• Title/Summary/Keyword: Rubber Materials

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Preparation and Characterization of Wood Polymer Composite by a Twin Screw Extrusion (이축 압출공정을 이용한 Wood Polymer Composite의 제조 및 특성 분석)

  • Lee, Jong-Hyeok;Lee, Byung-Gab;Park, Ki-Hun;Bang, Dae-Suk;Jhee, Kwang-Hwan;Sin, Min-Cheol
    • Elastomers and Composites
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    • v.46 no.3
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    • pp.211-217
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    • 2011
  • Wood Polymer Composite (WPC) has attracted a great deal of attention in environmental industries due to renewable resources, processability, excellent physical properties and logging regulations for application to housing units and engineering construction materials. In this study, commercial WPCs were prepared by using a modular intermeshing co-rotating twin screw extruder. The effect of three main factors such as wood flour contents, coupling agent concentrations and pre-treatment of wood flour on the properties of WPCs was extensively investigated. It was found that tensile strength and thermal stability were decreased with increasing wood flour contents whereas the water absorption was increased. Addition of maleic anhydride grafted polypropylene (PP-g-MA) into WPC exhibited better physical properties. On the contrary, the water absorption was slightly decreased with PP-g-MA. Finally the sample, which was prepared with pre-treated wood flour, represented the highest tensile strength. However, the water absorption of the sample was increased due to the transition of crystalline structure of cellulose.

A Study on the Manufacturing and Mechanical Properties of the PA66/EPDM/PP Composites for Enhanced Low Temperature Fracture Resistances (저온 내충격성 향상을 위한 PA66/EPDM/PP 복합체 제조와 기계적 특성 연구)

  • Lee, Tae-Sik;Yoon, Chang-Rok;Bang, Dae-Suk;Ahn, Dae-Young;Kye, Hyoung-San;Shin, Kyung-Chul
    • Elastomers and Composites
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    • v.44 no.2
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    • pp.164-174
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    • 2009
  • PA66/EPDM/PP-g-MA and PA66/EPDM-g-MA/PP-g-MA composites were manufactured by a modular intermeshing twin screw extruder for enhanced low temperature impact resistance with different content of PP-g-MA. The results showed that composite containing 90 wt% of PA66, 8 wt% of EPDM-g-MA, and 2 wt% of PP-g-MA has a optimum value in the thermal and mechanical properties. The characteristics of the composites were analyzed by TGA, DSC, and SEM. From above results, we established that the low interfacial strength and the impact resistance at low temperature shown in a pre-existing PP/EPDM composite were enhanced by grafting with compatibilizer such as maleic anhydride. These results show the possibility of local manufacturing process and cost down with optimum screw configuration for best mixing quality in the twin screw extruder.

Melt Grafting of EPDM and Itaconic Acid: Effect of Reaction Conditions and Initiator Type/Concentration (Ethylene-propylene-diene terpolymer (EPDM)와 itaconic acid의 melt grafting: 반응조건과 개시제 종류 및 농도의 영향)

  • Kim, Ki-Jae;Bae, Jong-Woo;Kim, Jung-Soo;Lee, Jin-Hyok;Kim, Gu-Ni;Oh, Sang-Taek;Kim, Wonho
    • Elastomers and Composites
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    • v.49 no.3
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    • pp.181-190
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    • 2014
  • Melt grafting of itaconic acid (IA) onto an ethylene-propylene-diene terpolymer (EPDM) with various organic peroxide initiators was performed. Finding the optimum mixing conditions and concentration of ingredients is critical for effective grafting and optimum properties of grafted materials. This study focused on the effects of mixing conditions (temperature and time), initiator type/concentration and monomer concentration on the grafting degree and efficiency, melt flow index, and gel content of EPDM-g-IA. The initiator, 2,5-dimethyl-2,5-di(tert-butyl peroxy)-hexane (T-101), appeared to meet for the best grafting degree (1.91%). The grafting degree increased markedly by increasing the amounts of monomer IA and initiator T-101. The grafting degree also increased by increasing mixing temperature and time. The optimum monomer and initiator concentrations and reaction temperature and time were found to be about 5wt%/0.05wt% and $160^{\circ}C$/15min, respectively. It was found that the physical properties of EPDM-g-IA were higher than those of the pristine EPDM.

