• 한국해양공학회지
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• 제25권2호
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• pp.85-91
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• 2011

Many protection methods such as surface coating, electric protection, or other methods have been applied to the numerous steel structures widely used in continental and marine areas to control their corrosion, which is done from an economic point of view. Most of these steel structures are primarily protected by coating methods. However, some steel piles under seawater are protected by the electric protection method, that is, either using an impressed current or a sacrificial anode method. Furthermore, environmental contamination may cause a severely corrosive environment, which, in turn, causes the accelerated corrosion of steel structures. Subsequently, coated steel structures could deteriorate more rapidly than the designed lifetime because of the acid rain caused by air pollution, etc. Therefore, a coating of marine paint exposed to seawater, that is, underwater hardening painting, is increasingly required to be fast drying as well as highly corrosion resistant. In this study, five types of underwater hardening paints were prepared with different resin series and additives. Their corrosion and water resistances were investigated using electrochemical methods such as corrosion potential, polarization curves, impedance and cyclic voltammogram measurements, etc. Even though it is generally accepted that the corrosion resistance of bare steel tends to increase with a shift of the corrosion potential in the noble direction, the corrosion resistance of a sample with a coating exhibited a relatively better tendency when it had a lower corrosion potential in this study. The corrosion current density was also decreased with a decrease in the diffusion limiting current density, which may mean that there is some relationship between corrosion and water resistance. The S sample of the ceramic resin series showed the relatively best corrosion and water resistance among those of samples, while the worst corrosion and water resistance were observed for the R sample of the epoxy resin series. The corrosion and water resistance of those samples tended to deteriorate with an increase in the immersion days, and their corrosion and water resistances were considered to be apparently improved by the types of resin and additives.

• Journal of Advanced Marine Engineering and Technology
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• 제33권3호
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• pp.387-394
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• 2009

It has been observed that coated steel structures are rapidly deteriorated than designed lifetime due to acid rain caused by air pollution etc.. Therefore improvement of corrosion resistance of anti-corrosive paint is very important in terms of safety and economic point of view. In this study corrosion resistance for five kinds of anti-corrosive paints including acryl, fluorine and epoxy resin series were investigated with electrochemical methods such as corrosion potential, polarization curves, impedance and cyclic voltammogram measurements etc.. There were somewhat good relationships between values measured by electrochemical methods such as corrosion current density obtained by cathodic and anodic polarization curves, value of impedance estimated with AC impedance, and polarization resistance on the cyclic voltammogram, for example, corrosion current density was decreased with increasing of values of impedance and polarization resistance on the cyclic voltammogram. However their relationships between corrosion current density and corrosion potential were not well coincided each other. Consequently it is considered that although a corrosion potential of F101 of fuoric resin series shifted to negative direction than other anti-corrosive paints, its corrosion resistance, indicating on the cathodic and anodic polarization curves, AC impedance curves and cyclic voltammogram, was the most superior to other paints, whereas A100 containing arcylic resin showed a relatively poor corrosion resistance compared to other paints.

• Carbon letters
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• 제4권2호
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• pp.86-92
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• 2003

A series of micro- and mesoporous activated carbons were prepared from two kinds of phenolic resin using a metal treated chemical activation methodology. $N_2$-adsorption data were used to characterize the surface properties of the produced activated carbons. Results of the surface properties and pore distribution analysis showed that phenolic resin can be successfully converted to micro- and mesoporous activated carbons with specific surface areas higher than 973 $m^2/g$. Activated carbons with porous structure were produced by controlling the amount of metal chlorides ($CuCl_2$). Pore evolvement depends on the amount of additional metal chloride and precursors used. From the SEM and EDX data, copper contents were shown to be most effected by the incremental addition of metal chloride.

• Macromolecular Research
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• 제10권4호
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• pp.194-203
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• 2002

In resin infusion process(RIP), the fiber and the resin are in contact with each other for an impregnation step and often results in flow-induced defects such as poor fiber wetting and void formation. Resin flow characteristics in transverse direction and process modeling for woven fabric were studied, and the process modeling was applied to the manufacturing of hybrid composite materials. This study also considered the compressibility of woven fabrics in a series of compression force, and it was fitted well to an elastic model equation. Void formation was varied with the processing conditions in the stage of manufacturing composites using RIP. It was concluded from this study that proper combination of pressure build-up and dynamic heating condition makes important factor for flow-induced composite processing.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 1999년도 추계학술발표대회 논문집
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• pp.73-76
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• 1999

Near infrared spectroscopy techniques were used to study the cure reactions of epoxy resin system based on diglycidyl ether of bisphenol A(DGEBA) resins cured with 4, 4' diaminodiphenyl sulfone (DDS) hardner. Stoichiometric DGEBA/DDS resin formulation was involved in this study. The infrared absorption spectra of the prepared formulation were obtained on an FTIR spectrometer operating in the region of 11000 to 4000$cm^{-l}$. The chemical group peaks of interest in a DFEBA/DDS spectrum were identified by a comparative study with individual spectra of DGEBA and DDS monomers. Where necessary, special model compounds were used to identify unknown bands, such as the primary amine band at 4535$cm^{-l}$. The absorption bands of interest were integrated to quantify the areas and then converted to molar concentrations. This series of quantitative analyses of the major chemical groups led us to understand not only the reaction mechanism but also the cure kinetics. In this paper, the reaction mechanisms observed in stoichiometric DGEBA/DDS resin formulation and the various properties of the resin system as a function of cure temperature are described.

