• Title/Summary/Keyword: S-47

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Biodegradation of Cutting Oil by Pseudomonas aeruginosa KS47 (Pseudomonas aeruginosa KS47에 의한 절삭유의 생물학적 분해)

  • Kim, Lan-Hee;Lee, Sang-Seob
    • Korean Journal of Microbiology
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    • v.44 no.1
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    • pp.22-28
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    • 2008
  • Cutting oils are emulsionable fluids widely used in metal working processes. Their composition is mineral oil, water, and additives (fatty acids, surfactants, biocides, etc.) generating a toxic waste after a long use. Cutting oils also affect colour, taste and odour of water, making it undesirable for domestic and industrial uses. In these days, conventional treatment methods as evaporation, membrane separation or chemical separation have major disadvantages since they generate a concentrated stream that is more harmful than the original waste. In this study, our purpose is to reduce cutting oils by using biological treatment. Eighty one strains were isolated from cutting waste oil of industrial waste water sludge under aerobic conditions. Among these strains, KS47, which removed 90.4% cutting oil in 48 hr, was obtained by screening test under aerobic conditions(pH 7, $28^{\circ}C$). KS47 was identified as Pseudomonas aeruginosa according to morphological, physiological and biochemical properties, 16S rDNA sequence, and fatty acid analysis. P. aeruginosa KS47 could utilize cutting oil as carbon source. In batch test, we obtained optimal degradation conditions(1.5 g/L cell concentration, pH 7, and temperature $30^{\circ}C$). Under the optimal conditions, 1,060 mg/L cutting oil was removed 83.7% (74.1 mg/L/hr).

Solvolysis of Phenylacetyl Chlorides in Methanol-Acetonitrile Mixtures

  • Lee Ikchoon;Huh Chul;Lee Hai Whang
    • Bulletin of the Korean Chemical Society
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    • v.10 no.1
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    • pp.47-50
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    • 1989
  • The methanolysis reactions of phenylacetyl chlorides have been investigated in methanol-acetonitrile mixtures at temperatures ranging - $15.0-0.0^{\circ}C.$ Substituent and solvent effects on the rate supported an associative $S_N2$ mechanism for the solvolysis. Activation parameters indicated that the reaction is entropy controlled, while the a/s ratios of the Taft's solvactochromic correlation proved to be remarkably constant with a typical value of 0.50 that is consistent for the reactions proceeding by a typical $S_N2$ path.

Conjugate Heat Transfer in Cylindrical Annulus for an Insulated Tube (단열관을 위한 원통 환상공간 내에서의 복합 열전달)

  • Kang, B.H.;Yang, S.H.;Kwon, S.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.4
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    • pp.633-641
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    • 1995
  • The effect of the gap width on conjugate heat transfer in the cylindrical annulus for an insulated tube has been studied numerically by the finite difference method. The parameters considered here are the Rayleigh number, Ra, the dimensionless insulated wall thickness, $W/D_i$ and the dimensionless gap width, S/W. As S/W increases, the mean wall temperature increases at the inside wall of annulus and decreases at the outside walls of annulus and the insulated tube at $S/W{\leq}0.5$, and then slightly increases at $Re=10^4$, $W/D_i=1.47$. The heat transfer rate decreases at $S/W{\leq}0.5$ and then increases apparently as S/W increases at $Re=10^4$, W/Df=1.47. Therefore, it is considered that $$S/W{\sim_=}0.5$$ is the optimum gap width for the effect of insulation at $Re=10^4$, $W/D_f=1.47$.

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