• Title/Summary/Keyword: S-MMA

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Synthesis and Properties of Polyurethane-Acrylate Top-Coating Agent

  • Son, Young-Joon;Lee, Dong Jin;Bae, Jong Woo;Lee, Jung Hee
    • Elastomers and Composites
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    • v.50 no.2
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    • pp.98-102
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    • 2015
  • A series of polyurethane-acrylate hybrids were synthesized by 2-step emulsion polymerization of a variety of acrylate monomers such as 2-hydroxy ethyl methacrylate (HEMA), methyl methacrylate (MMA). Experiment was performed to improve stability and emulsibility of surface treatment agent, and it was found that the polyurethane-acrylate hybrids having an optimum composition (MMA : 20%, LA(EO)3-S : 3% and TDA-7 : 5%) was shown to be quite surface active in the solid contents. These results suggests that the optimal polyurethane-acrylate hybrids in this study have high potential as top coating agent, which may have high gloss and excellent properties.

A Study on the Acquisition Policy of Military Affairs Administration Manuscripts (병무행정 매뉴스크립트 수집정책 연구)

  • Lee, Jung-Hee
    • Journal of Korean Society of Archives and Records Management
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    • v.9 no.1
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    • pp.5-32
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    • 2009
  • The purpose of this paper is to establish the manuscripts acquisition policy on the Military Affairs Administration focused on historical, cultural, and informational value. The collection of manuscripts is part of 40 anniversary of MMA to build the MMA archives and to establish acquisition policy. To achieve this objective, we proposed the MAA's archival mission statement, collection coverage, collection methods and procedures.

Gravitational-wave Electromagnetic Counterpart Korean Observatory (GECKO): Network of Telescopes and Follow-up Observation of GW190425

  • Paek, Gregory S.H.;Im, Myungshin
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.36.3-37
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    • 2020
  • Recent observation of the neutron star merger event, GW170817, through both gravitational wave (GW) and electromagnetic wave (EM) observations opened a new way of exploring the universe, namely, multi-messenger astronomy (MMA). One of the keys to the success of MMA is a rapid identification of EM counterpart. We will introduce GW follow-up observation project in Korea for hunting GW EM counterpart rapidly and its strategy for prioritization of GW source host galaxy candidates. Our method relies on recent simulation results regarding plausible properties of GW source host galaxies and the low latency localization map from LIGO/Virgo. We will show a test result for both binary neutron star merger events using previous event and describe observing strategy with our facilities for GW events during the ongoing LIGO/Virgo O3 run. Finally, we report the results of optical/NIR follow-up observation of GW190425, the first neutron.

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Synthesis and Effect of Plasma Treatment of Acrylic Composite Particle Binder (아크릴계 복합입자 바인더의 제조와 플라즈마 처리영향)

  • Sim, Dong-Hyun;Seul, Soo-Duk
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.276-283
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    • 2008
  • Kind of monomer(MMA, EA, BA, St)and the monomer ratio(80/20 to 20/80) where changed in the preparation of the core shell binder, and property was improved the plasma processing. Each material changed by plasma treatment time($1{\sim}10\;s$) to change to measure the tensile strength, contact angle and adhesion peel strength for the core shell binder optimal conditions for handling the output of the surface treatment. The type of polymerization and composition of the binder is a regardless initiator of APS, the reaction temperature of $85^{\circ}C$ to 0.3 wt% of the surfactant used to indicate when the conversion rate was the highest, core shell composite particle binder got two glass temperature curves. Core shell binder after the plasma processing contact angle change is the PEA/PSt 38 percent of cases within five seconds to indicate slight decrease was a decline rapidly if not handled $0^{\circ}$ to reach. Tensile strength PSt/PMMA varies $46.71{\sim}46.27\;kg_f$/2.5 cm and adhesion strength PEA/PMMA varies $7.89{\sim}14.44\;kg_f$/2.5 cm increases. Overall, adhesion strength of core shell composite particle is in the order of order PEA>PBA>PSt for shell monomer MMA.

Study on Model of Emulsion Polymeration 1. Pseudo-homopolymerization (유화중합의 모델연구 1. Pseudo-homopolymerization)

  • Park, S.B.;SE, C.S.
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.294-299
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    • 1998
  • To prove pseudo-homopolymerization(PHP) method indirectly for general system which includes more than one growing radicals per particle, Mayo-Lewis equation of bulk copolymer system was derived form probability equation about instantaneous copolymer composition of emulsion copolymer system during interval II. From Extended Smith-Ewart equation proposed by Ballard et al. in emulsion copolymerization, exact solution was obtained for 0-1 system (i.e., the system containing no more than one growing radical per particle). From the exact solution, average number of radicals per particle and instantaneous copolymer composition were predicted to reach the steady state which a few minutes. So the reliability of this approximation method could by proved directly for 0-1 system. Styrene-butadiene(St-Bu) and Styrene-methyl methacrylate (St-MMA) system were used for model calculations.

