• Title/Summary/Keyword: Reverse-osmosis

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A Study on the Treatment of Wastewater from Ion Removal Process for Purifying Electrocoat Paint in the Bath by Use of Reverse Osmosis (역삼투압을 이용한 전착도료 정제공정폐수처리에 관한 연구)

  • 김진성
    • Membrane Journal
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    • v.8 no.2
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    • pp.77-85
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    • 1998
  • To treat effectively EDIR (electrodeposition ion removal) wastewater in terms of CO$_{Mn}$ 1,500~2,000 ppm generated from aluminum painting process, a RO (reverse osmosis) process was designed and installed to recover and reuse the concentrated solvent sent back to the electrocodeposition tank while the permeate reused as rinse water. A RO system in which three polyamide-spiral wound modules ($102\Phi \times 1,016L$ mm) connnected in series had been running to treat 20 m$^3$ in waste volume in 3 days batch operation at the condition of system recovery of 30 %, applied pressure 11.5 $kg_f/cm^2$ and room temperature. During 42 hours continuous operation leading to 5-fold decrease in waste volume, nearly constant permeation flux of 390 l/m$^2$-hr was maintained and the permeate with average CO$_{Mn}$, 300 ppm was obtained which could be used for washing the remaining paint solution in ion-exchange tower instead of demineralized water. Also COD$_{Mn}$ rejection as a function of running time was observed to be in the range of 78~87 % and the observed solvent rejections for ethyl cellusolve, buthyl cellusolve and n-butanol were 79 %, 87 % and 70 %, respectively.

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Effects of Concentrated Pig Slurry Separated from Membrane Filter and Several Environment-Friendly Agro-Materials Mixtures on the Growth and Yield of Lettuce (Lactuca sativa L.) in Hydroponics (막분리 돈분농축액비와 몇가지 친환경농자재의 혼합액이 수경재배에서 상추의 생육과 수량에 미치는 영향)

  • Ryoo, Jong-Won
    • Journal of Animal Environmental Science
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    • v.16 no.1
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    • pp.51-60
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    • 2010
  • This experiment was conducted to investigate the effects of concentrated pig slurry separated from membrane filter and by environment-friendly agro-materials mixtures on growth of lettuce in hydroponics. The swine waste treatment system having a ultra filtration and a reverse osmosis process was designed in this study. Filtration of pig slurry was necessary to prevent the hose clogging in hydroponics. Primary separation using ultra filter was followed by concentration by RO (Reverse Osmosis). The concentrated pig slurry (CS) was mixed by five different environment-friendly agro-materials mixtures. The chemical nutrient solution was the solution of National Horticulture Research Station for the growth of lettuce. The concentration of nutrient solution in hydroponics was adjusted a range of 1.5 mS/cm in EC. The concentrated pig slurry was low in phosphorus(P), suspended solid and heavy matal, but rich in potassium (K). The concentrated slurry was lowest in the growth characteristics of leaf lettuce. And also SPAD value in leaf was reduced in plot treated with concentrated slurry. But the growth of lettuce in the mixtures plot (CS+BM+AA, CS+BM+AA+SW) in hydroponics was significantly high compared to concentrated slurry. The fresh yield of lettuce was 78, 84% that of nutrient solution as 131.9, 142.2g in plot of CS+BM+AA and CS+BM+AA+SW, respectively. Our studies have shown that it is possible to produce organic culture using concentrated slurry and environment-friendly agro-materials mixture, although growth is slower than when using a conventional inorganic hydroponic solution.

Progress in Nanofiltration-Based Capacitive Deionization (나노여과 기반 용량성 탈이온화의 진전)

  • Jeong Hwan Shim;Rajkumar Patel
    • Membrane Journal
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    • v.34 no.2
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    • pp.87-95
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    • 2024
  • Recent studies explore a wide array of desalination and water treatment methods, encompassing membrane processes such as reverse osmosis (RO), nanofiltration (NF), and electrodialysis (ED) to advanced capacitive deionization (CDI) and its membrane variant (MCDI). Comparative analyses reveal ED's cost-effectiveness in low-salinity scenarios, while hybrid systems (NF-MCDI, RO-NF-MCDI) show improved salt removal and energy efficiency. Novel ion separation methods (NF-CDI, NF-FCDI) offer enhanced efficacy and energy savings. These studies also highlight the efficiency of these methods in treating complex wastewater specific to various industries. Environmental impact assessments emphasize the need for sustainability in system selection. Additionally, the integration of microfabricated sensors into membranes allows real-time monitoring, advancing technology development. These studies underscore the variety and promise of emerging desalination and water treatment technologies. They provide valuable insights for enhancing efficiency, minimizing energy usage, tackling industry-specific issues, and innovating to surpass conventional method limitations. The future of sustainable water treatment appears bright, with continual advancements focused on improving efficiency, minimizing environmental impact, and ensuring adaptability across diverse applications.

