• Bulletin of the Korean Chemical Society
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• v.20 no.9
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• pp.1005-1009
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• 1999

Wustite with NaCl structure is successfully synthesized in a quartz tube sealed under vacuum ( ≒1×10 -3 torr). Hematite in an evacuated quartz tube progressively loses oxide ion at 1373 K. XRD patterns disclose that α-Fe2O3 is transformed into the Fe3O4 after heat treatment at 1373 K for 32 h, and the poorly crystallized FeO is appeared after heat treatment for 48 h. Finally, α-Fe2O3 is completely transformed into the well crystallized Fe 0.935O after heat treatment for 84 h. The electrical resistivity, ac-susceptibility measurement, Mossbauer spectroscopy, and x-ray absorption spectroscopy corroborate the structural phase transition on the iron oxides prepared in a sealed quartz tube depending on the heating time at 1373 K.

• Bulletin of the Korean Chemical Society
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• v.21 no.10
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• pp.1049-1051
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• 2000

A chromia-pillared clay has been prepared by ion exchange type intercalation reaction between the sodium ion in montmorillonite and the trimeric chromium oxyformate (TCF) ion, and by subsequent heat-treatment. The structural and thermal properties have been systematically studied by thermal analysis, powder XRD, IR spec-troscopy, and XAS. The gallery height of~6.8 $\AA$ upon intercalation of the TCF ion suggests that the $Cr_3O$ plane is parallel to the aluminosilicate layers. Even though the basal spacing of TCF intercalated clay decreases slightly upon heating, the layer structure was retained up to $550^{\circ}C$ as confirmed by XRD and TG/DTA. Ac-cording to the EXAFS spectroscopic analysis, it is identified that the (Cr-Cr) distance of 3.28 $\AA$ between vertex-linked CrO6 octahedra in TCF splits into 2.64 $\AA$, 2.98 $\AA$, and 3.77 $\AA$ due to the face-, edge-, and corner-shared CrO6 octahedra after heating at $400^{\circ}C$, implying that a nano-sized chromium oxide phase was stabilized within the interlayer space of clay.

• Bulletin of the Korean Chemical Society
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• v.12 no.5
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• pp.525-529
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• 1991

A simple route is described for the selective functionalization of calixarene at the para positions of phenyl rings. Calix[4]arene tetraacetate 2, obtained from the treatment of calix[4]arene with acetic anhydride, undergoes Fries rearrangement to yield the diametrically para substituted p-diacetylcalix[4]arene 3 in 80% yield. The crystal and molecular strucutre has been determined by X-ray diffraction method. The crystals are orthorhombic, space group Pna21, with a = 11.121 (3), b = 10.374 (3), c = 21.690 (6) $\AA$ and Z = 4. The structure was solved by direct method and refined by full-matrix least-squares methods to final R of 0.036 for 1795 observed reflections. Each hydroxyl hydrogen atom is disordered over two positions. The macrocycle exists in the cone conformation which is determined by the strong circular intramolecular flip-flop type hydrogen bonds of phenolic OH, while crystal packing effects of the diametrically para-acetyl substituents seem to be responsible for the distortion of the cone conformation.

• Bulletin of the Korean Chemical Society
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• v.22 no.12
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• pp.1328-1332
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• 2001

The structure and electrochemical properties of the LixCoyNi1-yO2 (y=0.1, 0.3, 0.5, 0.7, 1.0) system synthesized by solid state reaction with various starting materials have been investigated to optimize the characteristics and synthetic conditions of the LixCoyNi1-yO2. The first discharge capacities of LixCoyNi1-yO2 are 60 mAh/g-180 mAh/g with synthetic conditions. Among them, the LixNi0.7Co0.3O2, which was prepared with LiOH, NiO, and Co3O4 at $850^{\circ}C$, had the best electrochemical properties. The first discharge capacity of the compound was 180 mAh/g.

