• Title/Summary/Keyword: Reused

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Nickel Nanoparticles: An Ecofriendly and Reusable Catalyst for the Synthesis of 3,4-Dihydropyrimidine-2(1H)-ones via Biginelli Reaction

  • Sapkal, Suryakant B.;Shelke, Kiran F.;Shingate, Bapurao B.;Shingare, Murlidhar S.
    • Bulletin of the Korean Chemical Society
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    • v.31 no.2
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    • pp.351-354
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    • 2010
  • Nickel nanoparticles (Ni NPs) appeared to exhibit the catalytic activity in one-pot cyclocondensation reaction for the preparation of 3,4-dihydropyrimidine-2(1H)-ones via Biginelli reaction from aromatic/heteroaromatic/aliphatic aldehydes, urea/thiourea and ethyl acetoacetate under microwave irradiation has been described. The UV absorbance spectra showed metallic Ni characteristics and appreciate with the particle size determined by Transmission electron microscopy (TEM). After reaction course the Ni NPs can be re-covered and reused without any apparent loss of activity.

Synthesis of 2-Substituted Benzofurans from o-Iodophenols and Terminal Alkynes with a Recyclable Palladium Catalyst Supported on Nano-sized Carbon Balls under Copper- and Ligand-Free Conditions

  • Yum, Eul Kgun;Yang, Ok-Kyung;Kim, Ji-Eun;Park, Hee Jung
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2645-2649
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    • 2013
  • We have developed a one-step synthesis of benzofurans from o-iodophenol and various terminal alkynes, by using Pd catalyst supported on nano-sized carbon balls (NCB) under copper- and ligand free conditions. This recyclable catalyst could be reused more than 5 times in the same heteroannulation reaction. The results have demonstrated that diverse 2-substituted benzofurans with tolerant functional groups can be prepared simply and conveniently under these conditions.

Selection of Cluster Topic Words in Hierarchical Clustering using K-Means Algorithm

  • Lee Shin Won;Yi Sang Seon;An Dong Un;Chung Sung Jong
    • Proceedings of the IEEK Conference
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    • 2004.08c
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    • pp.885-889
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    • 2004
  • Fast and high-quality document clustering algorithms play an important role in providing data exploration by organizing large amounts of information into a small number of meaningful clusters. Hierarchical clustering improves the performance of retrieval and makes that users can understand easily. For outperforming of clustering, we implemented hierarchical structure with variety and readability, by careful selection of cluster topic words and deciding the number of clusters dynamically. It is important to select topic words because hierarchical clustering structure is summarizes result of searching. We made choice of noun word as a cluster topic word. The quality of topic words is increased $33\%$ as follows. As the topic word of each cluster, the only noun word is extracted for the top-level cluster and the used topic words for the children clusters were not reused.

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Preparation of the MnO2/Macroporous Carbon for PET Glycolysis

  • Choi, Bong Gill;Yang, MinHo
    • Journal of Powder Materials
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    • v.25 no.3
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    • pp.203-207
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    • 2018
  • Plastic pollution is threatening human health and ecosystems, resulting in one of the biggest challenges that humanity has ever faced. Therefore, this study focuses on the preparation of macroporous carbon from biowaste (MC)-supported manganese oxide ($MnO_2$) as an efficient, reusable, and robust catalyst for the recycling of poly(ethylene terephthalate) (PET) waste. As-prepared $MnO_2/MC$ composites have a hierarchical pore network and a large surface area ($376.16m^2/g$) with a narrow size distribution. $MnO_2/MC$ shows a maximum yield (98%) of bis(2-hydroxyethyl)terephthalate (BHET) after glycolysis reaction for 120 min. Furthermore, $MnO_2/MC$ can be reused at least nine times with a negligible decrease in BHET yield. Based on this remarkable catalytic performance, we expect that $MnO_2$-based heterogeneous catalysts have the potential to be introduced into the PET recycling industry.

Microsurgical Training using Reusable Human Vessels from Discarded Tissues in Lymph Node Dissection

  • Ishii, Naohiro;Kiuchi, Tomoki;Oji, Tomito;Kishi, Kazuo
    • Archives of Plastic Surgery
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    • v.43 no.6
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    • pp.595-598
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    • 2016
  • The use of human vessels at the beginning of microsurgery training is highly recommended. But vessels with the appropriate length for training are not often obtained. Whether these vessels may be reused for training has not been reported. Accordingly, we harvested vessels from discarded tissues in lymph node dissection and demonstrated that vascular anastomosis training using the same human vessels several times is possible by placing the vessels in a freezer and defrosting them with hot water. Vascular walls can be stored for microsurgical training until about 4 years after harvest, as shown in the gross appearance and histologic findings of our preserved vessels. We recommend the technique presented here for the long-term reuse of human vessels for microsurgery training that closely resembles real procedures.

