• Journal of Powder Materials
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• v.13 no.1 s.54
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• pp.10-17
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• 2006

Model experiment was introduced to obtain the formation of a core/rim structure by only liquid phase reaction in Ti(C, N)-based cermet alloys. Infiltrated Ti(C, N)-Ni, $MO_2C-Ni$, and TaC-Ni cermets were bonded to sandwiched specimen by heat treatment $1450^{\circ}C$ for 5hr. With nitrogen addition, both (Ti, Mo) (C, N) and (Ti, Ta) (C, N) rim structure was nucleated around comer of cuboidal Ti(C, N) core. However, equilibrium shapes of(Ti, Mo) (C, N) and (Ti, Ta) (C, N) rim were different possibly due to the effect of interface energy. The core/rim and rim! binder interfaces were parallel to each other with TaC addition, while rotated to each other with $MO_2C$ addition.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2002.11a
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• pp.8-8
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• 2002

TiC core/(Ti,Mo)C rim structure in TiC-$Mo_2C$-Ni base cermet which is generally prepared by sintering below 145$0^{\circ}C$ had been believed to be generated by the solid diffusion of Mo atoms 1 into TiC grains (D. Moskowitz and M.Humenik, 1r.:1966). Afterward, it was clarified that the c core/rim structure is generated by solution/re-precipitation mechanism : (1) $Mo_2C$ grains and s small TiC grains dissolve into the Ni liquid, (2) the dissolved Mo, Ti and C atoms migrate to the s surface of TiC coarse grains, (3) the Mo, Ti and C precipitate on the surface of TiC coarse g grains and form (Ti,Mo)C solid solution rim, and (4) the Ostwald ripening (grain growth by s solution/re-precipitation mechanism) of TiC-core/(Ti,Mo)-rim grains continues, and thus the w width of (Ti,Mo)C rim (at the same time, the grain size) increases with sintering time, etc. ( (H.Suzuki, K.Hayashi and O.Terada: 1973). The TiC-core was found not to disappear even by s sintering at 190$0^{\circ}C$ (ibid.: 1974) Recently, FeSi core/$Fe_2Si_5$-rim structure in Fe-66.7at%Si thermoelectric aIloy was found to also h hardly shrink and disappear by long heating at an appropriate temperature (1999: M.Tajima and K K.hayashD. Then, the authors considered its cause, and clarified experimentaIly that the disappearance of FeSi-core/$Fe_2Ski_5$-rim structure could be attributed to the exhaustion of diffusion-contributable vacancies in core/rim structure (N.Taniguchi and K.Hayashi:2001). At p present, the authors and my coworker are investigating whether the non-disappearance of TiC c core can be explained also from the new hypothesis "Exhaustion of diffusion-contributable v vacancies in corelrim structure".ure".uot;.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2004.05a
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• pp.383-387
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• 2004

• Proceedings of the Korean Nuclear Society Conference
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• 2002.05a
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• pp.232.1-232
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• 2002

• KSCE Journal of Civil and Environmental Engineering Research
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• v.42 no.2
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• pp.181-186
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• 2022

Dam slope RIM is a highly important contact interface where the main body and the base surface are connected. In general, when the grouting for the slope of the dam structure is designed, it is planned using limited data (drilling, geological map, etc.). This makes it very difficult to accurately consider the original ground characteristics of the slope RIM grouting target, In addition, when the grouting volume planned during the design is drilled and injected into the original ground where the waterstop is secured, there is a possibility that the original ground with the waterstop is disturbed and the effect of the waterstop is rather diminished. In order to overcome such problems, it is more suitable to first consider geological conditions and determine whether to perform optimal grouting on the original ground through on-site repair tests before performing RIM grouting. In this paper, to determine the grouting of the RIM unit, a pilot hole water pressure test was performed on the rock of the slope in the target section. The analysis shows grouting volume of 1 Lugeon or less, and the cement injection amount also shows the injection result of 1 kg/m or less. In this case, performing grouting is rather counterproductive. This result can be evaluated through a rock of which some degree of order of mass is secured, as it is a dam design standard of 1 Lugeon or less when analyzed, using the results of visual observation and geological map creation during slope cutting. Therefore, in conclusion, it is preferable to make the decision for using RIM grouting on the slope of the dam body structure, based on 1 Lugeon in a rock state, and the cement injection amount also at 1 kg/m.

