• Title/Summary/Keyword: Reversible heat

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Cost Estimating of Heat and Electricity on a Gas-Turbine Cogeneration (가스터빈 열병합발전에서 생산된 열과 전기의 원가산정)

  • Kim, Deok-Jin
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.351-356
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    • 2008
  • When various kinds of outputs are produced from a single energy system, the methodology which allocates the common cost to each output cost is very important because it is directly related with the profit and loss of producers and purchasers. In the cost allocation methodology of the heat and the electricity on a cogeneration, there are energy method, work method, proportional method, benefit distribution method, various exergetic methods, and so on. On the other hand, we have proposed a worth evaluation method which can be applied to any system. The definition of this methodology is that the unit cost of a product is proportion to the worth. Where, worth is a certain evaluating basis that can equalize the worth of products. In this study, we applied this methodology to a gas-turbine cogeneration which produces 119.2 GJ/h of electricity and 134.7 GJ/h of heat, and then we allocated 3,150 $/h of fuel cost to electricity cost and heat cost. Also, we compared with various cost allocation methods. As the result, we conclude that exergy of various kinds of worth basis evaluates the worth of heat and electricity most reasonably on this system.

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Syntheses and Characterisitics of New Photochromic Spiroxazine Dyes (새로운 광변색성 Spiroxazine색소의 합성과 특성)

  • 김성훈
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.159-168
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    • 1994
  • The Aggregation State of thin vapor deposite Film made by Cyanine Dye were changed into Monomeric molecular state(M) and Dimeric Aggregation(D) at the acidic treatment, into reversible H-Aggregation (H) at alkalic gas or heat treatment. Photo-electric properties were higher H than D and M, this stats were effective in enhancing Photoelectric-conversion characteristic. Substitute group of Meso-Position being stronger electronic Donors, Electronic density is higher and Electric conductivity is enhanced, we confirmed Oscillator Strength calculated by PPP-Molecular Orbital Calculation and Absorption Spectra at solvent stats were agreed good.

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Plotting of 13 Kinds of Properties on Temperature-Entropy Chart of Air (공기의 온도-엔트로피 선도 상에서 13 종류의 물성치 작도)

  • Kim, Deok-Jin;Kim, Duck-Bong
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.1191-1196
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    • 2009
  • The T-s chart of air displays graphically the thermophysical properties, so it is very conveniently used in various thermal systems. In previous study, the software analyzing 31 kinds of values in water system and 32 kinds of values in air-conditioning system were developed. In this study, the software drawing 13 kinds of quantity of state on air properties as ideal gas and analyzing 25 kinds of values in any air system was developed. The 13 kinds of quantity of state on air properties are temperature, pressure, specific volume, specific internal energy, specific enthalpy, specific entropy, specific exergy, exergy ratio, density, isobaric specific heat, isochoric specific heat, ratio of specific heat, and velocity of sound, and the 25 kinds of values including 13 kinds are mass flow rate, volume flow rate, internal energy flow rate, enthalpy flow rate, entropy flow rate, exergy flow rate, heat flow rate, power output, power efficiency, reversible work, lost work, and relative humidity. The developed software can draw any range of chart and analysis any state or process on air system. Also, this supports various document-editing functions such as power point. We wish to this chart is a help to design, analysis, and education in air system field.

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Preparation and Characterization of $Ge_{20}As_{20}Se_{60}$ Amorphous Chalcogenide Thin Film by Spin Coating (Spin-coating에 의한 $Ge_{20}As_{20}Se_{60}$ 비정질 chalcogenide 박막의 제조 및 광특성 분석)

