• Title/Summary/Keyword: Resin Mixture Ratio

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Study on the Recovery and Determination of Scandium from Tin Slag (주석슬러그에서 스칸듐원소의 정량 및 회수에 관한 연구)

  • Cha, Gi Won;Jeong, Ui Sik;Kim, Gyeong Hwan
    • Journal of the Korean Chemical Society
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    • v.34 no.1
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    • pp.98-101
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    • 1990
  • A new spectrophotometric determination method of scandium in the tin slag solution has been investigated using methyl thymol blue as a colorimetric reagent. Scandium is recovered by the anion exchange resin, Amberlite IRA 400, using the mixture solution of ammonium sulfate and sulfuric acid and an eluent. The mole ratio of complex of scandium and MTB at pH 6 is 1 to 1 and the wave length of the maximum absorbance is 585 nm and the molar absorptivity at this wave length is $2.0 {\times} 10^4\;\iota{\cdot}mol^{-1}{\cdot}cm^{-1}$. When tin slag solution is loaded into anion exchange resin and eluted, ions in the solution except scandium ion are eluted rapidly and scandium is eluted lately. So scandium is recovered easily.

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Effects of UF Resin and Taro Adhesive Mixture on Plywood Bonding Strength (요소수지(尿素樹脂)와 토란접착제(土卵接着劑) 혼용(混用)이 합판(合板)의 접착력(接着力)에 미치는 영향(影響))

  • Lee, Phil-Woo;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.12 no.1
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    • pp.3-10
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    • 1984
  • Taro-UF mixed type resin system was developed for gluing plywoods. The taro adhesive that was activated with sodium hydroxide was mixed with the definite ratios of UF resin adhesive. At the sametime, wheat-UF mixed type resin was also applied with the same method as taro-UF mixed type resin The mixing ratios of taro or wheat adhesive: UF resin were 0:100, 10:90, 20:80, 30:70, 40:60, 50:50, 60:40, 80:20, and 100:0 by weight. In addition, the UF resins extended with wheat powder at the extending ratios of wheat powder UF resin, 10:90, 20:80, 30:70, 40:60, and 50:50 by weight, were also used. The dry and wet shear strengths of the plywoods of 30:70 (taro adhesive : UF resin) mixing ratio were highest. The dry shear strengths of the plywoods manufactured with the UF resin-mixing taro adhesive were higher than those of the plywoods with the UF resin-mixing wheat adhesive at 10:90, 20:80, 30:70, 40:60, 50:50, and 60:40 (taro or wheat adhesive: UF resin) mixing ratios. At all mixing ratios, the wet shear strengths of the plywoods manufactured with the UF resin-mixing taro adhesive were higher than those of the plywoods with the UF resin-mixing wheat adhesive. The dry and wet shear strengths of the plywoods manufactured with the UF resin-mixing wheat adhesive were higher than those of the plywoods with the wheat powder-extending UF resin at the mixmg ratios, 10:90, 20:80, 30:70, and 40:60 (wheat adhesive or wheat powder: UF resin). So, it was found that the plywoods manufactured with the UF resin-mixing taro adhesive and the UF resin mixing wheat adhesive had better shear strength than the plywoods with the wheat powder-extending UF resin. It was because the taro adhesive and wheat adhesive themselves took the bonding properties after being activated with alkali.

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Physical and Mechanical Properties of Three-layer Particleboards Bonded With UF and UMF Adhesives

  • Iswanto, Apri Heri;Simarmata, Janrahman;Fatriasari, Widya;Azhar, Irawati;Sucipto, Tito;Hartono, Rudi
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.6
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    • pp.787-796
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    • 2017
  • A low dimensional stability and poor bending strength properties were main problems in particleboard manufacturing. The objective of this research was to evaluate the effect of mixed wood species and urea-formaldehyde (UF) or urea-melamine-formaldehyde (UMF) resins on the physical and mechanical properties of three-layer particleboards. The ratio of face/core/back layer was 1 : 2 : 1. The resin content of 12% for both UF resins and UMF resins (UF/MF = 70/30% w/w) was used. The results of this study showed that the utilization of S.mahagony shaving using both UF and UMF resins caused a decrease in the thickness swelling and water absorption of the boards. Thickness swellings of particleboard made of Sengon/Sengon/Sengon (SSS), Mahogany/Mahogany/Mahogany (MMM), Sengon/Mahogany/Sengon (SMS), and Mahogany/Sengon/Mahogany (MSM) were in the range of 23%, 12~16%, 14~16%, and 13~21%, respectively. The board bonded with UMF resin demonstrated better dimensional stability than that bonded with UF resin alone. Modulus of elasticity (MOE) and modulus of rupture (MOR) of particleboards made of S. mahagony shaving in the surface layer in both MMM and MSM boards were better than those of the SSS and SMS. MOE of MMM and MSM board was in the ranges of 24,000 to $26,000kg.cm^{-2}$ and 18,000 to $21,000kg.cm^{-2}$ respectively. Meanwhile, the MOR of board was in the ranges of 200 to $240kg.cm^{-2}$ and 190 to $228kg.cm^{-2}$, respectively.

