• Title/Summary/Keyword: S-Glass

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Studies on the Physico-chemical Properties of Mixed Radioactive Waste Glass

  • Kim, C.W.;Choi, J.R.;Ji, P.K.;Park, J.K.;Shin, S.W.;Ha, J.H.;Song, M.J.;Hwang, T.W.;Park, S.J.
    • Journal of Radiation Protection and Research
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    • v.29 no.1
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    • pp.33-39
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    • 2004
  • In order to vitrify the W1 waste (ion-exchange resin(IER), zeolite, and dry active waste(DAW)) generated from Korean Nuclear Power Plants, a glass formulation development based on waste compositions and production rates was performed. A aluminoborosilicate glass, AG8W1, was formulated to vitrify the W1 waste in an induction cold crucible melter(CCM). The processability, product performance, and economics of the candidate glass were calculated using a computer code and were measured experimentally in the laboratory and CCM. The glass viscosity and electrical conductivity as the process parameters were in the desired ranges. Start-up and maintaining glass melt of the candidate glass were favorable in the CCM. The product quality of the glass such as chemical durability, phase stability, etc. was satisfactory. The vitrification process using the candidate glass was also evaluated to be operated as economically as possible.

Characterization and Evaluation of Worker s Exposure to Airborne Glass Fibers in Glass Wool Manufacturing Industry (유리섬유 단열재 제조업 근로자의 공기중 유리섬유 폭로 특성 및 평가 방법에 관한 연구)

  • 신용철;이광용;박천재;이나루;정동인;오세민
    • Journal of Environmental Health Sciences
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    • v.22 no.2
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    • pp.43-57
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    • 1996
  • To characterize worker's exposure to glass fibers, to find the correlation between airborne total dust concentrations and fiber concentrations and to recommend an appropriate evaluation method for worker's exposure to fibrous dusts in glass wool industry, we carried out this study. Average respirable fiber levels at five factories were 0.013-0.056 f/cc, and fairly below the OSHA PEL, 1 f/cc. A factory showed the lowest airborne fiber level, 0.013 f/cc, which was different significantly from those of other factories of which average fiber concentration was 0.046 f/cc. The cutting and grinding operations of insulation products resulted in higher airborne fiber cocentrations than any other processes(p<0.05). To characterize airborne fiber dimension, fiber length and diamter were determined using phase contrast microscope. The geometric means of airborne fiber lengths were $42-105 \mu m$. One factory had airborne fibers whose length distribution(GM = $105 \mu m$) was different from those of other factories(GM = $42-50 \mu m$). The percentages of respirable fibers less thinner than 3 gm were 38.9-90.9% at four factories, and two factories of them had the higher percentages than others. The findings explain for variation of airborne fiber diameters between factories. On the other hand, between the processes were the difference of fiber-length distributions observed. The cutting and grinding operations showed shorter fiber-length distributions than the fiber forming one. However, fiber-diameter distributions or respirable fiber contents were similar in all processes. The airborne fiber concentrations and the dust concentrations had relatively weak correlation(r=0.25), thus number of fibers couldn't be expected reliably from dust amount. Fiber count is appropriate for assessing accurate exposures and health effects caused by fibrous dusts including glass fibers. Ministry of Labor have established occupational exposure limit to glass fibers as nuisiance dust, but should establish it on the basis of respirable fiber concentration to provide adequate protection for worker's health

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Porosity Control of the Sealing Glass for Joining Alumina Components in a NaS Battery Cell Packaging (NaS 배터리 셀 패키지의 알루미나 컴포넌트 접합용 Sealing Glass의 기공율 제어)

  • Kim, Chi Heon;Heo, Yu Jin;Kim, Hyo Tae
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.4
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    • pp.57-61
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    • 2016
  • Thick film sealing glass paste is required for cell packaging of NaS based battery for energy storage system, to join the beta-alumina electrolyte tube and the alpha-alumina battery cell cap components. This paper presents the effect of the particle sizes of seal glass powder and the sealing temperatures on the microstructure of the glass sealants was investigated. It was found that the larger in the particle size of seal glass powder, the smaller the pore volume and the number of pores in a unit area. Also, the number of pores decreased with increasing the sealing temperatures while the pore size was increased. This result enables the control of porosity, pore distribution and number of pores in a microstructure of glass sealing component by proper selection of glass powders particle size and sealing temperature.

Experimental Study and Finite Element Analysis about Vehicle Laminated Glass Subject to Headform Impact (머리모형 충돌에 의한 자동차 접합유리의 실험적 연구 및 유한요소해석)

  • Choi, Jihun;Oh, Wontek;Kim, Jonghyuk;Park, Jongchan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.25 no.3
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    • pp.374-379
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    • 2017
  • In vehicle to pedestrian accidents, cracks occur in the vehicle laminated glass due to impact of a pedestrian's head. In this study, FMH(Free Motion Headform) was used to experiment on and analyze the crack patterns on a vehicle laminated glass that collides with an adult headform at speeds of 20 km/h, 30 km/h, and 40 km/h, respectively. Applying the acquired experimental data and material property of the vehicle laminated glass to the structural analysis program LS-Dyna, we could develop the FE model of vehicle laminated glass similar to real vehicle laminated glass. We could estimate the head impact velocity and pedestrian's vehicle impact velocity using the Madymo program.