  • 이강구;최세영
    • Journal of the Korean Ceramic Society
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    • v.37 no.3
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    • pp.219-226
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    • 2000
  • Amorphous Ge20As20Se60 chalcogenide thin films were prepared by spin coating technique from mixed solutions of As40Se60 and Ge40Se60 dissolved in ethylenediamine. Films were prepared at a roating speed of 3500 rpm and spinning time was 10 second and heat-treateed at 27$0^{\circ}C$ for 1 hour. The resulting film thickness and RMS roughness were approximately 340 nm and 15$\AA$. Photostructure changes were investigated with 514.5nm Ar+ laser irradiation and heat-treatment. After Ar+ laser irradiation, transmittance and transmission efficiency decreased respectively up to 24.9% at 2.43 eV and 67.5% at 3.27 eV, and absorption edge shifted toward long wavelength. Optical bandgap changed from 2.03 to 1.83 eV, and absoprtion coefficient and absorption efficiency increased up to 0.33$\times$105cm-1 at 3.37eV and 88.3% at 1.31 eV, respectively. These photodarkening state were recovered reversibly by heat-treatment at 27$0^{\circ}C$ for 1 hour. Photodarkening and thermal bleaching effects by laser irradiation and heat-treatment revealed reversible amorphous-to-amorphous transition varying only coordination number.

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Program Development for Drawing of 26 Properties and System Analysis on T-s Diagram of Water or Vapor (물의 T-s 선도 상에서 26 종류의 물성치 작도 및 시스템 해석 프로그램 개발)

  • Kim, Deok-Jin
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.157-164
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    • 2008
  • The temperature-entropy diagram of water or vapor displays graphically the thermophysical properties, so it is very conveniently used in various thermal systems. On general T-s chart of water, there are temperature, pressure, quality, specific volume, specific enthalpy, specific entropy. However, various state and process values besides above properties can be plotted on T-s diagram. In this study, we developed the software drawing twenty six kinds of properties, that is temperature, pressure, quality, specific volume, specific internal energy, specific enthalpy, specific entropy, specific exergy, exergy ratio, density, isobaric specific heat, isochoric specific heat, ratio of specific heat, coefficient of viscosity, kinematic coefficient of viscosity, thermal conductivity, prandtl number, ion product, static dielectric constant, isentropic exponent, velocity of sound, joule-thomson coefficient, pressure coefficient, volumetric coefficient of expansion, isentropic compressibility, and isothermal compressibility. Also, this software can analyze and print the system values of mass flow rate, volume flow rate, internal energy flow rate, enthalpy flow rate, entropy flow rate, exergy flow rate, heat flow rate, power output, power efficiency, and reversible work. Additionally, this software support the functions such as MS-Power Point.

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Numerical Simulation considering Latent Heat Effect for Laser Cladding Process (잠열을 고려한 레이저 클래딩 공정의 수치해석)

  • Zhao, Guiping;Si, Ho-Mun;Jo, Jong-Du;Kim, Jae-Do
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.10
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    • pp.134-147
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    • 2001
  • Laser cladding process accompanies phase transformations from melting (on heating) through solidifying (on cooling) at the same time within a small material volume and to final solid phase. The phase transformations are not reversible, but an irreversible thermodynamic process; they accompany either absorption or release of thermal energy (referred to latent heat) during transformation. Yet, most analyses on materials processed by laser as a heat source have been performed on models of neglecting the latent heat in the process and those did not Justify the simplification. With literatures on the laser material process, we have not place an answer to how little the assumption affects on analyses. This led us to our current study: the effects of latent heat on thermo-mechanical analysis. To this end, we developed a fairly accurate program accommodating an algorithm for enforcing the latent heat whenever necessary and ran it combining with ABAQUS$^{TM}$. The simulation techniques we used in this study were verified by directly comparing our prediction with experimental publications elsewhere; our numerical results agreed accurately with the experiments. On the effects of the latent heat, we performed two alternatives about considering the latent heat in analysis, and compared each other. As a result, we found that more accurate conclusions might come out when considering the latent heat in process analyses.s.

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Synthesis of AlO(OH) Nano Colloids from γ-Al2O3 via Reversible Process (γ-Al2O3로부터 가역과정을 경유한 AlO(OH) 나노콜로이드의 합성)

  • Cho, Hyun-Ran;Kim, Sook-Hyun;Park, Byung-Ki
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.288-294
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    • 2009
  • The platelet AlO(OH) nano colloids were prepared by hydrothermal reaction of the $\gamma-Al_2O_3$ obtained with dehydration of $\gamma$-AlO(OH) and dilute $CH_3COOH$ solution. In hydrothermal reaction process, reversible reaction was accompanied between $\gamma-Al_2O_3$ and AlO(OH), and hydrothermal reaction temperature, hydrothermal reaction time and $CH_3COOH$ concentration had an effect on the crystal structure, surface chemical property, surface area, pore characteristics and crystal morphology of the AlO(OH) nano colloid particles. In this study, it was investigated to the hydrothermal reaction condition of the AlO(OH) nano colloid for using catalyst support, heat resisting agent, adsorbents, binder, polishing agent and coating agent. The crystal structure, surface area, pore volume and pore size of the platelet AlO(OH) nano colloids were investigated by XRD, TEM, TG/DTA, FT-IR and $N_2$ BET method in liquid nitrogen temperature.

