• Nuclear Engineering and Technology
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• v.47 no.7
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• pp.859-866
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• 2015

The aim of this work is to investigate the transport mechanism of radioactive nuclides through the reverse osmosis (RO) membrane and to estimate its effectiveness for nuclide separation from radioactive liquid waste. An analytical model is developed to simulate the RO separation, and a series of experiments are set up to confirm its estimated separation behavior. The model is based on the extended Nernst-Plank equation, which handles the convective flux, diffusive flux, and electromigration flux under electroneutrality and zero electric current conditions. The distribution coefficient which arises due to ion interactions with the membrane material and the electric potential jump at the membrane interface are included as boundary conditions in solving the equation. A high Peclet approximation is adopted to simplify the calculation, but the effect of concentration polarization is included for a more accurate prediction of separation. Cobalt and cesium are specifically selected for the experiments in order to check the separation mechanism from liquid waste composed of various radioactive nuclides and nonradioactive substances, and the results are compared with the estimated cobalt and cesium rejections of the RO membrane using the model. Experimental and calculated results are shown to be in excellent agreement. The proposed model will be very useful for the prediction of separation behavior of various radioactive nuclides by the RO membrane.

• Membrane and Water Treatment
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• v.13 no.1
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• pp.39-49
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• 2022

Seawater desalination is doubtlessly a viable option to supply fresh drinking water. Nevertheless, RO (reverse osmosis) desalination plants in specific areas may be intermittently operated to match the imbalance between water demand and supply. Although a handful of works have been done on other membrane systems, few studies have attempted to mitigate fouling in intermittent RO systems. Accordingly, the objectives of this paper were to examine the effect of the intermittent operation on RO fouling; and to compare four intermittent operation modes including feed solution recirculation, membrane storage in the feed solution, deionized water (DI) recirculation, and membrane storage in DI water. Results showed that intermittent operation reduced RO fouling under several conditions. However, the extents of fouling mitigation were different depending on the feed conditions, foulant types, and membrane lay-up methods. When the feed solution was recirculated during the lay-up, the restoration of the flux was less significant than that by the feed solution feed-up. The use of deionized water during the lay-up was effective to restore flux, especially when the feed solution contains scale-forming salts (CaSO₄) and/or colloidal silica.

• Membrane Journal
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• v.29 no.6
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• pp.339-347
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• 2019

Forward osmosis (FO) is operated at a lower pressure than reverse osmosis (RO), which has great advantages in terms of fouling control, maintenance, membrane cleaning, and potential energy reduction. In particular, since the membrane fouling layer of the forward osmosis process has a relatively loose and dispersed property, it is possible to control the membrane fouling by physical cleaning, unlike the reverse osmosis process. However, existing studies do not apply the proper cleaning flow rate for forward osmosis physical cleaning, and thus there is a limit that the optimal operation can not be performed. Therefore, this study aims to evaluate the justification of proper flow rate that can show high efficiency cleaning with economical energy amount. The membrane fouling experiments of the forward osmosis process were maintained at a circulating flow rate of 8.54 cm/s and the recovery rates were compared with the three cleaning flow rates. As a result of this experiment, it was confirmed that the 2 × speed cleaning showed the same efficiency as the water permeability recovery rate of the 3 × speed cleaning, and it was confirmed that the 2 × speed cleaning was an appropriate flow rate with high cleaning efficiency and economical SEC.

• Membrane Journal
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• v.32 no.2
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• pp.126-132
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• 2022

Water purifiers have a quite different characteristic in comparison with general membrane water treatment processes in which the running and resting are repeated dozens of times a day. In the case of water purifiers using reverse osmosis membranes, this characteristic makes a phenomenon that the total dissolved solids (TDS) of permeate in water purifiers at the beginning of running shows a higher value than a normal value (TDS reduction is lower than a normal value). It is called "TDS creep". The effects of resting times and feed concentrations on the TDS creep were investigated. The feed flushing, the volume increase in permeate side and the flushing with purified water were applied to reduce TDS creep and the effectiveness were observed. Among these trials, the minimization of concentration between feed and permeate side of reverse osmosis membrane like the flushing with purified water can be an ultimate solution to reduce the TDS creep.