Preparation and Characteristic of Sheet Molding Compound using Unsaturated Polyester Resin with Low Profile Agent of Polystyrene (저수축제 폴리스틸렌과 불포화 폴리에스터 수지를 사용한 Sheet Molding Compound 제조 및 특성)

  • Bae, Gi Boong;Lee, Sang Goo;Yoon, Hong Jin;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.588-593
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    • 2012
  • Compatibility of unsaturated polyester (UP) and low profile agent (LPA) of polystyrene (PS) have been investigated under various mixing conditions such as the ratio of UP and LPA, mixing time, mixing temperature, and input amount of 2nd UP. It was possible to obtain mixture with small particle size and low phase separation in condition of 35 g of LPA, 25 g of 1st UP input, 5 min of mixing time, 1700 rpm of mixing speed, and 45 g of 2nd UP input. It was found that compatibility of UP and LPA was very sensitive to mixing conditions. In addition, molded sample using sheet molding compound prepared by stable mixing condition appeared good properties such as low water adsorption, low shrinkage, and high gloss.

Ballistic impact response of Kevlar Composites with filled epoxy matrix

  • Pekbey, Yeliz;Aslantas, Kubilay;Yumak, Nihal
    • Steel and Composite Structures
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    • v.24 no.2
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    • pp.191-200
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    • 2017
  • Impact resistance and weight are important features for ballistic materials. Kevlar fibres are the most widely reinforcement for military and civil systems due to its excellent impact resistance and high strength-to-weight ratio. Kevlar fibres or spectra fiber composites are used for designing personal body armour to avoid perforation. In this study, the ballistic impact behaviour of Kevlar/filled epoxy matrix is investigated. Three different fillers, nanoclay, nanocalcite and nanocarbon, were used in order to increase the ballistic impact performance of Kevlar-epoxy composite at lower weight. The filler, nanoclay and nanocalcite, content employed was 1 wt.% and 2 of the epoxy resin-hardener mixture while the nanocarbon were dispersed into the epoxy system in a 0.5%, 1% and 2% ratio in weight relating to the epoxy matrix. Specimens were produced by a hand lay-up process. The results obtained from ballistic impact experiments were discussed in terms of damage and perforation. The experimental tests revealed a number of damage mechanisms for composite laminated plates. In the ballistic impact test, it was observed whether the target was perforated completely penetrated at the back or not. The presence of small amounts of nanoclay and nanocalcite dispersed into the epoxy system improved the impact properties of the Kevlar/epoxy composites. The laminates manufactured with epoxy resin filled by 1 wt.% of nanoclay and 2 wt% nanocalcite showed the best performance in terms of ballistic performance. The addition of nanocarbon reduced ballistic performance of Kevlar-epoxy composites when compared the results obtained for laminates with 0% nanoparticles concentration.

Study on the Strength Characteristics of PP and ABS According to the Ratio of Recycled Resin (재사용 수지 비율에 따른 PP, ABS의 강도 특성에 관한 연구)

  • Jun-Han Lee;Jong-Sun Kim
    • Design & Manufacturing
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    • v.18 no.2
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    • pp.57-63
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    • 2024
  • In this study, the recyclability of commonly used PP (polypropylene) and ABS (acrylonitrile butadiene styrene) was evaluated by molding test specimens from mixture of virgin and shredded material, followed by measuring their strength properties, Experiments were conducted o two type of PP (transparent and non-transparent) and two types of ABS (white and yellow). Test specimens for each resin were prepared with shredded material ratios ranging from 10% to 50% in 10% increments. Changes in tensile strength, elastic modulus, and elastic limit were analyzed based on the mixing ratio of the shredded material. The experimental results demonstrated that the strength properties of all the resins remained consistent within a certain range, even with increasing proportions of shredded material. For transparent PP, the tensile strength ranged from 30.87± MPa, the elastic modulus from 1.23±0.04 GPa, and the elastic limit from 19.17±0.44%. Non-transparent PP exhibited a tensile strength ranging from 27.71±0.58 MPa, an elastic modulus from 1.03±0.06 GPa, and an elastic limit from 17.35±0.41%. For ABS, white ABS had a tensile strength of 39.42±0.28 MPa, an elastic modulus of 1.94±0.01 GPa, and an elastic limit of 36.76±0.25%. Yellow ABS showed a tensile strength of 39.25±0.78 MPa, an elastic modulus of 1.94±0.01 GPa, and an elastic limit of 37.14±0.23%, with values remaining consistent within this range. Based on these results, it was confirmed that the mechanical properties of the resins used in this study do not change significantly when mixed with recycled shredded material, indicating excellent mechanical recyclability.

