• Title/Summary/Keyword: Rheological behavior

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Effects of dissolution temperature on the rheological properties of polyvinyl alchol solutions in dimethyl sulfoxide

  • Cho, Yong-Han;Dan, Kyung-Sik;Kim, Byoung-Chul
    • Korea-Australia Rheology Journal
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    • v.20 no.2
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    • pp.73-77
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    • 2008
  • The rheological properties of polar solutions are very sensitive to preparative methods as well as measuring conditions. The effects of dissolution temperature on the rheological properties of the solutions of polyvinyl alcohol (PVA) in dimethyl sulfoxide were investigated over the range of dissolution temperatures $70-130^{\circ}C$. Viscosity was increased as dissolution temperature was increased. PVA solutions prepared at 120 and $130^{\circ}C$ showed Bingham behavior, which became less noticeable with decreasing dissolution temperature. The modified Cole-Cole plot of the solutions gave slope less than 2, suggesting the solutions were a heterogeneous system irrespective of optical transparency. Further, the slope was decreased with increasing dissolution temperature, indicating that the solid character got more prominent as dissolution temperature was increased. However, the relaxation time of the solutions was little dependent on dissolution temperature.

Thixotropic Properties of Polyacrylamide Hydrogels with Various Synthetic Conditions (합성조건에 따른 Polyacrylamide 수화 겔의 흐름변성 성질)

  • Kim, Nam-Jeong
    • Journal of the Korean Chemical Society
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    • v.50 no.6
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    • pp.447-453
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    • 2006
  • of synthetic conditions and water content on rheological properties of polyacrylamide hydrogels were studied. The non-Newtonian flow curves of polyacrylamide hydrogels were obtained by using a cone-plate rheometer. The rheological parameters were obtained by applying non-Newtonian equation to the flow curves for polyacrylamide hydrogels. The polyacrylamide hydrogels are shear thinning under increasing shear rate modes which result in thixotropic behavior. These flow properties are controlled by the characteristics of flow units and the interaction among the flow segments.

A Description of Thermomechanical Behavior Using a Rheological Model (리올러지 모델을 이용한 열적 기계적 변형 거동 모사)

  • Lee Keum-Oh;Hong Seong-Gu;Lee Soon-Bok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.7 s.250
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    • pp.757-764
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    • 2006
  • Isothermal cyclic stress-strain deformation and thermomechanical deformation (TMD) of 429EM stainless steel were analyzed using a rheological model employing a bi-linear model. The proposed model was composed of three parameters: elastic modulus, yield stress and tangent modulus. Monotonic stress-strain curves at various temperatures were used to construct the model. The yield stress in the model was nearly same as 0.2% offset yield stress. Hardening relation factor, m, was proposed to relate cyclic hardening to kinematic hardening. Isothermal cyclic stress-strain deformation could be described well by the proposed model. The model was extended to describe TMD. The results revealed that the hi-linear thermomechanical model overestimates the experimental data under both in-phase and out-of-phase conditions in the temperature range of $350-500^{\circ}C$ and it was due to the enhanced dynamic recovery effect.

Effect of Blastfurnace Slag Fineness on the Rheological Properties of Cement Pastes (고로슬래그 분말도가 시멘트 페이스트의 유동특성에 미치는 영향)

  • Song, Jong-Taek;You, Chang-Dal;Byun, Seung-Ho
    • Journal of the Korean Ceramic Society
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    • v.44 no.2 s.297
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    • pp.103-109
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    • 2007
  • In this study, the rheological properties of cement pastes containing blastfurnace slag of different fineness were investigated. The fluidity of cement pastes with low Blaine value blastfurnace slag was increased with decreasing the plastic viscosity and the yield stress of pastes. And the optimum dosage of polycarboxylate type superplasticizer to the cement pastes was confirmed according to the fineness and the replacement ratio of blastfurnace slag. All cement pastes showed the thixotropy behavior. And also it was formed that the segregation range of cement pastes was occurred below $10D/cm^2$ of the yield stress and below 350 cPs of the plastic viscosity by the coaxial cylinder viscometer.

Effect of Extraction Time on the Rheological Properties of Sericin Solutions and Gels

  • Yoo, Young Jin;Um, In Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.27 no.1
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    • pp.180-184
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    • 2013
  • Recently, silk sericin has attracted the attention of researchers owing to its useful properties as a biomaterial including 1) good wound healing and cell activities, 2) fast gelation character, and 3) high water retention property. In the present study, silk sericin was prepared using different extraction times in hot water and the effect of extraction time on the rheological properties of sericin solutions and gels was examined. It was found that the production yield of sericin increased with extraction time. The shear viscosity of sericin solutions and gels decreased with increasing extraction time due to a decrease in sericin molecular weight. When the sericin solution transformed to a gel, the viscosity increased and the shear thinning behavior was more evident. In addition, the shear stress measurements indicated that the slip between the sericin samples and the measuring plate of the rheometer was increased by the gelation of sericin. The compression strength of sericin gel could be increased remarkably (by more than 100 fold) by preparation using the freezing and thawing method.

