, Shin-Young;Nah, Chang-Woon
    • Elastomers and Composites
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    • v.33 no.4
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    • pp.281-289
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    • 1998
  • Tensile properties including Young's modulus and tear strength were measured for four different rubber compounds; natural rubber(NR), styrene-butadiene copolymer(SBR), ethylene-propylene diene monomer (EPDM), and brominated isobutylene-p-methyl-styrene copolymer(BIMS) as a function of temperature and degree of cure. To see the effect of over cure, a measurement was made of the tensile strength and swelling behavior of the over-cured rubber compounds. Young's modulus, E, was found to have linear dependency on the degree of cure for all rubber compounds. EPDM and BIMS showed the highest and lowest slopes, respectively. The slope of NR and SBR lay between EPDM and BIMS. Tear strength, Gc, decreased in the order of NR>BIMS>SBR>EPDM. As the cure time was extended the degree of cure of NR and SBR decreased, while that of BIMS increased. EPDM showed little change in the degree of cure.

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Studies on the Ozone Resistance and Physical Properties of SBR/EPDM Blend Compound due to EPDM Content Variation (EPDM 함량 변화에 따른 SBR/EPDM 블렌드 혼합물의 내오존성과 물리적 성질에 관한 연구)

  • Ha, Ki-Ryong;Lee, Jong-Cheol;Kim, Tae-Geun;Hwang, Ki-Seob
    • Elastomers and Composites
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    • v.43 no.1
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    • pp.8-17
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    • 2008
  • Styrene-butadiene rubber(SBR) has good abrasion resistance, miscibility, and anti-vibration property. however, it is easily damaged by ozone and swelled by hydrocarbon fluids because of unsaturation part in main chain, that causes loss of visco-elasticity and reduction of product's life cycle. Therefore, object of this study is to cope with this problem. SBR is blended with various proportion of ethylene-propylene-diene terpolymer(EPDM), which has excellent ozone and oxygen resistance, to improve physical properties and ozone resistance, and diverse analytical techniques are used to measure morphology, glass transition temperature$(T_g)$, ozone-resistance, degradation temperature, static spring constant, hardness for considering a suitability for anti-vibration industrial product. We found that the blend consisting of SBR 70% and EPDM 30% showed no crack after ozone test and good miscibility between SBR and EPDM from this study.

Studies on the Chemical Treatment of Silica for Synthetic Rubber Reinforcement (II) -Silica Treatment by LBR-MDI- (합성(合成)고무 보강제(補强劑) Silica의 화학처리(化學處理)에 관(關)한 연구(硏究) (II) -MDI 처리(處理) Silica의 LBR처리(處理)-)

  • Jin, Je-Yong;Kim, Hong-Seon;Choi, Sei-Young
    • Elastomers and Composites
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    • v.30 no.3
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    • pp.207-217
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    • 1995
  • The reinforcement of Inorganic filler silica treated with LBR-MDI In SBR vulcanizates were Investigated. The inorganic filler silica treated with MDI on unmodified surface and that of silica treated by MDI was retreated with LBR. The charateristics of vulcanization, physical properties, surface properites and dynamic properties were investigated after mixing those silica with SBR and unmodified silica with SBR. Rheometric studies of the vulcanization showed that S-series has fast scorch $time(t_{10})$ and an optimum cure $time(t_{90})$ in the SBR compounds. And it was turned out that SBR vulcanizates compounded with LBR treated silica was better than any other componnds in hardness, tensile strenght, 100 300% modula and elongation. We could confirm that urea bonding is formed from IR spectrum. We concluded that L-series shows the best reinforcement effect in SBR vulcanizates.

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The Effect of Surface Area of Silicas on Their Reinforcing Performance to Styrene-butadiene Rubber Compounds

  • Ryu, Changseok;Kim, Sun Jung;Kim, Do Il;Kaang, Shinyoung;Seo, Gon
    • Elastomers and Composites
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    • v.51 no.2
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    • pp.128-137
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    • 2016
  • The effect of the surface area of silicas on their reinforcing performance to styrene-butadiene rubber (SBR) compounds was systematically investigated. The feasibility of the Brunauer-Emmett-Teller surface area ($S_{BET}$) as a parameter representing the characteristics of the silicas was discussed compared to the mesopore volume, c value, oil absorption, and uptake of silane. The increase in $S_{BET}$ of silicas caused a considerable increase in Mooney viscosity, minimum torque, and hysteresis loss of the silica-filled SBR compounds, while significantly enhancing their abrasion property. These changes were explained by the attrition between the hydrophilic silica surface and the hydrophobic rubber chains. As expected, the change in $S_{BET}$ did not induce any remarkable changes in the cure, processing, tensile, and dynamic properties of the silica-filled SBR compounds because the crosslinking density of the rubber chains mainly determined these properties.