HELIUM CONCENTRATION DECREASE DUE TO AIR ENTRAINMENT INTO GLASS FIBER COOLING UNIT IN A HIGH SPEED OPTICAL FIBER DRAWING PROCESS (광섬유 고속인출공정용 유리섬유 냉각장치 내 공기유입에 의한 내부헬륨농도 저하현상 연구)

  • Kim, K.;Kim, D.;Kwak, H.S.;Park, S.H.;Song, S.H.
    • Journal of computational fluids engineering
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    • v.15 no.4
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    • pp.92-98
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    • 2010
  • In a modern high speed drawing process of optical fibers, it is necessary to use helium as a cooling gas in a glass fiber cooling unit in order to sufficiently cool down the fast moving glass fiber freshly drawn from the heated silica preform in the furnace. Since the air is entrained unavoidably when the glass fiber passes through the cooling unit, the helium is needed to be injected constantly into the cooling unit. The present numerical study investigates and analyzes the air entrainment using an axisymmetric geometry of glass fiber cooling unit. The effects of helium injection rate and direction on the air entrainment rate are discussed in terms of helium purity of cooling gas inside the cooling unit. For a given rate of helium injection, it is found that there exists a certain drawing speed that results in sudden increase in the air entrainment rate, which leads to the decreasing helium purity and therefore the cooling performance of the glass fiber cooling unit. Also, the helium injection in aiding direction is found to be more advantageous than the injection in opposing direction.

Fabrication of Glass Ceramics for Dental Artificial Tooth(II) -Biocompatibility- (인공 치아용 결정화 유리의 제조(II) - 생체적합성)

  • 유기수;한복섭
    • Journal of Biomedical Engineering Research
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    • v.14 no.3
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    • pp.257-264
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    • 1993
  • A study on the biocompatibility of two types of new glass-ceramics materials, metal disc and dental porcelain that were already made for dental artificial tooth in the previous study, have been attempted. The chemical behavior and the Victor's hardness change in she artificial saliva and Ringer's solution have been also investigated. From the experiment of Implantation of glass-ceramics Into dorsal subcutaneous tissue of Sprague-Dawley rats, glass-cerarmics did not show any particular system of rejection for histrocompatibility.

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THE EFFECT OF ACID ETCHING ON GLASS IONOMER CEMENT SURFACES (Glass ionomer cement 표면의 산부식 효과에 관한 연구)

  • Han, Seung-Weon;Park, Sang-Jin;Min, Byung-Soon;Choi, Ho-Young;Choi, Gi-Woon
    • Restorative Dentistry and Endodontics
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    • v.18 no.1
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    • pp.1-26
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    • 1993
  • The purpose of this study was to investigate the effect of acid etching on the surface appearance and fracture toughness of five glass ionomer cements. Five kinds of commercially available glass ionomer cements including chemical curing filling type, chemical curing lining type, chemical curing metal reinforced type, light curing tilling type and light curing lining type were used for this study. The specimens for SEM study were fabricated by treating each glass ionomer cement with either visible light curing or self curing after being inserted into a rubber mold (diameter 4mm, depth 1mm). Some of the specimens were etched with 37% phosphoric acid for 0, 15, 30, 60, go seconds, at 5 minutes, 1 hour and 1 day after mixing of powder and liquid. Unetched ones comprised the control group and the others were the experimental groups. The surface texture was examined by using scanning electron microscope at 20 kV. (S-2300, Hitachi Co., Japan). The specimens for fracture toughness were fabricated by curing of each glass ionomer cement previously inserted into a metal mold for the single edge notch specimen according to the ASTME399. They were subjected to a three-point bend test after etching for 0, 30, 60, and 90 seconds at 5 minutes-, 1 hour-and 1 day-lapse after the fabrication of the specimens. The plane strain fracture toughness ($K_{IC}$) was determined by three-point bend test which was conducted with cross-head speed of 0.5 mm/min using Instron universal testing machine (Model No. 1122) following seven days storage of the etched specimens under $37^{\circ}C$, 100% humidity condition. Following conclusions were drawn. 1. In unetched control group, crack was present, but the surface was generally smooth. 2. Deterioration of the surface appearance such as serious dissolving of gel matrix and loss of glass particles occured as the etching time was increased beyond 15 s following Immediate etching of chemical curing type of glass ionomer cements. 3. Etching after 1 h, and 1 d reduced surface damage, 15 s, and 30s etch gave rough surface appearance without loss of glass particle of chemical curing type of glass ionomer cements. 4. Light curing type glass ionomer cement was etched by acid, but there was no difference in surface appearances according to various waiting periods. 5. It was found that the value of plane stram fracture toughness of glass ionomer cements was highest in the light curing filling type as $1.79\;MNm^{-1.5}$ followed by the light curing lining type, chemical curing metal reinforced type, chemical curing filling type and chemical curing lining type. 6. The value of plane stram fracture toughness of the chemical curing lining type glass ionomer cement etched after 5 minutes was lower than those of the cement etched after 1 hour or day or unetched (P < 0.05). 7. Light curing glass ionomer cement showed Irregular fractured surface and chemical curing cement showed smooth fractured surface.

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A Study on the Preparation of CdS Doped $SiO_2$ Glass Coating Films by Sol-Gel Method (졸-겔법에 의한 CdS 분산 $SiO_2$ Glass 코팅막의 제조에 관한 연구)

  • 박한수;김경문;문종수
    • Journal of the Korean Ceramic Society
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    • v.30 no.11
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    • pp.897-904
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    • 1993
  • CdS doped SiO2 glass coating films which are good candidates for the nonlinear optical materials were prepared by the Sol-Gel method. TEOS, C2H5OH, H2O and HCl were used as starting materials to obtain SiO2 matrix solutions. Then Cd(NO3)2.2H2O and CS(NH2)2 were dissolved into the SiO2 matrix solutions. Coating was performed several times in order to increase the thickness of coated film by the dip-coating method. Then heat treatments were carried out to control the size of CdS microcrystals doped in SiO2 glass matrix with respect to temperatures and times. CdS-doped SiO2 transparent coating films were successfully obtained. CdS crystals were changed from cubic to hexagonal type about $600^{\circ}C$.

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