Model Synthesis and Performance analysis of an Engine Mount Using Electro-Rheological Fluids (전기유동유체를 이용한 엔진마운트의 모델구성과 성능해석)

  • 최영태;김기선;최승복;정재천;전영식
    • Transactions of the Korean Society of Automotive Engineers
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    • v.2 no.3
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    • pp.62-74
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    • 1994
  • This paper addresses on the model synthesis and performance analysis of an engine mount featuring electro-rheological(ER) fluids which undergo a phase change when subjected to electric fields. A novel type of ER fluid-filled engine mount is devised and its hydraulic model is constructed. An equivalent mechanical model is subsequently obtained from the governing equation of the hydraulic model. The model parameters associated with the ER fluids are distilled from experimental investigations on the Bingham properties of the fluids. The distilled data are then incorporated into the governing model to undertake feasible work through computer simulations,. It is shown that the proposed engine mount has an inherent capability of controlling both the damping force and the resonance frequency. Other superior performance characteristics accrued from the proposed methodology are also evaluated.

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Design of Compact Magneto-Rheological Fluid Damper for Artificial Low-Limb Prosthesis (Magneto-Rheological Fluid를 이용한 인공지능 의족의 Compact damper 개발)

  • Sung, So-Young;Kang, S.J.;Moon, I.H.;Moon, M.S.;Jang, S.M.
    • Proceedings of the KIEE Conference
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    • 2005.07d
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    • pp.2962-2964
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    • 2005
  • Magneto-Rheological (MR) fluid is suspension of fine magnetic particles in a liquid carrier such as silicon oil or water. MR fluid exhibits solid-like mechanical behavior into chain or clusters with high yield stress when magnetic field is applied to the particles. The response of MR fluids is very quick and reversible after removal of the field. MR Fluids have high yield stress (up to 5kPs) and operate in low voltage power supply. Recently, MR damper using MR fluids was open used in vibration control system such as structural devices, seat vibration controllers and helicopter rotor systems, but it is too big in size and heavy. Therefore, it is not appreciate to rehabilitation devices such as prosthetic limbs.

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Physical and Rheological Properties of Thermoplasticized Crosslinked-Polyethylene Foam in Supercritical Methanol

  • Cho, Hang-Kyu;Hong, Soon-Man;Baek, Kyung-Yeol;Koo, Chong-Min;Lee, Hong-Shik;Lee, Youn-Woo
    • Macromolecular Research
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    • v.17 no.12
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    • pp.950-955
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    • 2009
  • The physical and rheological properties of thermoplasticized irradiation-crosslinked polyethylene foam using supercritical methanol treatment were investigated by GPC, FTIR, DSC, WAXS, DMTA and UDS. The polyethylene foam was selectively decrosslinked into thermoplasticized polyethylene in an appropriate supercritical methanol condition without any undesirable side reactions such as oxidation and disproportionation. The thermoplasticization was promoted with increasing reaction temperature to reach completion above $380^{\circ}C$. The supercritical reaction condition affected the crystallization behavior, and mechanical and rheological properties of the decrosslinked polyethylene foam, but not its crystallographic structure or crystallinity.

Elastohydrodynamic Lubrication of Line Contacts Incorporating Bair & Winer's Limiting Shear Stress Rheological Model (한계전단응력형태의 Bair & Winer 리올로지 모델을 사용한 선접촉 탄성유체윤활해석)

  • 이희성;양진승
    • Tribology and Lubricants
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    • v.14 no.1
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    • pp.85-93
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    • 1998
  • The Bair & Winer's limiting shear stress rheological model is incorporated into the Reynolds equation to successfully predict the traction and film thickness for an isothermal line contact using the primary rheological properties. The modified WLF viscosity model and Barus viscosity model are also adapted for the realistic prediction of EHD tractional behavior. The influences of the limiting shear stress and slide-roll ratio on the pressure spike, film thickness, distribution of shear stress and nonlinear variation of traction are examined. A good agreement between the disc machine experiments and numerical traction prediction has been established. The film thickness due to non-Newtonian effects does not deviate significantly from the fdm thicknesss with Newtonian lubricant.

Non-Newtonian Characteristics of Gochujang and Chogochujang at Different Temperatures

  • Choi, Ji Eun;Lee, Jun Ho
    • Preventive Nutrition and Food Science
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    • v.22 no.1
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    • pp.62-66
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    • 2017
  • This study was conducted to determine the rheological properties of gochujang and chogochujang at different temperatures (25, 35, and $45^{\circ}C$). Rheological properties of the samples were determined using a rotational rheometer at a shear range of 1 to $40s^{-1}$. Gochujang and chogochujang were found to be non-Newtonian fluids according to the Herschel-Bulkley model. Yield stress and consistency coefficient of gochujang at different temperatures were higher than those of chogochujang, whereas the opposite was observed for flow behavior index. Moreover, all rheological properties of gochujang and chogochujang decreased with increasing temperature. The consistency coefficient was related to temperature using an Arrhenius-type relationship. Gochujang (14.48 kJ/mol) had slightly higher activation energy than chogochujang (14.03 kJ/mol).