• Title/Summary/Keyword: Rhenium

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Characteristics of Rhenium-Iridium coating thin film on tungsten carbide by multi-target sputter

  • Cheon, Min-Woo;Kim, Tae-Gon;Park, Yong-Pil
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.328-331
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    • 2012
  • With the recent development of super-precision optical instruments, camera modules for devices, such as portable terminals and digital camera lenses, are increasingly being used. Since an optical lens is usually produced by high-temperature compression molding methods using tungsten carbide (WC) alloy molding cores, it is necessary to develop and study technology for super-precision processing of molding cores and coatings for the core surface. In this study, Rhenium-Iridium (Re-Ir) thin films were deposited onto a WC molding core using a sputtering system. The Re-Ir thin films were prepared by a multi-target sputtering technique, using iridium, rhenium, and chromium as the sources. Argon and nitrogen were introduced through an inlet into the chamber to be the plasma and reactive gases. The Re-Ir thin films were prepared with targets having a composition ratio of 30 : 70, and the Re-Ir thin films were formed with a 240 nm thickness. Re-Ir thin films on WC molding core were analyzed by scanning electron microscope (SEM), atomic force microscope (AFM), and Ra (the arithmetical average surface roughness). Also, adhesion strength and coefficient friction of Re-Ir thin films were examined. The Re-Ir coating technique has received intensive attention in the coating processes field because of promising features, such as hardness, high elasticity, abrasion resistance and mechanical stability that result from the process. Re-Ir coating technique has also been applied widely in industrial and biomedical applications. In this study, WC molding core was manufactured, using high-performance precision machining and the effects of the Re-Ir coating on the surface roughness.

Densification Behavior of Rhenium Alloy using Master Sintering Curve

  • Park, Dong Yong;Oh, Yong Jun;Kwon, Young Sam;Lim, Seong Taek;Park, Seong Jin
    • Journal of Powder Materials
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    • v.21 no.1
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    • pp.7-15
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    • 2014
  • This study investigated the densification behavior of rhenium alloys including W-25 wt.%Re and Re-2W-1Ta (pure Re) during sintering. The dilatometry experiments were carried out to obtain the in-situ shrinkage in $H_2$ atmosphere. The measured data was analyzed through shrinkage, strain rate and relative density, and then symmetrically treated to construct the linearized form of master sintering curve (MSC) and MSC as a well-known and straightforward approach to describe the densification behavior during sintering. The densification behaviors for each material were analyzed in many respects including apparent activation energy, densification parameter, and densification ratio. MSC with a minimal set of preliminary experiments can make the densification behavior to be characterized and predicted as well as provide guideline to sinter cycle design. Considering the results of linearized form and MSC, it was confirmed that the W-25 wt.%Re compared to Pure Re is more easily densified at the relatively low temperature.

Surface Properties of Re-Ir Coating Thin Film on Tungsten Carbide Surface (Tungsten Carbide 표면에 코팅된 Re-Ir 박막의 표면 특성)

  • Lee, Ho-Shik;Cheon, Min-Woo;Park, Yong-Pil
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.3
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    • pp.219-223
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    • 2011
  • Rhenium-Iridium(Re-Ir) thin films were deposited onto the tungsten carbide(WC) molding core by sputtering system. The Re-Ir films were prepared by multi-target sputtering with iridium, rhenium and chromium as the sources. Argon and nitrogen were inlet into the chamber to be the plasma and reactive gases. The Re-Ir thin films were prepared with targets having atomic percent of 3:7 and the Re-Ir thin films were formed with 240 nm thickness. The Re-Ir thin films on tungsten carbide molding core were analyzed by scanning electron microscope(SEM) and surface roughness. Also, adhesion strength and coefficient friction of Re-Ir thin film were examined. The Re-Ir coating technique has been intensive efforts in the field of coating process because the coating technique and process have been their feature, like hardness, high elasticity, abrasion resistance and mechanical stability and also have been applied widely the industrial and biomedical areas. In this report, tungsten carbide(WC) molding core was manufactures using high performance precision machining and the efforts of Re-Ir coating on the surface roughness.