Adhesive Strength in Tension of SBR-Modified Cement Mortar with Self-Flowability Material for Floor-Finishing (자기 평활성 바닥 마감용 SBR 시멘트 모르타르의 인장부착강도)

  • Do, Jeong-Yun;Soh, Yang-Seob
    • Journal of the Korea Concrete Institute
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    • v.15 no.4
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    • pp.549-556
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    • 2003
  • Various researches on the application of polymer dispersions to the cement mortar and concrete have been practised in many countries like America, Japan and Germany and so on because of high performance and good modification effect of these. In this study, SBR, Polymer dispersion that widely used in situ is employed that the self-flowability may be induced in the cemen mortar. In order to comprehend and investigate the modification of cement mortar with self-flowability by SBR and properties and fracture mode of adhesive strength in tension of that, experimental parameter was set as SBR solid-Cement ratio(S/C) and Cement:Fine aggregate(C:F) and the experiments such as Unit weight, Flow, Consistency change, Crack resistance and Segregation that inform on the general properties have been done. In addition of that, Adhesion in tension is measured with a view to comprehending the properties and fracture mode in tensile load. Consistency change of cement mortar modified by SBR did grow better as the ratio of SBR solid-Cement increased and was much superior to that of resin based flooring such as polyurethane and epoxy which recorded the loss of consistency in 90min. after mixing. Adhesive strength in tension increased with continuity in the curing age and showed the maximum in case of C:F=1:1 and S/C=20%. As the increase of curing age, the fracture mainly happened in the concrete substrate and the interface between the specimen and concrete substrate.

The Potential Energy Recovery and Thermal Degradation of Used Tire Using TGA (열분석법을 이용한 사용후 타이어의 열적 특성과 포텐셜 에너지의 회수)

  • Kim, Won-Il;Kim, Hyung-Jin;Hong, In-Kwon
    • Elastomers and Composites
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    • v.34 no.2
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    • pp.135-146
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    • 1999
  • The thermal degradation kinetics of SBR and tire were studied using a conventional thermogravimetric analysis in the stream nitrogen at a heating rate of 5, 10, 15, $20^{\circ}C/min$, respectively. Thermogravimetric curves and their derivatives were analyzed using various analytical methods to determine the kinetic parameters. The degradation of the SBR and tire was found to be a complex process which has multi-stages. The Friedman method gave average activation energies for the SBR and tire of 247.53kJ/mol and 230.00kJ/mol, respectively. Mean-while, the Ozawa method Eave 254.80kJ/mol and 215.76kJ/mol. It would appear that either. Friedman's differential method or Ozawa's integral method provided satisfactory mathematical approaches to determine the kinetic parameters for the degradation of the SBR and tire. Approximately 86% and 55% of oil products were obtained at a final temperature of $700^{\circ}C$ and a heating rate of $20^{\circ}C/min$ for the SBR and tire respectively.

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Structure of Bacterial Communities in Biological Nitrogen Removal System (Biological Nitrogen Removal System의 세균 군집 분석)

  • Kim, Kyung-Mi;Lee, Sang-Ill;Lee, Dong-Hun
    • Korean Journal of Microbiology
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    • v.42 no.1
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    • pp.26-33
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    • 2006
  • To understand the efficient process of biological nitrogen removal (BNR) system, the structure of bacterial communities in nitrification reactors was analyzed using PCR and terminal restriction fragment length poly morphism (I-RFLP) methods. In this study, we used an advanced treatment system with plotting media, Nutrient Removal Laboratory system, or the rumination type sequencing batch reactor (SBR) system. The terminal restriction fragments of ammonia-oxidizing bacteria (AOB) and other $\beta-proteobacteria$ were observed in all of three BNR systems. The nucleotide sequence analysis of terminal restriction fragments showed that Nitrosomonas and Nitrosolobus were major populations of AOB in SBR system, whereas uncultured $\beta-proteobacteria$ and Cardococcus australiensis were the predominant groups in other two BNR systems. Also the SBR system may be more efficient to enrich AOB. These results indicate that the different structure of bacterial community may be developed depending on the wastewater treatment systems, although the same influent is used.