A Study on the Water Resistance and Thermo-mechanical Behaviors of Epoxy Adhesives (에폭시 접착제의 내수성, 열적 및 기계적 물성에 관한 연구)

  • Park, Soo-Jin;Kim, Jong-Hak;Choi, Kil-Yeong;Joo, Hyeok-Jong;Jin, Fan-Long
    • Elastomers and Composites
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    • v.40 no.3
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    • pp.166-173
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    • 2005
  • Effect of thermal aging on the weight loss and water absorption of epoxy adhesives was investigated in the presence of three types of different hardeners, such as D-230, G-5022, and HN-2200. Thermal and mechanical properties of the cured epoxy resins were also studied througth the glass transition temperature and shear adhesion strength measurements. Weight losses of DGEBA/D-230 and DGEBA/HN- 2200 systems were not varied. However, the weight of DGEBA/G-5022 system was significantly decreased with increasing the thermal aging time. The water absorption of the specimens was increased as the thermal aging time increased except that using G-5022. DEGBA/HN-2200 system showed higher $T_g$ value than those of other systems, due to the formation of the fine three-dimensional network structure containing aliphatic ring. Shear adhesion strength of all systems was increased with increasing the thermal aging tine, which is attributed to increased degree of cure and fine three-dimensional network structure formation. And $T_g$ values and shear adhesion strength of all specimens exposed to water was decreased as the immersion time increased.

A Study on the Noxious Materials in the Waste Shipped into Solid Recovered Fuel(SRF) Facilities and Their Influence (고형연료(SRF)시설로 반입되는 폐기물의 영향 및 유해성물질 등에 관한 연구)

  • Lee, Seung-Won;Kim, Sang-Hun;Lee, Sang-Seok;Kim, Jung-Kwon
    • Journal of Environmental Science International
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    • v.27 no.2
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    • pp.91-97
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    • 2018
  • This study carried out first a component survey on the domestic waste shipped into a waste disposal facility in B city, and then heavy metal analysis of each component according to the SRF standards. Based on this, this study explored the problems with domestic waste and measures to improve them. The results are as follows. The result of the survey of physical components show that paper accounted for the largest proportion with 20.5 %~59.9 %, metals (including batteries) among incombustibles accounted for 0.0~8.3 %, other inorganic substances, glass and ceramics accounted for 0.0~43.7 % and 0.0 %~19.6 % respectively. However, the proportion of coated viny and plastics, which have high lead and cadmium content, was rather high with 2.9 %~30.9 %. This suggests the possibility that actual concentration of lead and cadmium within SRF is likely to be higher. Among the 15 components contained in the waste brought into the waste disposal facility, 10 components (food waste, textiles, vinyl, plastics, wood, rubber and leather, paper, metals, electronic substrates, and nail polish) were analyzed according to assay samples (approximately 0.1 g and 0.3 g). The result of analysis shows that the amount of Cd and Pb detected in coated vinyl for 0.109 g of assay sample was 98.6 mg/kg and 20.6 mg/kg respectively; 117.0 mg/kg and 29.0 mg/kg respectively for 0.313 g of assay sample. This is high contents exceeding the Cd standard. As for wooden component, the amount of Pb was 480.0 mg/kg for 0.3 g of assay sample. This suggests that there always exists the possibility of exceeding the exposure level of heavy metals (Cd and Pb) in SRF as long as coated wood and vinyl plastics with high contents of Pb and Cd are shipped into the waste disposal facility; and the local government and the residents need to work hard to improve the situation including development of the machine to sort electronic substrates and batteries for separate collection of the waste of coated vinyl and plastics within domestic waste.

