• Title/Summary/Keyword: Rubidium

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Crystallographic Studies of Dehydrated Zeolite-X Reacting with Rubidium Vapor (루비듐 증기로 처리한 탈수한 제올라이트 X의 결정학적 연구)

  • Han, Young Wook
    • Journal of the Mineralogical Society of Korea
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    • v.6 no.2
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    • pp.116-121
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    • 1993
  • A single crystla of zeolite $Na_{78}Rb_{28}-X$ (approximate composition) was prepared by exposing $Na_{92}-X$ at $350^{\circ}C$ to 0.1 Torr of rubidium vapor, and its structure was determined by single-crystal x-ray diffraction methods in the cubic space group, Fd3, ${\alpha}=25.045(4){\AA}$. The structure was refined to the final error indices $R_1=0.082$ and $R_2=0.084$ with 353 for which I>$3{\sigma}(I)$. Only about 28 of the 92 $Na^+$ ions per unit cell were reduced and only about 14 of the 28 $Na^0$ atoms produced were retained within the zeolite. A $Na_5{^{4+}}$ cluster is present within each sodalite cavity. It is a centered tetrahedron (like $CH_4$) with bond $length=2.80(2){\AA}$ and angle tetrahedral by symmetry, and shows the full symmetry of its site. $T_d$, at the center of the sodalite cavity. Each of the four terminal atoms of the $Na_5{^{4+}}$ cluster bond to three framework oxygens at $2.36(2){\AA}$. At the centers of some double 6-rings are sodium atoms which bridge linearly between $Na_5{^{4+}}$ clusters to form agglomerations such as short zig-zag chains $Na_5{^{4+}}$ clusters. Delocalized electrons, located primarily on the sodiums at centers of the sodalite and (likely) double-six-ring cavities, contribute to the stability of the clusters.

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Radiopharmaceuticals Used in Cardiac Imaging (심장영상에 이용되는 방사성의약품)

  • Hwang, Kyung-Hoon;Chung, Yong-An;Lee, Byeong-Il;Lee, Yu-Kyung;Lee, Min-Kyung;Choe, Won-Sick
    • Nuclear Medicine and Molecular Imaging
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    • v.43 no.3
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    • pp.174-178
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    • 2009
  • Many radiopharmaceuticals have been developed and wildy used in the imaging cardiac function. Myocardial perfusion imaging (MPI) is a well established noninvasive method of assessing coronary blood flow and has been widely used in patients diagnosed or suspected with coronary artery diseases. The innovation of radiopharmaceuticals used in the cardiac imaging is one of the most important contributors to the development of nuclear cardiology. Thallium-201 and various technetium-99m agents have been globally used for myocardial perfusion SPEG, and N-13 ammonia (13NH3), rubidium-82 (82Rb), 0-15 water (H2150) for myocardial perfusion PET. As well as the cardiac perfusion studies, new radiopharmaceuticals that visualize fat metabolism or receptors of the sympathetic nervous system have successfully been applied to clinical practice. Useful information can be obtained for diagnosing coronary artery disease, evaluating patients' condition, or assessing therapeutic effects. In this review, we describe the characteristics and clinical usefulness of radiopharmaceuticals used for cardiac SPEG and PET.

Velocity selective optical pumping spectroscopy (속도군 선택 광펌핑 분광학)

  • Park, Sung-Jong;Cho, Hyuck;Lee, Ho-Seong
    • Korean Journal of Optics and Photonics
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    • v.8 no.5
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    • pp.366-371
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    • 1997
  • We performed the velocity selective optical pumping(VSOP) spectroscopy using the rubidium atomic vapor in the room temperature. This spectroscopic technique removes the Doppler broadening by both optical pumping effect and the selection of atoms with a particular velocity. In this experiment, we used two independent lasers; one was a locked laser whose frequency was fixed and the other was a sweep laser whose frequency was tunable. The two beams were passing through the sample in the same direction unlike the conventional VSOP spectroscopy using two counter-propagating beams. We could make the velocity selective range of atoms much wider with this method than the old one.