The Limiting Current Density and the Regeneration of a Heterogeneous Ion Exchange Membrane in a Nickel Plating Rinse Waters Treatment Process by Electrodialysis (전기투석에 의한 니켈도금 폐수처리 공정에서 한계전류밀도와 불균질 이온교환막의 재생)

  • 윤용수
    • Journal of environmental and Sanitary engineering
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    • v.16 no.2
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    • pp.38-46
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    • 2001
  • In this work, the heterogeneous ion exchange membrane was used in a electrodialysis apparatus to treat a Ni planting rinse water because the heterogeneous ion exchange membrane was excellent efficiency as compared with low manufacturing cost, was easy to make, and had a good mechanical properties. For a regeneration of membrane and to obtain the optimal condition for a scale-up of apparatus after treating Ni plating rinse water, we would find about the limiting current density and the concentration polarization. When the Ni plating rinse water 150mg/L was treated with the electrodialysis apparatus using the heterogeneous ion exchange membrane, the limiting current density was about $1.49{\;}mA/\textrm{cm}^2$. And the limiting current density increased with the flow rate and concentration of Ni plating rinse water. We recognized that the used membrane could be reused by periodic backwashing because efficiency was constant when the membrane was backwashed after treating wastewater.

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PHYSICAL PROPERTIES OF THE REUSED IPS-EMPRESS CERAMIC. PART II : STUDY ON THE FLEXURE STRENGTH (반복사용된 IPS-Empress ceramic의 물리적 성질에 관한 연구 Part II:굽힘강도에 관한 연구)

  • Jin, Tai-Ho;Kim, Hee-Jin
    • The Journal of Korean Academy of Prosthodontics
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    • v.36 no.3
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    • pp.524-529
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    • 1998
  • The purpose of this study was to investigate the possibility on recycling of IPS-Empress ceramic for the wide use of IPS-Empress ceramic in prosthodontic treatment. The frexure strength of first pressed, second pressed, and third pressed IPS-Empress ceramic were measured and compared. There was no ststistical difference among three groups, and the result of this study implied the recycled IPS-Empress ceramic has enough frexure strength for clinical use.

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A study on the marginal fitness to reuse with a Au-Pt-Pd alloy for porcelain fused to metal crown (도재용 금합금 재사용에 따른 변연 적합도에 관한 연구)

  • Moon, Hee-Kyung
    • Journal of Technologic Dentistry
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    • v.32 no.1
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    • pp.17-21
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    • 2010
  • This experimental study was to determine the fitness in each cervical margin of reusing porcelain gold alloy. The gold alloy used in this experimental study was a Au-Pt-Pd alloy (BDCG-898, Bukwang Inc, Korea) for the fabrication of porcelain fused to metal crown. Twenty-five copings were divided into the five groups. And the group A, B, C, D and E were cording successively according to the frequency of reuse to five times. Each specimen was reused without adding new metal. The experimental results were as follows: 1. The group A, B, C showed good fitness in each cervical margin. 2. The group D got good fitness in labio and linguo cervical margin, but the mesio and disto cervical margin showed more than $40{\mu}m$ 3. The group E showed worse fitness than the other groups in each cervical margin.

A Study on the Removal of Phosphorus in the Lake (호수내의 인 제거에 관한 연구)

  • Kim, Kyoungtae;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.2
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    • pp.59-66
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    • 1998
  • The feasibility of usage of sludge from water treatment plant and chalk from schools and institutes was investigated to remove the phosphorus in the lakes which induce the eutrophication every year. In this study phosphorus removal efficiencies of sludge and chalk were investigated by changing various factors. Higher phosphorus removal efficiency using larger particle size of chalk was observed which means that the surface area is not an important factor in removing phosphorus in aqueous phase. The proper shaking time and temperature were 2 hours and $25^{\circ}C$, respectively. The removal efficiency using sludge from water treatment plant was almost 100%, which is similar to those of CaO and $Ca(OH)_2$. It means that sludge can be reused in removing phosphorus. It was also found that chalk was better in removing phosphorus under alkaline condition and sludge was better under acidic condition. About 75% phosphorus removal efficiency was observed using sludge from the water sample in Lake Sihwa.

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Effect of Reactivation of Activated Carbon on Adsorption of Natural Organic Matter (활성탄 재생이 자연유기물질의 흡착에 미치는 영향)

  • Hong, Seongho;Choi, Jusol
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.3
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    • pp.323-329
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    • 2007
  • There is no certain definition about advanced drinking water treatment but it is generally known as activated carbon process, membrane process or ozone process which can remove non-conventional pollutants such as taste and odor compounds, and micro-pollutants. There are more than 20 processes related to activated carbon as adsorber or biological activated carbon in Korea. The saturated carbon by pollutants can be reused by reactivation. However, the effect of reactivation on activated carbon is not well-understood in terms of changing physical properties of carbon to adsorption capacity of natural organic matter (NOM). In this study, the effects of reactivation on physical properties of activated carbon were investigated by isotherm and breakthrough of NOM. Ash content was increased from 8% to 13.3%. Iodine number is commonly used as an indicator for performance of reactivation. The iodine number was decreased about 20% after reactivating twice. The degree of reactivation can be evaluated by not only iodine number but also apparent density.