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A study on the resist characteristics of plasma polymerized thin film of (MMA-Sty-TMT) (플라즈마중합 (MMA-Sty-TMT) 박막의 레지스트 특성조사)

  • Park, J.K.;Park, S.H.;Park, B.G.;Jung, H.D.;Han, S.O.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1268-1270
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    • 1994
  • Fine lithographic technology in a submicron design regime is necessary for the fabrication of VLSI circuits. In such lithography, fine pattern delineation is performed by electron beam, ion beam and X-ray lithography instead of photolithography. Therefore, the new resist materials and development method have been required. So, we are investigating another positive E-beam resists which have high sensitivity and dry etching resistance, Plasma co-polymerized resist was prepared using an interelectrode gas-flow-type reacter. Methymethacrylate, tetramethyltin and styrene were chosen as the monomer to be used. The delineated pattern in the resist was developed with gas-flow-type reactor using an argon and 02 as etching gas. We studied about the effects of discharge power and mixing rate of the co-polymerized thin :film. The molecular structure of thin film was investigated by ESCA and IR, and then was discussed in relation to its quality as a resist.

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A Novel Mutation in the MUT Gene in an Asymptomatic Newborn with Isolated Methylmalonic Acidemia (메틸말론산혈증 신생아의 MUT 유전자에서 발견된 새로운 돌연변이)

  • Kwak, Min Jung;Kim, Yoo-Mi
    • Journal of The Korean Society of Inherited Metabolic disease
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    • v.14 no.2
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    • pp.174-177
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    • 2014
  • Isolated methylmalonic acidemia (MMA) is a group of autosomal recessive inborn errors of metabolism caused by impaired activity of methylmalonyl-coenzyme A mutase (MCM). Mutations in the gene encoding MCM (MUT ) is the most common cause of isolated MMA. In this report, we identify an asymptomatic 15 days old female who had elevated C3-acylcarnitine (C3) in the newborn screening. Her serum homocysteine was normal and urine methylmalonic acid was increased that suggested isolated MMA. She was maintained on a low-protein diet and carnitine supplementation. At 3 months of age, she was still asymptomatic and had normal growth. We analyzed MUT gene mutations. Two heterozygote mutations in the MUT gene were identified including c.323G>A and c.1672+2T>C (IVS8(+2)T>C. Among these, c.1672+2T>C (IVS8(+2)T>C) have not been described previously.

Quantification of Arsenic Species in Some Seafood by HPLC-AFS (HPLC-AFS를 이용한 해산물 중 비소 화학종 분리정량)

  • Jeong, Seung-Woo;Lee, Chae-Hyeok;Lee, Jong-Wha;Jang, Bong-Ki
    • Journal of Environmental Health Sciences
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    • v.47 no.5
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    • pp.496-503
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    • 2021
  • Background: Considering the expenses of and difficulties in arsenic speciation by high performance liquid chromatography-inductively coupled plasma-mass spectrometry (HPLC-ICP-MS), alternative measurement methods should be useful, especially for large-scale research and projects. Objectives: A measurement method was developed for arsenic speciation using HPLC-atomic fluorescence spectrometry (HPLC-AFS) as an alternative to HPLC-ICP-MS. Methods: Total arsenic and toxic arsenic species in some seafoods were determined by atomic absorption spectrometry coupled with hydride vapor generation (AAS-HVG) and HPLC-AFS, respectively. Recovery rate of arsenic species in seafood was evaluated by ultra sonication, microwave and enzyme (pepsin) for the optimal extraction method. Results: Limits of detection of HPLC-AFS for As3+, dimethylarsinate (DMA), monomethylarsonate (MMA) and As5+ were 0.39, 0.53, 0.60 and 0.64 ㎍/L, respectively. The average accuracy ranged from 97.5 to 108.7%, and the coefficient of variation was in the range of 1.2~16.7%. As3+, DMA, MMA and As5+ were detected in kelp, the sum of toxic arsenic in kelp was 40.4 mg/kg. As3+, DMA, MMA and As5+ were not detected in shrimp and squid, but total arsenic (iAS and oAS) content in shrimp and squid analyzed by AAS-HVG were 18.1 and 24.7 mg/kg, respectively. Conclusions: HPLC-AFS was recommendable for the quantitative analysis method of arsenic species. As toxic arsenic species are detected in seaweeds, further researches are needed for the contribution degree of seafood in arsenic exposure.

Performance Analysis of Blind Equalization Algorithms using Multilevel Modulus (다중레벨 Modulus를 사용한 블라인드 등화 알고리즘의 성능 분석)

  • 오길남
    • Proceedings of the IEEK Conference
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    • 2001.09a
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    • pp.69-72
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    • 2001
  • 본 논문에서는 디지털 통신 시스템의 블라인드 등화에 있어서, 다중레벨 modulus를 기준 신호로 사용하여 등화기의 탭 계수 갱신 식에 사용되는 오차 신호를 형성함으로써 등화기의 블라인드 수렴 특성을 개선한 다중레벨 modulus 알고리즘들의 성능을 분석하였다. 다중경로 채널 하에서 QAM 신호점에 대해 컴퓨터 모의실험을 통하여 단일/다중레벨 modulus 알고리즘(SMMA)과 기존의 modified constant modulus algorithm(MCMA) 및 최근에 제안된 다중레벨 modulus 알고리즘(MMA) 등의 블라인드 수렴 및 정상 상태 성능을 비교하였다.

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