Dynamic Behaviors of Externally-stimulated Monolayers on the Water Surface (외부 자격에 의한 수면상 단분자막의 동적 거동)

  • 배명한;송경호;박태곤;박근호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.4
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    • pp.318-325
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    • 2000
  • Dynamic behaviors of saturated-fatty acids $C_{16}$, $C_{18}$, $C_{20}$ and 8A5H with azobenzene were measured by displacement current method when the molecules are stimulated by pressure light and heat. When a barrier was compressed I-A, $\pi$-A isotherms of $C_{16}$, $C_{18}$, and $C_{20}$ were similar to each other but the displacement current of $C_{20}$ which has a long alkyl chain was relatively low. 8A5H showed the form of double liquid films and had a reversible reaction when a barrier was compressed and then expanded. When the molecules of 8A5H were stimulated by 365[nm] light the positive currents which were generated by the structural changes from trans to cis were measured. But the negative currents of the structural changes from cis to trans by 450[nm] light were too weak to detect. When the temperature of the water subphase was increased the surface pressures of the monolayers were increased early because of the thermal activations of the molecules and the double liquid films of 8A5H were disappeared above 40[$^{\circ}C$]EX>].

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Exergy Analysis on the System of Superheated Steam (700℃, 3 atm) Production for the Reversible Electrolysis: Based Hydrogen Production (양방향수전해 기반 수소제조용 초고온스팀 생산시스템의 엑서지 분석)

  • HAN, DANBEE;PARK, SENGRYONG;CHO, CHONGPYO;BAEK, YOUNGSOON
    • Journal of Hydrogen and New Energy
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    • v.29 no.3
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    • pp.235-242
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    • 2018
  • Hydrogen can be produced by reforming reaction of natural gas (NG) and biogas, or by water electrolysis. In this study, hydrogen production through water-electrolysis needs superheated steam above $700^{\circ}C$ for high efficiency. The production method of hydrogen like this was recommended for the 4-type processes for superheated steam ($700^{\circ}C$, 3 atm) by Bio-SRF combustion furnace. The 4-type processes to produce superheated steam at $700^{\circ}C$ from the heat source of SRF combustion furnace was simulated using PRO II. The optimum process was selected through exergy analysis. The difference of process 1 and 2 is to the order of depressure and heating process to change $180^{\circ}C$ and 7 atm to $700^{\circ}C$ and 3 atm. Process 3 and 4 is to utilize 25% of steam to generate superheated steam and remaining to use for the power generation by steam generator.

Preparation and Characterization of Pitch/Cokes Composite Anode Material for High Power Lithium Secondary Battery

  • Yu, Lan;Kim, Ki-Jung;Park, Dae-Yong;Kim, Myung-Soo;Kim, Kab-Il;Lim, Yun-Soo
    • Carbon letters
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    • v.9 no.3
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    • pp.210-217
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    • 2008
  • Petroleum pitch and coke with wet mixture method or with dry mixture method were investigated to develop the composite anodic carbon material of high power lithium ion battery. Cokes coated with pitch were obtained by the heat treatment of mixture of cokes and pitch with different weight ratios at $800{\sim}1200^{\circ}C$. The charge and discharge characteristic of the consequent composite anodic carbon material assembled in batteries was tested. Cokes with wet mixture method have a smooth surface and their capacity changed little with changing temperature and content as compared to the cokes with dry mixture method. Although the reversible capacities showed different values by the anode manufacturing method, the composite anode with the mixture of 20 wt% of petroleum pitch and 80 wt% of coke showed the higher power capability and initial efficiency than the pitch based anode. However, the reversible capacity of the composite anode showed the reduced value as compared with the pitch based anode.