• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.316-316
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• 2006

The preparation of an organic/inorganic polymer hybrid from a novolac derivatives is described. The hybrid was prepared by the acid-catalyzed solgel reaction of phenyl-trimethoxysilane (PhTMOS) in the presence of anisole novolac. The resulting film was transparent and showed a high heat stability. The dispersion of two components might be due to the utilization of the p-p interaction between the phenyl ring of the silica matrix and that of novolac. This makes it possible to prepare a hybrid glass having a highly content of novolac derivatives.

• Journal of the Korean Ceramic Society
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• v.29 no.9
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• pp.681-688
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• 1992

Ultrafine Si3N4 and Si3N4+SiC mixed powders were synthesized through thermal plasma chemical vapor deposition(CVD) using a hybrid plasma, which was characterized by the supersposition of a radio-frequency plasma and arc jet. The reactant SiCl4 was injected into an arc jet and completely decomposed in a hybrid plasma, and the second reactant CH4 and/or NH3 mixed with H2 were injected into the tail flame through double stage ring slits. In the case of ultrafine Si3N4 powder synthesis, reaction efficiency increased significantly by double stage injection compared to single stage one, although crystallizing behaviors depended upon injection speed of reactive quenching gas (NH3+N2) and injection method. For the preparation of Si2N4+SiC mixed powders, N/C composition ratio could be controlled by regulating the injection speed of NH3 and/or CH4 reactant and H2 quenching gas mixtures as well as by adjusting the reaction space.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.27 no.11
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• pp.1949-1957
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• 2003

A hybrid finite element analysis was used to analyze the influence of ring gear rim thickness and spline number on the static properties of a planetary gear system with manufacturing errors. Both of these parameters affected the bearing force and critical stress. The effect of changes in the rim thickness on the load sharing between the gears depended on the type of manufacturing error. Ring flexibility improved the load sharing between planetary gears only in systems with planet tooth thickness or planet tangential errors; for other types of error, ring flexibility worsened the load sharing. To improve load sharing, rim thickness and spline number should be controlled within a specific range. The minimum rim thickness limit should be determined considering not only the critical stress but also the load sharing. The effect of the ring gear boundary condition was more apparent in a system with errors than in a normal system.

• Journal of the Optical Society of Korea
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• v.12 no.3
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• pp.157-161
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• 2008

A wavelength-selective reflector, composed of a double-ring-resonator add/drop filter and a loop-back mirror at the drop port to be used for a hybrid-integrated tunable laser is designed and fabricated. High-index-contrast polymer waveguide is used to realize a compact device as small as $2mm{\times}0.4mm$. The radii of the rings are slightly different from each other to obtain a wide wavelength tuning via a vernier effect. Peak reflectivity is measured to be 52% for TE mode and polarization-dependent wavelength shift is 0.95 nm. The tuning range is measured to be about 42 nm for applied current as small as 46 mA.

• Journal of the Korean Applied Science and Technology
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• v.26 no.3
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• pp.288-296
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• 2009

In this study, the silica-based hybrid material with high barrier property was prepared by incorporating ethylene-vinyl alcohol (EVOH) copolymer, which has been utilized as packaging materials due to its superior gas permeation resistance, during sol-gel process. In preparation of this EVOH/$SiO_2$ hybrid coating materials, the (3-glycidoxy-propyl)-trimethoxysilane (GPTMS) as a silane coupling agent was employed to promote interfacial adhesion between organic and inorganic phases. As confirmed from FT-IR analysis, the physical interaction between two phases was improved due to the increased hydrogen bonding, resulting in homogeneous microstructure with dispersion of nano-sized silica particles. However, depending on the range of content of added silane coupling agent (GPTMS), micro-phase separated microstructure in the hybrid could be observed due to insufficient interfacial attraction or possibility of polymerization reaction of epoxide ring in GPTMS. The oxygen barrier property of the mono-layer coated BOPP (biaxially oriented polypropylene) film was examined for the hybrids containing various GPTMS contents. Consequently, it is revealed that GPTMS should be used in an optimum level of content to produce the high barrier EVOH/$SiO_2$ hybrid material with an improved optical transparency and homogeneous phase morphology.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2010.05a
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• pp.555-556
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• 2010