• Membrane Journal
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• v.10 no.1
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• pp.1-18
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• 2000

• Membrane Journal
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• v.23 no.6
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• pp.439-449
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• 2013

This study investigated the aromatic polyamide reverse osmosis membrane was modified with diphenylamine (DPA) for enhanced chlorine and fouling resistance and how to optimize. DPA has high reactivity and thermo chemical stability. The performance of a modified membranes was investigated and its surface analyzed using atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and contact angle measurement. The experiment was conducted while changing the conditions of temperature and DPA solution concentration.

• Membrane Journal
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• v.27 no.4
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• pp.291-312
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• 2017

Seawater desalination is currently considered to be one of the primary technologies to resolve the global water scarcity problem. A basic understanding of membrane filtration phenomena is significant not only for further technological development but also for integrated design, optimal control, and long-term maintenance. In this vein, the present work reviews the major transport and filtration models, specifically related to reverse osmosis phenomena, provides theoretical insights based on statistical mechanics, and discusses model-based physical meanings as related to their practical implications.

• Transactions of the KSME C: Technology and Education
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• v.1 no.1
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• pp.59-68
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• 2013

In the present study, sea water reverse osmosis desalination system was composed with an ultra-filtration membrane as a pre-treatment. Sea water was induced into the pre-treatment composed with an auto-screen filter and an ultra-filtration membrane. It was proved that the permeate of the pre-treatment was adequate for reverse osmosis desalination system by measuring the $SDI_{15}$ and the turbidity. Feed salinities was changed by mixing the brine and the permeate. Inlet salinities effected the performances of sea water reverse osmosis desalination system in a large amount such as the salt rejection, the recovery ratio, the pressure, the product salinity. Energy consumptions per the ton of the product were almost linearly increased with the inlet salinities.

• Membrane and Water Treatment
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• v.4 no.1
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• pp.69-81
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• 2013

The pH-dependent inter-conversion of the three free chlorine species ($Cl_2$, HOCl, OCl-) present in the aqueous hypochlorite solution was theoretically investigated. Each species was found overwhelmingly present in a characteristic pH range. Hypochlorite treatment of the polyamide membrane was carried out over these pH ranges and various membrane responses were observed. As pH is less than 8, membrane tends to be N-chlorinated by $Cl_2$ and HOCl, and N-chlorinated membrane showed reduced water permeance and salt rejection. As pH rises to 10-12, $OCl^-$ appears to be the dominating chlorine species. Membrane hydrolysis was found to well interpret the improved water permeance and salt rejection. When the pH is between 8-10, both N-chlorination and hydrolysis contribute to the response of the membrane, and the treated membrane showed improved salt rejection but reduced water permeation. Excessive hydrolysis occurred while the membrane was treated at pH 13 for the much stronger alkalinity.

• Proceedings of the Membrane Society of Korea Conference
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• 1992.04a
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• pp.1-4
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• 1992

기존의 일반적인 에탄올 제조법으로는 1) ethylene의 가수분해, 2)전분이나 당분의 발효, 3)acetylene으로부터 얻은 acetaldehyde의 환원반응이 있다. 기존의 화석연로에 의존하지 않고 에탄올을 생성하는 방법은 발효에 의한 방법이다. 발효에 의해 생성되는 에탄올의 농도는 batch식 발효에서 13-14%, 고정화 발효방법에서 5-10%정도이다. 이를 고순도의 에탄올로 농축하기 위한 방법으로는 증류법, 투과증발법, 역삼투법등이 있으며 증류를 이용하여 농축하는 경우에는 상당히 큰 열에너지를 필요로 한다.