• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2489-2493
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• 2012

A new fluorescent system (acridine/RTIL hybrid gel) confined in the 3D micro-structure of a poly(lactic acid) membrane were prepared from 1-butyl-3-methylimidazolium-based ionic liquids ([bmim]X (X = $SbF_6$, $NTf_2$, Cl); RTILs), poly(lactic acid) (PLA), and acridine via the sol-gel route. SEM images showed that, in the presence of [bmim]$SbF_6$ and [bmim]$NTf_2$, 3D-ly paticulated structures were created inside the PLA membranes and acridine/RTIL hybrid gels were confined in gabs of particulates. However, the use of [bmim]Cl induced the formation of a 3D-ly porous structure containing the hybrid gel of acridine/[bmimCl in the micropores. The three fluorescent systems exhibited different fluorescence behaviors (fluorescence maximum and intensity) depending on the C2-H acidity scale of the RTILs (or their anion type). Acridine gels hybridized with [bmim]$SbF_6$ and [bmim]$NTf_2$ showed blue fluorescence with relative high intensity, whereas the hybrid gel with [bmim]Cl exhibited almost no fluorescence under dry conditions. However, the acridine/[bmim]Cl hybrid system in the micro-porous PLA membrane started to emit fluorescent light under humid conditions and showed a possible response, indicating that it could be applied as a humidity sensor.

• 한국가스학회지
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• 제22권5호
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• pp.46-52
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• 2018

최근 국내 대형화재 발생으로 화재예방 및 소방에 대한 관심이 높아지고 있는 추세이다. 화재에 대한 피해를 최소화하기 위해서는 감지설비, 경보설비, 소화설비, 피난설비 및 유지관리 등 모든 요소가 중요하지만 화학공장과 같이 철골구조에 가연성 물질을 집중적으로 취급하는 시설에서는 화재 시 그 구조를 유지할 수 있도록 주요구조부에 적용하는 내화구조의 중요성이 특히 대두된다. 현재 건축법, 산업안전보건법 등 국내법에서는 산업시설에 대하여 일괄적으로 지상으로부터 6m까지 내화구조를 적용하도록 규정하고 있다. 하지만 화학공장은 경우에 따라 가연성 물질을 대량으로 취급할 수도 비가연성 물질만을 취급할 수도 있다. 이 연구에서는 화학공장에서 발생할 수 있는 화재 규모에 따라 필요한 내화구조 적용이 필요한 높이에 대하여 연구하였다.

• 한국농공학회논문집
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• 제53권6호
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• pp.153-163
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• 2011

This research describe improved algorithm that is able to decide terminal criterion of Evolutionary Structural Optimization (ESO), reducing load of calculation to search load path of concrete beam, and apply to agricultural facilities. The ESO method is that make to discrete structure, structural analyze each element stress through FEM. And repeat generation with next material condition to become for most suitable composing. Individual element introduces concept of zero stiffness, but zero stiffness decisions are gone to direction of exclusion. In this stduy, improve algorithm to be convergence by 'Rule of Alive or Die' in arrival because is most suitable. Also, existing terminal criterion lack consistency because that used depend on experience of researcher. This research procedure is fellowed. First, all modulus of elasticity assume a half of elasticity modulus of material, Second, structural analysis by FEM, Third, apply to the remove ratio and restoration ratio for the 'rule of alive or die'. Forth, reconstruct the element and material conditions. And repeat the first to forth process. The terminal time of evolutional procedure is the all elastic modulus of element changed to blank value or elasticity modulus value of original. Therefore, in this study, consist the algorithm for programming, and apply to the agricultural facilities with concrete.

• Journal of information and communication convergence engineering
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• 제6권3호
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• pp.255-260
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• 2008

In the recently years, there has been a big interest in ad hoc wireless network as they have tremendous military and commercial potential. An Ad hoc wireless network is composed of mobile computing devices that use having no fixed infrastructure of a multi-hop wireless network formed. So, the fact that limited resource could support the network of robust, simple framework and energy conserving etc. In this paper, we propose a new ad hoc multicast routing protocol for based on the ontology scheme called inference network. Ontology knowledge-based is one of the structure of context-aware. And the ontology clustering adopts a tree structure to enhance resilient against mobility and routing complexity. This proposed multicast routing protocol utilizes node locality to be improve the flexible connectivity and stable mobility on local discovery routing and flooding discovery routing. Also attempts to improve route recovery efficiency and reduce data transmissions of context-awareness. We also provide simulation results to validate the model complexity. We have developed that proposed an algorithm have design multi-hierarchy layered networks to simulate a desired system.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 춘계학술발표대회
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• pp.40.2-40.2
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• 2011

As the old saying 'nothing is complete unless you put it in final shape', although nanosheets (NSs) are a promising functional building block for various electrochemical applications, their true value cannot be realized until they are well woven into electrical conducting materials. As an effort to determine their ideal shape, in this study, a unique manufacturing route to build a layer-by-layer (LBL) structure of two-dimensionally ordered, free-standing ${\beta}$-nickel hydroxide nanosheets (${\beta}$-NHNSs) that are fully electrically addressed with single-wall carbon nanotube fabrics was demonstrated, and its capabilities were verified through a comparative study on the differences between a simple bulky and LBL-structured electrochemical cathode, representing two extreme cases. The LBL-structured cathode showed a discharging current peak that was 25 times larger than the bulky structured one measured in cyclic voltammetry, which implies that the LBL structure is near an ideal electrode configuration for NS-based electrochemical applications.