• Proceedings of the Zoological Society Korea Conference
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• 1997.10b
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• pp.274.2-274
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• 1997

No Abstract, See Full Text

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3690-3694
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• 2013

The $H_2Ge=Ge:$ and its derivatives ($X_2Ge=Ge:$, X = H, Me, F, Cl, Br, Ph, Ar${\ldots}{\ldots}$) is a new species. Its cycloaddition reactions is a new area for the study of germylene chemistry. The mechanism of the cycloaddition reaction between singlet state Cl2Ge=Ge: and formaldehyde has been investigated with CCSD(T)//MP2/$6-31G^*$ method. From the potential energy profile, it could be predicted that the reaction has only one dominant reaction pathway. The reaction rule presented is that the two reactants first form a fourmembered Ge-heterocyclic ring germylene through the [2+2] cycloaddition reaction. Because of the 4p unoccupied orbital of Ge: atom in the four-membered Ge-heterocyclic ring germylene and the ${\pi}$ orbital of formaldehyde forming a ${\pi}{\rightarrow}p$ donor-acceptor bond, the four-membered Ge-heterocyclic ring germylene further combines with formaldehyde to form an intermediate. Because the Ge: atom in intermediate hybridizes to an $sp^3$ hybrid orbital after transition state, then, intermediate isomerizes to a spiro-Ge-heterocyclic ring compound via a transition state. The research result indicates the laws of cycloaddition reaction between $H_2Ge=Ge:$ and formaldehyde, and laid the theory foundation of the cycloaddition reaction between $H_2Ge=Ge:$ and its derivatives ($X_2Ge=Ge:$, X = H, Me, F, Cl, Br, Ph, Ar${\ldots}{\ldots}$) and asymmetric ${\pi}$-bonded compounds, which is significant for the synthesis of small-ring and spiro-Ge-heterocyclic compounds. The study extends research area and enriches the research content of germylene chemistry.

• Asian Journal of Atmospheric Environment
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• v.4 no.2
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• pp.63-71
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• 2010

The removal characteristics for aromatic and aliphatic VOCs by electron beam (EB) were discussed in terms of several removal variables such as initial VOC concentration, absorbed dose, background gas, moisture content, reactor material and inlet temperature. It was reviewed that only reactor material was an independent variable among the potential control factors concerned. It was also suggested that main mechanism by EB should be radical reaction for the VOC removal rather than that by primary electrons. It was discussed that the removal efficiency of benzene was lower than that of hexane due to a closed benzene ring. In the case of aromatic VOCs, it was observed that the decomposition of the VOCs with more functional groups attached on the benzene ring was much easier than those with less ones. As for aliphatic VOCs, it was also implied that the longer carbon chain was, the higher the removal efficiency became. An EB-catalyst hybrid system was discussed as an alternative way to remove VOCs more effectively than EB-only system due to much less by-products. This hybrid included supporting materials such as cordierite, Y-zeolite, and $\gamma$-alumina.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.15 no.1
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• pp.71-79
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• 1990

An analog phase shifter is designed at the operating frequency 10GHz that is coupled with a hybrid ring and the network connecting an inductor series with a varactor to extend a continuous chage in the phase of the reflected output wave to be produced from a variation in the terminated varactor reactance as a variation in the reverse bias voltage. It is manufactured in a microstripline in consideration of an effect of the dispersion characteristics and discontinuities. As a resuls of an experiment, a change in the phase is achieved over 180 degree from $52.34^{\circ}$ degrees to $235.01^{\circ}$degrees, the transmission loss is -3.6~-14.3dB, and the return loss is -16~-8dB(1.37