Performance Analysis of A Variable-Spacing Cesium Thermionic Energy Converter (열전변환 장치의 특성 분석에 대한 연구)

  • Lee, Deuk-Yong
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.9
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    • pp.1085-1094
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    • 1992
  • A variable-spacing cesium thermionic energy conversion test station is designed and fabricated for the study of power generation. The diode is in the form of a guard-ringed plane-parallel geometry in which a polycrystalline rhenium emitter of 2 cmS02T area faces a radiation-cooled polycrystalline rhenium collector of 1.9 cmS02T area. The emission of plasma from heated refractory electrode metal is the driving reaction in the direct conversion of heat to electricity by thermionic energy conversion. The plasma is produced from electrons and positive ions formed simultaneously by thermionic emission and surface ionization of cesium atoms incident on the hot emitter from the cesium vapor in the diode. And high plasma density causes plasma multiplication within the gap due to volume ionization that results in high power output. The variation of the saturation current of a Knudsen converter is investigated at an emitter-collector gap of 0.1 mm and an emitter temperatures. A maximum power output of 13.47 watta/cmS02T is observed at a collector temperature of 963 K and a cesium reservoir temperature of 603 K.

Labelling with Rhenium-188 (Rhenium-188 방사성 의약품)

  • Choe, Yearn-Seong
    • 대한핵의학회:학술대회논문집
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    • 1999.05a
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    • pp.193-195
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    • 1999
  • There is considerable interest in $^{188}Re$ due to its favorable properties as a therapeutic radionuclide $^{188}Re$ and $^{99m}Tc$ act as a matched pair because of their similar chemical properties, and therefore methods of labeling with $^{99m}Tc$ can be applied to the labeling with $^{188}Re$. With appropriately chosen agents as carriers of $^{188}Re$, the labeling can be readily carried out using $^{188}ReO_4^-$ in the presence of a reducing agent. $^{188}Re$ radio-pharmaceuticals based on $^{99m}Tc$ complexes have been synthesized and are currently being studied for clinical use. Some of them are shown to be suitable for therapeutic use and promising for radiotherapy in nuclear medicine.

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Development of Basking Neodymium Lamp Improving Reflector Globe and Rhenium Filament (레늄 필라멘트와 반사 글로브를 개선한 Basking Neodymium Lamp의 개발)

  • Eo, Ik-Soo;Yang, Hae-Sool
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.3
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    • pp.477-482
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    • 2007
  • This paper examines and analyzes improvement of structure of bulb, increase of luminous efficiency through application of reflector globe through aluminum coating and development of 60[W] basking neodymium lamp through optimum insertion ratio of krypton gas and nitrogen gas. The results of this development shows that the life of the lamp was 7,200 hours, and the luminous flux was 620[1m]. This brings in superior color temperature and superior color rendering index, which allows us to use that lamp for agricultural or general purpose.

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Recovery of Rhenium by Alamine304-1 from the trace amount of Rhenium in HCl Solution (Alamine304-1를 이용한 레늄미량함유 염산용액으로부터 레늄 회수)

  • Jeong, Hui-Gyeong;Jang, Jae-Yong;An, Jong-Gwan;Kim, Min-Seok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.84-85
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    • 2014
  • 레늄미량함유 염산용액중에서 추출제로 Alamine304-1(Henkel), Cyanex272(Daihachi)와 $D_2EHPA(Henkel)$를 사용하여 용매추출공정으로 레늄의 추출거동을 조사하였다. 수상에 존재하는 레늄은 60 ppm이며, Kerosine과 추출제를 혼합한 합성용액을 사용하였다. 레늄 회수의 최적조건을 조사하기 위해 추출제의 종류 및 농도, 수상과 유기상의 상비, HCl의 농도, 불순물 분리 실험 등을 진행하였다. 수상의 pH가 2 이하이고, 상비는 1:1로 하여 1 % Alamine304-1으로 10분간 반응시킨 후 상온에서 1시간 이상 정치시켰을 때 레늄의 추출율이 99 % 이상으로 가장 우수하였으며, Cyanex272와 D2EHPA를 사용한 경우에는 레늄의 거의 추출되지 않았다.

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