• 제어로봇시스템학회논문지
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• 제6권3호
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• pp.273-283
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• 2000

In this paper we suggest an optimal design method of Fuzzy-Neural Networks(FNN) model for complex and nonlinear systems. The FNNs use the simplified inference as fuzzy inference method and Error Back Propagation Algorithm as learning rule. And we use a HCM(Hard C-Means) Clustering Algorithm to find initial parameters of the membership function. The parameters such as parameters of membership functions learning rates and momentum weighted value is proposed to achieve a sound balance between approximation and generalization abilities of the model. According to selection and adjustment of a weighting factor of an aggregate objective function which depends on the number of data and a certain degree of nonlinearity (distribution of I/O data we show that it is available and effective to design and optimal FNN model structure with a mutual balance and dependency between approximation and generalization abilities. This methodology sheds light on the role and impact of different parameters of the model on its performance (especially the mapping and predicting capabilities of the rule based computing). To evaluate the performance of the proposed model we use the time series data for gas furnace the data of sewage treatment process and traffic route choice process.

• Bulletin of the Korean Chemical Society
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• 제32권12호
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• pp.4332-4336
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• 2011

The chalcopyrite-type $CuInSe_2$ is a remarkable material for thin film solar cells owing to its electronic structure and optical response. Single-phase sphere-like $CuInSe_2$ nanocrystallite particles were prepared by a facile noninjection method with triethanolamine as the complexing agent and the solvent simultaneously. The period of the reaction was the key to form single-phase $CuInSe_2$ nanocrystals at $240^{\circ}C$. TEM, XRD, XPS, EDX investigations were performed to characterize the morphology and the detailed structure of as-synthesized $CuInSe_2$ nanocrystals. All of the analysis results proved that the synthesized nanocrystals were pure phase and close to the stoichiometric ratio rather than a simple mixture. The band gap of the obtained $CuInSe_2$ nanocrystals was $1.03{\pm}0.03$ eV.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2007년도 춘계학술대회 논문집
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• pp.1121-1128
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• 2007

Subway routes $1{\sim}4$ were constructed in gravel roadbed track structure in consideration of the technological capabilities, construction cost and duration at the time of the initial construction. As such, 224.8km, approximately 81.2% of entire length, of total length of railway track at 276.9km was constructed on gravel roadbed. However, improvement of gravel roadbed to concreted roadbed began in 1998 due to problems including frequent repair works and limited time application for such works caused by occurrence of tract distortion during operation as well as lowering of roadbed functions and generation of dust caused by frictional power, impact absorption capabilities, abrasion and crushing of gravel on roadbed. Currently, this improvement is continuing with target of converting entire route into concreted roadbed structure. Therefore, this Study modifies formula for setting cant, analyze the correlation between wearing of rail side of the curvature and cant insufficiency following increasing of the running speed of the train, and to present the directions for fundamental review for adjustment of cant insufficiencies at the time of improvement of gravel roadbed to concreted roadbed that is being implemented on the operational tracks of the railway trains.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2008년도 춘계학술대회 논문집
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• pp.151-157
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• 2008

Subway routes $1\sim4$ were constructed in gravel roadbed track structure in consideration of the technological capabilities, construction cost and duration at the time of the initial construction. As such, 224.8km, approximately 81.2% of entire length, of total length of railway track at 276.9km was constructed on gravel roadbed. However, improvement of gravel roadbed to concreted roadbed began in 1998 due to problems including frequent repair works and limited time application for such works caused by occurrence of tract distortion during operation as well as lowering of roadbed functions and generation of dust caused by frictional power, impact absorption capabilities, abrasion and crushing of gravel on roadbed. Currently, this improvement is continuing with target of converting entire route into concreted roadbed structure. Therefore, this Study modifies formula for setting cant, analyze the correlation between wearing of rail side of the curvature and cant insufficiency following increasing of the running speed of the train, and to present the directions for fundamental review for adjustment of cant insufficiencies at the time of improvement of gravel roadbed to concreted roadbed that is being implemented on the operational tracks of the railway trains.

• Bulletin of the Korean Chemical Society
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• 제26권8호
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• pp.1214-1218
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• 2005

Ti-HMS samples in which titanium species exist in various forms of isolated tetrahedral state, finely dispersed $TiO_2$ cluster, and some in extra-framework anatase phase were prepared via a direct synthesis route using dodecylamine (DDS) as a structure directing agent by systematically varying the titanium loadings between 2 and 50 mol% Ti/(Ti+Si) in substrate composition. Physicochemical properties of the materials were evaluated using XRD, SEM/TEM, N2 adsorption, UV-vis and XANES spectroscopies. Catalytic properties of Ti-HMS in cyclohexene and 2,6-di-tert-butyl phenol (2,6-DTBP) oxidation using aqueous $H_2O_2$, and vapor phase photocatalytic degradation of acetaldehyde were evaluated. High $H_2O_2$ selectivity was obtained in cyclohexene oxidation, and cyclohexene conversion was found primarily dependent on the amount of tetrahedrally coordinated Ti sites. For bulky 2,6-DTBP oxidation and photocatalytic oxidation of acetaldehyde, on the other hand, conversions were found dependent on the total amount of Ti sites and maintaining an uniform mesoporous structure in the catalysts was not critical for efficient catalysis.