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Synthesis and Crystal Structures of Alkali Lithium Molybdates and Alkali Lithium Tungstates (알칼리 리치움 몰리브덴산염과 알칼리 리치움 텅그스텐산염의 합성과 결정구조)

  • 정수진
    • Journal of the Korean Ceramic Society
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    • v.22 no.3
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    • pp.72-76
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    • 1985
  • Single crystals of the compound MeI $(LiMoO_4)$ and $Me^I(LiWO_4)$ ($Me^I=K$, Rb, Cs) were synthesized by slow evaporation from aqueous solution and bycooling from melt. The compounds of potassium or rubidium are hygroscopic and they form easily hydrated crystals $Me^I LiMoO_4$.$H_2O$ or $Me^ILiMoO_4$.$H_2O$ or $Me^ILiWO_4$.$H_2O$ from aqueous solution. The structures of these hydrated crystals are each other isotypic and they are built up of distorted layers of $(LiMoO_5)$ or $(LiWO_5)$. There exist two types of tetrahedral framework structures in this group of anhydrous molybdates and tung-states ; tridymite-type and cristobalite-type. $KLiMoO_4$ and $KLiWO_4$ have two types of polymorphic structures where as only the cristobalite-type is found in the Rb-and Cs-compounds. The system $KLiSO_4-KLiMoO_4$ was studied. Two components are almost immiscible but there eixst a narrow area of solid solution on the side of sulfate in the system.

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Stable isotope and water quality analysis of coal bed methane produced water in the southern Qinshui Basin, China

  • Pan, Jienan;Zhang, Xiaomin;Ju, Yiwen;Zhao, Yanqing;Bai, Heling
    • Membrane and Water Treatment
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    • v.4 no.4
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    • pp.265-275
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    • 2013
  • China is one of the countries with the highest reserves of coal bed methane (CBM) in the world. Likewise, the CBM industry is significantly growing in China. However, activities related to CBM development have led to more environmental problems, which include serious environmental damage and pollution caused by CBM-produced water. In this paper, the detailed characteristics of CBM-produced water in the southern Qinshui Basin were investigated and analyzed and compared with local surface water and coal mine drainage. Most of CBM-produced water samples are contaminated by higher concentration of total dissolved solids (TDS), K (Potassium), Na (Sodium) and $NH_4$. The alkalinity of the water from coalmines and CBM production was higher than that of the local surface water. The concentrations of some trace elements such as P (Phosphorus), Ti (Titanium), V (Vanadium), Cr (Chromium), Ni (Nickel), Zn (Zinc), Ge (Germanium), As (Arsenic), Rb (Rubidium), and Pd (Palladium) in water from the coalmines and CBM production are higher than the acceptable standard limits. The ${\delta}D$ and ${\delta}^{18}O$ values of the CBM-produced water are lower than those of the surface water. Similarly, the ${\delta}D$ values of the CBM-produced water decreased with increasing drainage time.

Preparation of $^{82}Sr/^{82}Rb$ Generator and Positron Emission Tomographic Image of Normal Volunteer ($^{82}Sr/^{82}Rb$ 발생기의 제조 및 정상인 심근의 양전자 단층촬영상)

  • Jeong, Jae-Min;Chung, June-Key;Lee, Dong-Soo;Kwark, Cheol-Eun;Lee, Kyung-Han;Lee, Myung-Chul;Koh, Chang-Soon
    • The Korean Journal of Nuclear Medicine
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    • v.28 no.3
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    • pp.326-330
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    • 1994
  • A $^{82}Sr/^{82}Rb$ generator was prepared by loading $^{82}Sr$ to preconditioned tin dioxide column. The generator was eluted by normal saline with flow rate up to 8m1/min, and the eluted radioactivity was monitored by dose calibrator. Radioactivity began to come out at 5ml and reached to peak around 9ml. The total eluted radioactivity increased linearly with flow rate, and the maximum obtained radioactivity was 35mCi at 8m1/min. The $^{82}Rb$ preparation was proven to be free from both strontium radioactivity and pyrogen. The $^{82}Rb$ was injected to normal female volunteer and positron emission tomographic Image of heart was obtained successfully.

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Optimization of a Radio-frequency Atomic Magnetometer Toward Very Low Frequency Signal Reception

  • Lee, Hyun Joon;Yu, Ye Jin;Kim, Jang-Yeol;Lee, Jaewoo;Moon, Han Seb;Cho, In-Kui
    • Current Optics and Photonics
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    • v.5 no.3
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    • pp.213-219
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    • 2021
  • We describe a single-channel rubidium (Rb) radio-frequency atomic magnetometer (RFAM) as a receiver that takes magnetic signal resonating with Zeeman splitting of the ground state of Rb. We optimize the performance of the RFAM by recording the response signal and signal-to-noise ratio (SNR) in various parameters and obtain a noise level of 159 $fT{\sqrt{Hz}}$ around 30 kHz. When a resonant radiofrequency magnetic field with a peak amplitude of 8.0 nT is applied, the bandwidth and signal-to-noise ratio are about 650 Hz and 88 dB, respectively. It is a good agreement that RFAM using alkali atoms is suitable for receiving signals in the very low frequency (VLF) carrier band, ranging from 3 kHz to 30 kHz. This study shows the new capabilities of the RFAM in communications applications based on magnetic signals with the VLF carrier band. Such communication can be expected to expand the communication space by overcoming obstacles through the high magnetic sensitive RFAM.

