• Bulletin of the Korean Chemical Society
• /
• 제23권5호
• /
• pp.779-782
• /
• 2002

• Bulletin of the Korean Chemical Society
• /
• 제33권12호
• /
• pp.4150-4154
• /
• 2012

Efficient synthesis of ${\alpha}$-chloroenones bearing ${\beta}$-carbonates or ${\beta}$-carbamates was achieved by rhodium(II)-catalyzed reaction of cyclic diazodicarbonyl compounds with a variety of chloroformates or carbamyl chlorides in good yields. These reactions provided a useful and rapid route to ${\beta}$-substituted ${\alpha}$-haloenones.