Comparative Analysis of Seawater Desalination Technology in Korea and Overseas (국내 및 해외의 해수담수화 기술 비교분석)

  • Hwang, Moon-Hyun;Kim, In S.
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.5
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    • pp.255-268
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    • 2016
  • Climate change has increased the need to secure a new water resource in addition to the traditional water resources such as surface water and ground water. The seawater desalination market is growing sharply in accordance with this situation in Korea, "seawater engineering & architecture of high efficiency reverse osmosis (SEAHERO)" program was launched in 2007 to keep pace with world market trend. SEAHERO program was completed in 2014, contributed to turn the domestic technology in evaporative desalination technology to RO desalination technology. Currently, it is investigated that the average specific energy consumption of the whole RO plant is around $3.5kWh/m^3$. The Busan Gi-jang plant has shown $3.7{\sim}4.0kWh/m^3$, including operational electricity for plant and maintenance building. Although not world top level, domestic RO technology is considered to be able to compete in desalination market. Separately, many researchers in the world are developing new technologies for energy savings. Various processes, forward osmosis (FO), membrane distillation (MD) process are expected to compete with RO in the future market. In Korea, FO-RO hybrid process, MD and pressure retarded osmosis (PRO) process are under development through the research program in Ministry of Land, Infrastructure and Transport (MOLIT). The desalination technology level is expected to decrease to $2.5kWh/m^3$.

Characteristics of Adsorption on the RO Membrane Surface by Coagulants Types (응집제 종류에 따른 RO막 표면 흡착 특성)

  • Jeong, Youngmi;Park, Chanhyuk;Lee, Sanghyup;Kweon, Jihyang
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.4
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    • pp.477-483
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    • 2007
  • A coagulation process for RO (reverse osmosis) membrane pretreatment system was an effective technology to remove colloidal and particulate matters. However, coagulant residuals from the pretreatment process may negatively affect RO membrane performance. The bench-scale coagulant exposure study was performed to investigate the effect of their residual on adsorbed mass which related to the membrane performance. Coagulant addition in this study ranged from 0 to 5mg/L ferric chloride, alum, and 2mg/L cationic polymer(poly-di-methyldiallyl ammonium chloride) as coagulant aids. This results showed that adsorbed mass is not significantly increased during short-time period, however, accumulated mass of coagulants on the membrane surface is significantly increased during long-time experimental period. The effect of pH on coagulants adsorption characteristics was significantly differed due to the electrostatic repulsive interactions between soluble coagulants and membrane surface charge. This data suggest that the RO membrane performance of drinking water treatment plant could be decreased by adsorption of residual coagulants when applied for the coagulant pretreatment process.

An Economic Analysis of Desalination for Potential Application in Korea (국내 적용을 위한 해수 담수화 경제성 분석)

  • Park, No Suk;Park, Hee Kyung;Park, Mi Hyun;Kim, Byung Duck
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.3
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    • pp.48-54
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    • 1998
  • Korea becomes one of the countries which suffer from water shortage. It is expected that its water shortage in the early 2000's will be more than 10% of the annual demand. The shortage problem is more serious in the coastal areas where many industry complex locate. To solve the shortage problem, seawater desalination gets more attention as an alternative water supply source since Korea is surrounded by sea on its three sides. For potential application of seawater desalination in Korea, an economic analysis was conducted using cost data for the plants in the Middle Ease areas, The United states and others. The study is to provide a basis for the government to establish a strategy for promoting seawater desalination in Korea. It is discussed that the Reverse Osmosis (RO) process gets cheaper over times than the thermal processes of Multi-stage Flash Distillation (MSF) and Multi Effect Distillation (ME), especially in case where the capacity is less than about 50,000 ton/day. The unit cost of RO seawater is analyzed about US$1.35/ton in 1990 price. Since the Desalination plant can be operated regardless of weather conditions, industries in Korea's coastal areas which suffer from frequent droughts and water shortages are recommended to look into this option with more attention.