• Journal of Korean Society of Transportation
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• v.16 no.4
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• pp.225-237
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• 1998

본 연구의 목적은 가로망의 구조 및 통행수요의 변화에 따라 통행 중 교통정보제공의 효과가 어떻게 달라지는가를 모의실험을 통하여 분석하고자 하는 것이다. 이를 위하여 본 연구에서는 실제의 대규모 가로망에 대하여 적용할 수 있는 통행배정기법을 제안하였다. 제안된 모형은 시간의 흐름에 따른 가로망의 상태를 고려하여 통행을 배정하는 방법으로 $\ulcorner$시간종속적 통행배정$\lrcorner$이라 명하였다. 본 연구에서는 가로망 형태(격자형 및 방사환상형), 가로망 크기, 통행수요의 지역별 분포, 그리고 교통혼잡정도에 따라 각각 시나리오를 작성하고, 각 시나리오에 대하여 모의실험 및 사례연구(노드 348개, 링크 1179개)를 통해 정보를 받는 차량의 비율에 따른, 그리고 정보를 제공하는 빈도에 따른 통행중 교통정보제공에 대한 효과를 분석하였다. 연구 결과, 모의실험에서는 정보를 받는 차량의 비율이 30%~70% 구간에서 14%까지의 총체계비용의 감소효과가 나타났으며, 가로망의 규모가 클수록, 혼잡이 심할수록, 그리고 대안도로가 많을수록 교통정보제공의 효과는 커지는 것으로 분석되었다.

• Journal of Integrative Natural Science
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• v.12 no.1
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• pp.14-19
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• 2019

In this paper, we propose a system for controlling the brightness of street lights by predicting pedestrian paths, identifying the position of pedestrians with motion sensing sensors and obtaining motion vectors based on past walking directions, then predicting pedestrian paths through the route prediction smart street lighting system. In addition, by using motion vector data, the pre-treatment process using linear interpolation method and the fuzzy system and neural network system were designed in parallel structure to increase efficiency and the rough set was used to correct errors. It is expected that the system proposed in this paper will be effective in securing the safety of pedestrians and reducing light pollution and energy by predicting the path of pedestrians in the detection of movement of pedestrians and in conjunction with smart street lightings.

• Journal of the Microelectronics and Packaging Society
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• v.25 no.4
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• pp.101-104
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• 2018

An electric field was applied to a Mo conductive layer in the sandwiched structure of $glass/SiO_2/Mo/SiO_2/a-Si$ to induce Joule heating in order to generate the intense heat needed to carry out the crystallization of amorphous silicon. Polycrystalline silicon was produced via Joule heating through a solid state transformation. Blanket crystallization was accomplished within the range of millisecond, thus demonstrating the possibility of a new crystallization route for amorphous silicon films. The grain size of JIC poly-Si can be varied from few tens of nanometers to the one having the larger grain size exceeding that of excimer laser crystallized (ELC) poly-Si according to transmission electron microscopy. We report here the blanket crystallization of amorphous silicon films using the $2^{nd}$ generation glass substrate.

• Journal of the Semiconductor & Display Technology
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• v.20 no.2
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• pp.67-72
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• 2021

MANET(Mobile Ad Hoc Network) is the structure in which a source node communicates with a destination node by establishing a route with neighbor nodes without using the existing wired or wireless network. Therefore, the routing protocol for MANET must correspond well to changes in the channel state of moving nodes, and should have simple operation, high reliability, and no routing loop. In this paper, the simulation was perform by using a traffic model with on/off two states provided by the NS-3 network simulator. Also, the duration of the ON state and the duration of the OFF state used the traffic where inter arrival time of data is irregular by generating random values with constant, exponential distribution, and Pareto distribution. The performance of the DSDV, OLSR, and AODV protocols was compare and analyzed using the generated traffic model.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.06a
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• pp.119-120
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• 2020

Recently, a building fire has occurred due to various influences. Accordingly, we are developing an public safety & security unmanned aerial vehicle for fire prevention and initial response to fire. The public safety & security unmanned aerial vehicle is used to grasp the traffic route to enter the fire engine in the event of a fire in a dense structure and to determine the scale of the fire and the area of danger of collapse around the fire site. In this study, an environmental test of the public safety & security unmanned aerial vehicle's heat resistance was performed in an environment simulating a fire scene.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2021.10a
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• pp.637-639
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• 2021

As autonomous driving research is actively progressing, lane detection is an essential technology in ADAS (Advanced Driver Assistance System) to locate a vehicle and maintain a route. Lane detection is detected using an image processing algorithm such as Hough transform and RANSAC (Random Sample Consensus). This paper implements a linear shape detection algorithm using OpenCV on Raspberry Pi 3 B+. Thresholds were set through OpenCV Gaussian blur structure and Canny edge detection, and lane recognition was successful through linear detection algorithm.