• 제목/요약/키워드: Rheological behavior

검색결과 466건 처리시간 0.027초

Effects of dissolution temperature on the rheological properties of polyvinyl alchol solutions in dimethyl sulfoxide

  • Cho, Yong-Han;Dan, Kyung-Sik;Kim, Byoung-Chul
    • Korea-Australia Rheology Journal
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    • 제20권2호
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    • pp.73-77
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    • 2008
  • The rheological properties of polar solutions are very sensitive to preparative methods as well as measuring conditions. The effects of dissolution temperature on the rheological properties of the solutions of polyvinyl alcohol (PVA) in dimethyl sulfoxide were investigated over the range of dissolution temperatures $70-130^{\circ}C$. Viscosity was increased as dissolution temperature was increased. PVA solutions prepared at 120 and $130^{\circ}C$ showed Bingham behavior, which became less noticeable with decreasing dissolution temperature. The modified Cole-Cole plot of the solutions gave slope less than 2, suggesting the solutions were a heterogeneous system irrespective of optical transparency. Further, the slope was decreased with increasing dissolution temperature, indicating that the solid character got more prominent as dissolution temperature was increased. However, the relaxation time of the solutions was little dependent on dissolution temperature.

합성조건에 따른 Polyacrylamide 수화 겔의 흐름변성 성질 (Thixotropic Properties of Polyacrylamide Hydrogels with Various Synthetic Conditions)

  • 김남정
    • 대한화학회지
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    • 제50권6호
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    • pp.447-453
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    • 2006
  • 수화 겔의 유변성질에 있어서 합성 조건과 수화 물 양의 영향이 연구되었다. cone-plate 레오메타를 사용하여 polyacrylamide 수화 겔의 비 뉴톤 유동 곡선을 얻었다. 이렇게 얻은 유동곡선에 유동에 대한 비뉴톤식을 적용하여 유변 파라메타를 계산하여 얻었다. polyacrylamide 수화 겔은 전단속도가 증가함에 따라 구조가 약해지는 흐름변성 현상을 나타낸다. 이들 유동성질은 유동단위의 특성과 유동 분절사이의 상호 관계에 의해서 나타나는 물질적인 성질이다.

리올러지 모델을 이용한 열적 기계적 변형 거동 모사 (A Description of Thermomechanical Behavior Using a Rheological Model)

  • 이금오;홍성구;이순복
    • 대한기계학회논문집A
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    • 제30권7호
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    • pp.757-764
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    • 2006
  • Isothermal cyclic stress-strain deformation and thermomechanical deformation (TMD) of 429EM stainless steel were analyzed using a rheological model employing a bi-linear model. The proposed model was composed of three parameters: elastic modulus, yield stress and tangent modulus. Monotonic stress-strain curves at various temperatures were used to construct the model. The yield stress in the model was nearly same as 0.2% offset yield stress. Hardening relation factor, m, was proposed to relate cyclic hardening to kinematic hardening. Isothermal cyclic stress-strain deformation could be described well by the proposed model. The model was extended to describe TMD. The results revealed that the hi-linear thermomechanical model overestimates the experimental data under both in-phase and out-of-phase conditions in the temperature range of $350-500^{\circ}C$ and it was due to the enhanced dynamic recovery effect.

고로슬래그 분말도가 시멘트 페이스트의 유동특성에 미치는 영향 (Effect of Blastfurnace Slag Fineness on the Rheological Properties of Cement Pastes)

  • 송종택;유창달;변승호
    • 한국세라믹학회지
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    • 제44권2호
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    • pp.103-109
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    • 2007
  • In this study, the rheological properties of cement pastes containing blastfurnace slag of different fineness were investigated. The fluidity of cement pastes with low Blaine value blastfurnace slag was increased with decreasing the plastic viscosity and the yield stress of pastes. And the optimum dosage of polycarboxylate type superplasticizer to the cement pastes was confirmed according to the fineness and the replacement ratio of blastfurnace slag. All cement pastes showed the thixotropy behavior. And also it was formed that the segregation range of cement pastes was occurred below $10D/cm^2$ of the yield stress and below 350 cPs of the plastic viscosity by the coaxial cylinder viscometer.

Effect of Extraction Time on the Rheological Properties of Sericin Solutions and Gels

  • Yoo, Young Jin;Um, In Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • 제27권1호
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    • pp.180-184
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    • 2013
  • Recently, silk sericin has attracted the attention of researchers owing to its useful properties as a biomaterial including 1) good wound healing and cell activities, 2) fast gelation character, and 3) high water retention property. In the present study, silk sericin was prepared using different extraction times in hot water and the effect of extraction time on the rheological properties of sericin solutions and gels was examined. It was found that the production yield of sericin increased with extraction time. The shear viscosity of sericin solutions and gels decreased with increasing extraction time due to a decrease in sericin molecular weight. When the sericin solution transformed to a gel, the viscosity increased and the shear thinning behavior was more evident. In addition, the shear stress measurements indicated that the slip between the sericin samples and the measuring plate of the rheometer was increased by the gelation of sericin. The compression strength of sericin gel could be increased remarkably (by more than 100 fold) by preparation using the freezing and thawing method.