• Journal of KSNVE
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• v.6 no.4
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• pp.447-456
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• 1996

Dynamic characteristics of the bell-type structure including acoustic effects and transient dynamic problems were analyzed numerically. Natural frequencies, mode shapes and transient dynamic analysis used the finite element method with 3-D general shell element. Mode shapes and stress distributions of transient dynamic analysis were expressed by computer graphics. The method using this study was evaluated by comparision of theoretical results at reference papers(14), (15) and the experimental test using Fast Fourier Transform analyzer. Vibrational modes governing acoustic characteristics of the typical bell-type structure depended on the first flexural mode(4-0 mode) and the second flexural mode(6-0 mode). Asymmetric effects by Dangiwas, acoustic holes gave rise to beat frequencies, and the Dangjwa was found to be most effective. When impact load acted on the bell, stress concentration occured at the rim part of bell. It was found that the bell type structure should be designed thickly at the rim part in order to prevent impact load from stress concentration.

• Journal of Broadcast Engineering
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• v.9 no.4 s.25
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• pp.424-433
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• 2004

Jing(gong) is one of the most well known Korean traditional Samulnori instruments to the general public. Samulnori is consisted of four instruments, them being : the jingo the janggu (hour-glass drum). the kkwaenggwari, and the buk(drum). Of the four instruments, the jing with its deep, and yet soft and beautiful long lingering sound embraces the sounds of the other three. The jing is a brassware instrument, a compound of $70{\%}\;copper\;and\;22{\%}\;tin.$\;A high quality brassware is used when the jing is made. The jing is shaped with a 39-40cm circular plate and a rim that gives 7.0-7.5cm of depth to the instrument. Even with its most simple structure, when the circular plate is hit during performance, the rim which supports the circular plate gives resonance to the sound making low-frequency sounds. Therefore the range of the representative frequency of the full rim jing is between $118.4{\~}366.0[Hz],$\;the lingering sound lasts for more than 20 seconds afterwards. When the jing with half of its rim cut off is hit the basic frequency is $139.9{\~}387.5[Hz].$\;And the sound lasted for ten more seconds. The jing of its rimless frequencies are distributed between $990.5{\~}1,372[Hz].$\;And the lingering sound lasts for 5seconds afterwards. Therefore, different thickness and depth of the rim may give new resonance frequencies and alter the longing time of the sound. This thesis paper will try to reveal the relationship between the thickness or depth of the rim (which holds the bending circular plate) and the frequency or the lasting time of the sound.

• Communications of Mathematical Education
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• v.5
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• pp.524-532
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• 1997

• Bulletin of the Korean Chemical Society
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• v.17 no.6
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• pp.525-528
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• 1996

Seven cali[4]arenes, having two different substituents in AAAB or AABB pattern at the upper rim of calix were synthesized by fragmentation condensation reaction of p-substituted phenol trimer (AAA) with 2,6-bishydroxymethylated 4-substituted phenol (B) or that of dimer (AA) with 2,2'-bishydroxymethylated dimer (BB). An equimolar mixture of the coupling components (trimer and monomer or dimer and dimer) was refluxed in dioxane in the presence of TiCl4to afford calix[4]arene 6 and 7 in 15-38% yield. The structure of calix[4]arenes was confirmed by elemental analysis and the 1H/13C NMR spectroscopy.

• Bulletin of the Korean Chemical Society
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• v.16 no.11
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• pp.1122-1125
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• 1995

Three inherently chiral calix[4]arenes 3-5 were synthesized as racemate starting from the ethylation at 1.3-distal hydroxy groups of calix[4]arene 2 which has two phenyl groups at upper rim in AABB fashion, and then two remaining hydroxy groups were acetylated by treatment with acetyl chloride in the presence of NaH to produce calix[4]arene 4. Treatment of 4 with AlCl3 under Fries rearrangement conditions, only one acetyl group was rearranged to the para-position to afford calix[4]arene 5 with AABC substitution pattern at the upper rim of calix. The structure of chiral calix[4]arenes were confirmed based on NMR and massspectra.