The Effect of Various Plaque Control Devices on Roughness and Morphology of Titanium Implant Surface (다양한 치태조절기구가 타이타늄 임프란트의 표면조도와 형태에 미치는 영향)

  • Choi, Seoung-Hwan;Lim, Jeong-Su;Song, In-Taeck;Kim, Hyoug-Seop
    • Journal of Periodontal and Implant Science
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    • v.28 no.2
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    • pp.337-350
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    • 1998
  • The purpose of this' study was to compare surface roughness and morphologic changes after use of various plaque control devices to titanium implant surfaces. The study materials were 6 ITI titanium implants($Bonefit^{(R)}$) and 5 plaque control devices. 6 implants were divided into 6 different groups and instrumented by each plaque control devices as follows. 1) Group I : untreated control 2) Group II : Titanium curette(Titanium $curette^{(R)}$, 3i) 80 vertical/horizontal strokes 3) Group III : Plastic curette($Implacare^{(R)}$, Hu-Friedy) 80 vertical/horizontal strokes 4) Group N : Plastic tip-ultrasonic scaler($Amdent^{(R)}$, Amdent) 160 seconds 5) Group V : Rotating interdental brush($Identobrush^{(R)}$, Identoflex) 160 seconds 6) Group VI : Abrasive rubber cup polisher($Zircate^{(R)}$, Prophy paste, Dentsply) 160 sec-onds. All specimens were prepared for evaluation by surface roughness tester, optical stereomicroscopy(OM) and scanning electron microscopy(SEM). The Ra and Rt mean values of the tested specimens were 1) Group I ($Ra=0.170{\pm}0.007{\mu}m$, $Rt=1.297{\pm}0.016{\mu}m$) 2) Group II ($Ra=0.209{\pm}0.006{\mu}m$, $Rt=1.602{\pm}0.110{\mu}m$) 3) Group III ($Ra=0.179{\pm}0.001{\mu}m$, $Rt=1.429{\pm}0.055{\mu}m$) 4) Group IV ($Ra=0.182{\pm}0.005{\mu}m$, $Rt=1.511{\pm}0.085{\mu}m$) 5) Group V ($Ra=0.301{\pm}0.008{\mu}m$, $Rt=1.882{\pm}0.131{\mu}m$) 6) Group VI ($Ra=0.147{\pm}0.010{\mu}m$, $Rt=1.059{\pm}0.021{\mu}m$) In Ra values, experimental group II, V, VI were statistically significant different when compared with control. OM and SEM observation showed that experimental group III, IV were minimal changes when compared with control and group VI was smoothest among other experimental groups. The results suggested that plastic curette and plastic tip-ultrasonic scaler were predictable devices to titanium implant surface.

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The Study on the Development of Environmental-friendly Surface Material Using Condensed Tannin (축합형 탄닌을 이용한 친환경 건축마감재 개발에 관한 연구)

  • Jo, Jae-Min;Park, Moon-Soo;Chung, Kyung-Ho
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.199-205
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    • 2010
  • Medium-density fiberboard (MDF) is widely used as an indoor building materials. However, formaldehyde resins, commonly used to bind MDF together, emit formaldehyde and other volatile organic compounds that cause health risk at sufficient concentration. In this study, condensed tannin having formaldehyde absorption ability was used to solve the problem of formaldehyde emission generated from surface material. The synthesis of melamine-formaldehyde resin and reaction of melamine-formaldehyde and condensed tannin were analyzed by FT-IR spectrum. Also surface properties, such as shear force, impact strength, tape adhesion, pencil hardness and gloss retention were measured. Free formaldehyde analysis was performed to analyze remaining unreacted formaldehyde. According to the results, the optimum shear force and impact strength could be obtained by 10 wt.% usage of condensed tannin. In cases of pencil hardness and gloss retention, the optimum properties could be obtained at 20 wt.% of condensed tannin. The amounts of formaldehyde emission of surface material containing 20 wt.% of condensed tannin was 59 ${\mu}g/m^2{\cdot}h$. The amounts of formaldehyde emission could be reduced 3 times by using 20 wt.% of condensed tannin.