전기유동유체를 이용한 엔진마운트의 모델구성과 성능해석 (Model Synthesis and Performance analysis of an Engine Mount Using Electro-Rheological Fluids)

  • 최영태;김기선;최승복;정재천;전영식
    • 한국자동차공학회논문집
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    • 제2권3호
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    • pp.62-74
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    • 1994
  • This paper addresses on the model synthesis and performance analysis of an engine mount featuring electro-rheological(ER) fluids which undergo a phase change when subjected to electric fields. A novel type of ER fluid-filled engine mount is devised and its hydraulic model is constructed. An equivalent mechanical model is subsequently obtained from the governing equation of the hydraulic model. The model parameters associated with the ER fluids are distilled from experimental investigations on the Bingham properties of the fluids. The distilled data are then incorporated into the governing model to undertake feasible work through computer simulations,. It is shown that the proposed engine mount has an inherent capability of controlling both the damping force and the resonance frequency. Other superior performance characteristics accrued from the proposed methodology are also evaluated.

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Magneto-Rheological Fluid를 이용한 인공지능 의족의 Compact damper 개발 (Design of Compact Magneto-Rheological Fluid Damper for Artificial Low-Limb Prosthesis)

  • 성소영;강성재;문인혁;문무성;장석명
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 D
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    • pp.2962-2964
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    • 2005
  • Magneto-Rheological (MR) fluid is suspension of fine magnetic particles in a liquid carrier such as silicon oil or water. MR fluid exhibits solid-like mechanical behavior into chain or clusters with high yield stress when magnetic field is applied to the particles. The response of MR fluids is very quick and reversible after removal of the field. MR Fluids have high yield stress (up to 5kPs) and operate in low voltage power supply. Recently, MR damper using MR fluids was open used in vibration control system such as structural devices, seat vibration controllers and helicopter rotor systems, but it is too big in size and heavy. Therefore, it is not appreciate to rehabilitation devices such as prosthetic limbs.

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Physical and Rheological Properties of Thermoplasticized Crosslinked-Polyethylene Foam in Supercritical Methanol

  • Cho, Hang-Kyu;Hong, Soon-Man;Baek, Kyung-Yeol;Koo, Chong-Min;Lee, Hong-Shik;Lee, Youn-Woo
    • Macromolecular Research
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    • 제17권12호
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    • pp.950-955
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    • 2009
  • The physical and rheological properties of thermoplasticized irradiation-crosslinked polyethylene foam using supercritical methanol treatment were investigated by GPC, FTIR, DSC, WAXS, DMTA and UDS. The polyethylene foam was selectively decrosslinked into thermoplasticized polyethylene in an appropriate supercritical methanol condition without any undesirable side reactions such as oxidation and disproportionation. The thermoplasticization was promoted with increasing reaction temperature to reach completion above $380^{\circ}C$. The supercritical reaction condition affected the crystallization behavior, and mechanical and rheological properties of the decrosslinked polyethylene foam, but not its crystallographic structure or crystallinity.

한계전단응력형태의 Bair & Winer 리올로지 모델을 사용한 선접촉 탄성유체윤활해석 (Elastohydrodynamic Lubrication of Line Contacts Incorporating Bair & Winer's Limiting Shear Stress Rheological Model)

  • 이희성;양진승
    • Tribology and Lubricants
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    • 제14권1호
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    • pp.85-93
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    • 1998
  • The Bair & Winer's limiting shear stress rheological model is incorporated into the Reynolds equation to successfully predict the traction and film thickness for an isothermal line contact using the primary rheological properties. The modified WLF viscosity model and Barus viscosity model are also adapted for the realistic prediction of EHD tractional behavior. The influences of the limiting shear stress and slide-roll ratio on the pressure spike, film thickness, distribution of shear stress and nonlinear variation of traction are examined. A good agreement between the disc machine experiments and numerical traction prediction has been established. The film thickness due to non-Newtonian effects does not deviate significantly from the fdm thicknesss with Newtonian lubricant.

Non-Newtonian Characteristics of Gochujang and Chogochujang at Different Temperatures

  • Choi, Ji Eun;Lee, Jun Ho
    • Preventive Nutrition and Food Science
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    • 제22권1호
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    • pp.62-66
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    • 2017
  • This study was conducted to determine the rheological properties of gochujang and chogochujang at different temperatures (25, 35, and $45^{\circ}C$). Rheological properties of the samples were determined using a rotational rheometer at a shear range of 1 to $40s^{-1}$. Gochujang and chogochujang were found to be non-Newtonian fluids according to the Herschel-Bulkley model. Yield stress and consistency coefficient of gochujang at different temperatures were higher than those of chogochujang, whereas the opposite was observed for flow behavior index. Moreover, all rheological properties of gochujang and chogochujang decreased with increasing temperature. The consistency coefficient was related to temperature using an Arrhenius-type relationship. Gochujang (14.48 kJ/mol) had slightly higher activation energy than chogochujang (14.03 kJ/mol).