• Structural Engineering and Mechanics
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• 제62권3호
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• pp.273-279
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• 2017

A meso-scale model is proposed to study filament-wound composites with fiber undulations and crossovers. First, the crossover and undulation region is classified as the circumferential undulation and the helical undulation. Next, the two undulations are separately regarded as a series of sub-models to describe the meso-structure of undulations by using meso-parameters such as fiber orientation, fiber inclination angle, resin rich area, fiber volume fraction and bundle cross section. With the meso-structure model and the classic laminate theory, a method for calculating the stiffness of filament wound composites is eventually established. The effects of the fiber inclination angle, the fiber and resin volume fraction and the resin rich area on the stiffness are studied. The numerical results show that the elastic moduli for the circumferential undulation region decrease to a great extent as compared with that of the helical undulation region. Moreover, significant decrease in the elastic and shear moduli and increase in the Poisson's ratio are also found for the resin rich area. In addition, thickness and bundle section have evident effect on the equivalent stiffness of the fiber crossover and the undulation region.

• Geomechanics and Engineering
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• 제15권2호
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• pp.729-738
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• 2018

Soft clay soils due to their various geotechnical problems, stabilized with different additives. Traditional additives such as cement and lime will not able to increase the soil strength properties significantly. So, it seems necessary to use new additives for increasing strength parameters of soft clay soils significantly. Among the new additives, epoxy resins have excellent physical and mechanical properties, low shrinkage, excellent resistance to chemicals and corrosive materials, etc. So, in this research, epoxy resin used for stabilization of soft clay soils. For comprehensive study, three clay soil samples with different PI and various clay mineral types were studied. A series of uniaxial tests, SEM and XRD analysis conducted on the samples. The results show that using epoxy resin increases the strength parameters such as UCS, elastic modulus and material toughness about 100 to 500 times which the increase was dependent on the type of clay minerals type in the soil. Also, In addition to water conservation, the best efficiency in the weakest and most sensitive soils is the prominent results of stabilization by epoxy resin which can be used in different climatic zones, especially in hot and dry and equatorial climate which will be faced with water scarcity.

• 접착 및 계면
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• 제14권4호
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• pp.192-196
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• 2013

본 연구에서는 polypropylene (PP)을 기본 고분자로 하여, 석유수지(hydrocarbon resin, HCR) 종류와 함량을 달리하여PP/HCR 블랜드의 열량 거동을 분석하였고, 이를 이용하여 bi-axially oriented polypropylene (BOPP) 필름을 제조한 후 필름의 기계적 물성, 광학적 특성, 가스 및 수증기에 대한 투과도 그리고 수축률을 비교 평가하였다. 이 연구에서 HCR로는 수첨 dicyclopentadiene (DCPD) 수지와 수첨 C9 수지가 사용되었다. Homo-PP 대비 PP/HCR 블랜드는 stiffness의 증가 등 필름의 기계적 물성 증가, 필름의 haze 감소 등의 광학적 특성 향상, 가스 및 수증기에 대한 투과도 감소 그리고 필름의 수축률이 증가되었으며, HCR로 사용된 수첨DCPD수지와 수첨 C9수지는 기계적 물성 및 광학적 물성에서는 유사한 기여도를 보이지만, 가스 및 수증기에 대한 투과도와 필름의 수축률에 있어서는 차이를 보였다.

• 대한화학회지
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• 제20권3호
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• pp.240-243
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• 1976

리그닌을 알칼리로 活性化시키고 페놀 및 포름알데히드와 反應시켜 새로운 樹脂를 合成하였다. 合成된 樹脂는 木材의 接着劑로 쓸 수 있는 충분한 强度를 가졌음을 확인하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1987년도 정기총회 및 창립40주년기념 학술대회 학회본부
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• pp.499-503
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• 1987

The electrical characteristics of Epoxy Robin vary with temperature. In this study, the variation of the electric characteristics of Epoxy Resin with various hardening temperature was studied. Epoxy Resin used as samples are Epotohto YD-128 of Diglycidyl Ether of Bisphenol A (DGEBA) series and hardener, Goodmide G-240. It's mixing rate is 3 to 1. Hardening temperature was varied from 25[$^{\circ}C$] to 50[$^{\circ}C$] by 5[$^{\circ}C$]. During the hardening progress, illumination, resistivity and the internal temperature of material which were dependet on the variety of hardening temperature were measured. The electrical properties of hardened samples were examined by means of X-ray diffraction, tan $\delta$ test, TG-DTA analysis and treeing test. On this basis, optimal hardening temperature in insulation characteristics was examined.