Antimicrobial Effect of Various Chopping Boards against Food-borne Bacteria (도마의 재질별 식중독 원인균에 대한 항균효과)

  • Kim, Ji-Young;Lee, Hyoung-Jae;Cho, Jeong-Yong;Lim, Hyun-Cheol;Choi, Gyeong-Cheol;Kim, Du-Woon;Park, Keun-Hyung;Moon, Jae-Hak
    • Korean Journal of Food Science and Technology
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    • v.44 no.1
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    • pp.114-120
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    • 2012
  • The purpose of this study was to evaluate the antibacterial activities of chopping boards made of various materials such as three antibiotic plastics, a general plastic, and various woods (red pine, rubber tree, cypress, birch, and bamboo) using zone inhibition assay and real-time PCR. Wood chopping boards showed high antimicrobial activity against Vibrio vulnificus, while plastic chopping boards showed high antimicrobial activity against Escherichia coli O157:H7, Salmonella Typhimurium, and Staphylococcus aureus. Bamboo chopping board among the wood chopping boards showed the highest antimicrobial activity against five foodborne bacteria such as E. coli O157:H7, S. Typhimurium, Vibrio cholerae, and V. vulnificus. These results may be helpful in the selection of a chopping board with high antimicrobial activity and in the application of hygiene procedures for prevention of cross-contamination.

Field Application of RFID for the Cavity Maintenance of Under Pavement (도로하부 공동의 유지관리를 위한 RFID의 현장 적용성 평가)

  • Park, Jeong Jun;Shin, Eun Chul;Kim, In Dae
    • Journal of the Society of Disaster Information
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    • v.15 no.4
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    • pp.459-468
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    • 2019
  • Purpose: The cavity exploration of the lower part of the road is carried out to prevent ground-sinking. However, the detected communities cannot be identified by the cavity location and history information, such as repackaging the pavement. Therefore, the field applicability of RFID systems was evaluated in this study to enable anyone to accurately identify information. Method: During temporary recovery, tag recognition distance and recognition rate were measured according to underground burial materials and telecommunication tubes using RFID systems with electronic tag chips attached to the bottom of the rubber cap. Result: The perceived distance and perceived rate of depth for each position of the electron tag did not significantly affect the depth up to 15cm, but it did have some effect if the depth was 20cm. In addition, water effects from nearby underground facilities and rainfall are relatively small, and the effects of wind will need to be considered during the weather conditions of the road. Conclusion: The RFID tags for field application of the pavement management system store various information such as location and size of cavity, identification date, cause of occurrence, and surrounding underground facilities to maximize cavity management effect with a system that can be computerized and mobile utilization.

Factors Attributing to the Formation of N-Nitrosamines in Instant Food (즉석 식품에서 니트로사민이 검출되는 요인 분석)

  • Suh, Bokyung;Kwon, Hoonjeong
    • Journal of Food Hygiene and Safety
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    • v.32 no.2
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    • pp.114-122
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    • 2017
  • N-nitrosamines can be produced in the process of heating, processing, storage and packaging. Migration specifications for N-nitrosamines exist only for rubber baby bottle nipples, which are regulated by the Ministry of Food and Drug Safety (MFDS). There is no regulation for other food contact substances (FCS) and studies on N-nitrosamines migration from FCS are rather limited. A pilot study showed an increase in N-nitrosamines contents when cooking instant noodles. Thus, the migration from the packaging was suspected and it was necessary to monitor the migration of N-nitrosamines from food packaging materials and to examine the change in N-nitrosamines contents when cooking instant foods. Three N-nitrosamines, NDMA (N-nitrosodimethtlamine), NDEA (N-nitrosodiethylamine), NDBA (N-nitrosodibutylamine), were analyzed in migration test solutions from plastics such as polyethylene, polypropylene and polystyrene, papers and aluminium containers. In all test solutions, N-nitrosamines were detected less than method quantitation limits (MQLs). Food samples were also investigated to ensure that there is no effect from food contact substances when cooking instant foods. In retort sauces such as curry, black soybean sauce and tomato sauce, NDMA concentration was ranged from 0.54 to $3.81{\mu}g/kg$, but there were no significant differences between unheated and heated samples. However, the NDMA contents were significantly increased in most of the instant noodle samples tested when cooked (p < 0.05). No effects from the food contact substances or cooking water was observed. Only when the seasoning powder and noodles were cooked together was NDMA detected. Individual components (noodle, seasoning powder or dried vegetable) or other combinations such as noodles and dried vegetables did not generate N-nitrosamines. Therefore, it is speculated that NDMA may be formed from the precursors in noodles and seasoning powders when they are solubilized in a medium of water.