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Inorgainc fouling and it fouling reduction in direct contact membrane distillation process (직접 접촉식 막 증발공정에서 무기 막오염 특성 분석 및 저감방법)

  • Lee, Tae-Min;Kim, Seung-Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.2
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    • pp.115-125
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    • 2020
  • This study was aimed to examine inorganic fouling and fouling reduction method in direct contact membrane distillation(DCMD) process. Synthetic seawater of NaCl solution with CaCO3 and CaSO4 was used for this purpose. It was found in this study that both CaCO3 and CaSO4 precipitates formed at the membrane surface. More fouling was observed with CaSO4(anhydrite) and CaSO4·0.5H2O(bassanite) than CaSO4·2H2O(gypsum). CaCO3 and gypsum were detected at the membrane surface when concentrates of SWRO(seawater reverse osmosis) were treated by the DCMD process, while gypsum was found with MED(multi effect distillation) concentrates. Air backwash(inside to out) was found more effective in fouling reduction than air scouring.

Evaluation of Water Quality using ICR Mouse 1-cell Embryo (ICR계 생쥐 1세포배를 이용한 수질의 평가)

  • Kim, Chung-Hyon;Cheong, Kyung-Soon;Park, So-Hyun;Hwang, Do-Yeong;Kim, Ki-Chul;Min, Eung-Gi
    • Clinical and Experimental Reproductive Medicine
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    • v.21 no.1
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    • pp.63-68
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    • 1994
  • To confirm the overcome of in vitro 2-cell block, ICR mouse I-cell embryos were cultured in CZB media. All embryos in CZB were overcome in vitro 2-cell block and 92% of embryos were developed to the blastocyst at day 4. However, in m-KRB group(control) only 20% of embryos were developed over 2-cell. Any embryos in m-KRB did not develop to the morular stage. Developments and degenerations of ICR mouse I-cell embryos were compared in CZB medium prepared with water of three quality:(l) Milli-Q ultrafiltration water(UF);(2) Milli-Q reverse osmosis water(RO);(3) tap water(TAP). The objective was to evaluate the potential of quality control using ICR mouse 1-cell embryos. The more water was purified, the better embryo developments were supported and the less embryos were degenerated. As a quality control system, the culture of ICR 1-cell mouse embryos in CZB was useful.

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TDS Removal using Bio-sorption with AGS and High Concentration Nitrogen Removal (AGS의 생물흡착을 이용한 TDS 제거 및 고농도 질소제거에 관한 연구)

  • Eom, Han Ki;Choi, Yoo Hyun;Joo, Hyun Jong
    • Journal of Korean Society on Water Environment
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    • v.32 no.3
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    • pp.303-309
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    • 2016
  • This study aimed to assay the biological removal of TDS (total dissolved solids) from RO (reverse osmosis) rejected water. Following bio-sorption of TDS with AGS (aerobic granular sludge), the effects of TDS on biological nitrogen removal were examined. The bio-sorption of TDS after AGS treatment was confirmed by checking for TDS removal efficiency and surface analysis of microorganisms with SEM and EDS. Then, the effects of TDS on biological nitrogen removal and the denitrification efficiency were evaluated using the MBR reactor. According to the results, the bio-sorption of TDS with AGS was 0.1 mg TDS/mg AGS, and we confirmed that the microorganism surfaces had adsorbed the TDS. Biological nitrogen removal efficiency was measured at inhibiting denitrification at 4,000 mg/L of TDS-injected material. Based on this study, it is necessary to pretreat TDS-containing RO rejected water and to maintain TDS concentration lower than a specific value (≤4,000 mg/L), when considering biological nitrogen removal.

Measurements and methods for analyzing zeta potential of the external surface of hollow fiber membranes (중공사막 외부표면의 제타전위 측정방법 고찰)

  • Lee, Taeseop;Lee, Sangyoup;Lee, Joohee;Hong, Seungkwan
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.3
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    • pp.353-362
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    • 2009
  • A new method and equipment for measuring the zeta potential of the external surface of hollow fiber (HF) membranes is reported. An existing commercial streaming potential analyzer in conjunction with home-made test cells was used to determine the electrokinetic surface characteristics of various HF membranes. It was shown that measurements of the external surface of HF membrane using the home-made test cells designed in this study were easy and reliable. The zeta potential values were quite accurate and reproducible. By varying the physical shape of the test cells to adjust hydrodynamics inside the test cells, several upgrade versions of home-made test cells were obtained. It was shown that the zeta potential of the external surface of HF membranes was most influenced by membrane materials as well as the way of surface modification. However, the overall surface charge of tested HF membranes were much less than that of commercial polyamide thin-film-composite (TFC) reverse osmosis (RO) membranes due to the lack of surface functional groups. For the HF membranes with the same material, the effect of pore size on the zeta potential was not significant, implying the potential of accurate zeta potential measurements for various HF membranes. The results obtained in this study are expected to be useful for better understating of electrokinetic surface characteristics of the external surface of HF membranes.