Development and Characterization of Mobile Transceiver for Millimeter-Wave Channel Sounding Measurement (밀리미터파 채널사운딩 측정을 위한 이동형 송수신 장치의 개발과 특성평가)

  • Jonguk Choi
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.24 no.3
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    • pp.35-40
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    • 2024
  • In this paper, the design, implementation, and analysis of a device capable of transmitting and receiving millimeter-wave signals and performing channel sounding measurements in atmospheric conditions at distances of up to approximately 10km outdoors are presented. The device is expected to be instrumental in studying the propagation characteristics of millimeter-wave frequencies. Utilizing data such as received power levels and power delay profiles (PDPs), comparisons with predicted values using path loss, K-factor, and other propagation models are facilitated. The mobile transceiver unit, integrated onto a vehicle platform, allows for flexible adjustment of transmitter and receiver positions, while synchronization issues with distance are mitigated using a rubidium atomic clock. Furthermore, automatic boresight alignment using scanning techniques is employed to locate the main sector of the antenna.

Estimation of GPS Holdover Performance with Ladder Algorithm Used for an UFIR Filter (UFIR 필터 Ladder 알고리즘 이용 GPS Holdover 성능 추정)

  • Lee, Young-kyu;Yang, Sung-hoon;Lee, Chang-bok;Heo, Moon-beom
    • Journal of Institute of Control, Robotics and Systems
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    • v.21 no.7
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    • pp.669-676
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    • 2015
  • In this paper, we described the simulation results of the phase offset performance of a clock in holdover mode which was normally operated in GPS Disciplined Oscillator (GPSDO). In the TIE model, we included the time error term caused by environmental temperature variation because one of the most important parameters of clock phase error is the frequency offset and drift caused by the variation of temperature. For the simulation, we employed Maximum Time Interval Error (MTIE) for the performance evaluation when the frequency offset and drift are estimated by using an Unbiased Finite Impulse Response (UFIR) filter with ladder algorithm. We assumed that the noise in the GPS measurement is white Gaussian with zero mean and 1 ns standard deviation, and temperature linearly varies with a slope of $1{^{\circ}C}$ per hour. From the simulation results, the followings were observed. First, with the estimation error of temperature of less than 3 % and the temperature compensation period of less than 900 seconds, the requirement of CDMA2000 phase synchronization under 10 us could be achieved for more than 40,000 seconds holdover time if we employ an OCXO (Oven Controlled Crystal Oscillator) clock. Second, in order to achieve the requirement of LTE-TDD under 1.5 us for more than 10,000 seconds holdover time, below 3 % estimation error and 500 seconds should be retained if a Rubidium clock is adopted.

A Study on the Constituents of Pyrolusitum by XRD and XRF (XRD와 XRF를 이용한 무명이(無名異)의 구성 성분 연구)

  • Lee, Minwoo;Choi, Goya;Lee, Young-Jong
    • The Korea Journal of Herbology
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    • v.33 no.6
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    • pp.87-92
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    • 2018
  • Objectives: The aim of the study was to analyze the constituents of Pyrolusitum, which was used to eliminate static blood and inflammation, to establish the basis of clinical application. Methods: Qualitative analysis was performed by X-Ray Diffraction (XRD) using the sample as a powder, and the elemental content of granular sample was measured by X-Ray Fluorescence (XRF). 1 M hydrochloric acid and 5% sodium hydroxide aqueous solution were added to observe the changing shape, respectively. Results: Qualitative analysis by XRD revealed that the Pyrolusitum samples used in the study contained quarts and kaolinite. Quantitative analysis by XRF revealed that the manganese content in the samples used in the study was 6.16% on average, while iron was contained the highest amount of 22.99%. The minor constituents include 1.08% of titanium, 0.30% of barium, 0.18% of lead, 0.06% of zirconium, 0.05% of chromium, 0.04% of zinc, 0.03% of cadnium, 0.02% of nickel, 0.01% of arsenic, 0.01% of copper, 0.01% of rubidium, 0.01% of strontium, 0.00% of molybdenum, respectively. And cobalt, which is reported to be a constituent of Pyrolusitum, was not detected at all in the samples of the study. Pyrolusitum was dissolved in dark brown when it was put into 1 M hydrochlorid acid, and there was brown precipitate when sodium hydroxide solution was added to Pyrolusitum and stirred. Conclusions: It was found that manganese and iron were the major constituents of Pyrolusitum, and it could be identified by using concentrated hydrochloric acid and sodium hydroxide solution.