A Study on bending behavior of FRP sandwich beam with 2nd reinforced by double-lap-joint (Double-lap-joint 로 2차 보강 접착을 한 FRP Sandwich Beam의 굽힘 거동 특성에 관한 연구)

  • Son, Choong-Yul;Kim, Ik-Tae;Roh, Min-Shik;Kim, Sung-Jun;Kim, Sang-Ho
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.05a
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    • pp.185-190
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    • 2002
  • It has made a special study of bending behavior of F.R.P sandwich beams with bonded 2nd-reinforced plies. Specimens were made of Chopped Mat 300-450, Roving Clothes 570 and the mixture weight ratio of Resin versus hardener was 55:45 for bending tests. it was fabricated by hand lay-up method, hardened for 24 hours in nature, cut specimens according to ASTM standard C393-94 Knowing exact behavior of bonded area's stress and strain depends upon various bonded F.R.P length on which covered lap joint. We also considered shear stress in adhered area and have done computational estimation by ANSYS as well. This study reveals that the length of plies covered lap joint are longer, Failure stresses are remarkably larger.

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Effect of Rice Straw Steaming Time and Mixing Ratio between Acacia mangium Willd Wood and Steamed Rice Straw on the Properties of the Mixed Particleboard

  • Tran, Van Chu;Le, Xuan Phuong
    • Journal of Forest and Environmental Science
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    • v.31 no.2
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    • pp.119-125
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    • 2015
  • This study examined the effects of rice straw steaming time and mixing ratio between rice straw and wood particle on the properties of mixed particle board from Acacia mangium Willd wood and rice straw. Rice straw and Acacia mangium Willd wood were collected in Hanoi, Vietnam. The particle board was three-layer particle board with the structural ratio of 1:3:1. The thickness, density and board size of the particle board were 18 mm, $0.7g/cm^3$, and $800{\times}800{\times}18$ (mm, including trimming), respectively. A resin mixture between commercial Urea-formaldehyde (U-F) adhesive and methylene diphenyl isocyanate (MDI) adhesive was used with a dosage of 12% for the core layer and 14% for the surface layer. In this experimental design, the steaming time for rice straw was 15, 30, 45, 60, and 75 minutes at $100^{\circ}C$. The rice straw-wood mixing ratio was 10, 20, 30, 40, and 50%. The results showed that both mixing ratio and steaming time affect the properties of the particleboard, but the mixing ratio has a stronger impact. A higher mixing ratio and a longer steaming time resulted in a better quality of particleboard. The optimal steaming time for rice straw was 46.12 minutes with the straw-wood mixing ratio of 29.85% with the following characteristics of the particle board: the modulus of rupture (MOR) of 14.64 MPa, internal bond strength (IB) of 0.382 MPa, thickness swelling (TS) of 8.83%, and board density of $0.7-0.7g/cm^3$.

A Study of Fabrication and Estimation Passive Matrix Display Using Electronic Bead (전자비드를 이용한 패시브 매트릭스 디스플레이 제작 및 평가에 관한 연구)

  • Oh, Yoo-Mi;Park, Sun-Woo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.3
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    • pp.224-228
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    • 2012
  • We have developed new materials that lead to methyl meth acrylate monomer and styrene monomer to using polymerization method. The materials have a powder form and show liquid behavior. We call the "Electronic Bead". An our experiment, a positive-charged particle has $TiO_2$, polymer and CCA(-), while a negative-charged particle consists of carbon black, polymer and CCA(+). The charged particles have electrical characteristic of white -10 uC/g and black 10 uC/g, respectively. Also, these particles have good fluidity by additive of nano-sized silica. Using these materials, we demonstrated prototype displays that have $320{\times}320$ array of pixels and 6-in-diagonal viewable image size, driven by passive-matrix addressing. The reflectivity shows about 30% even though our experiment is at the beginning point. Also, the panel has contrast ratio 6:1. We think there are many chances to improve reflectivity through modifying components of particle resin, mixture ratio of each particle, panel structure and so on.

Recovery of Calcium Phosphate from Sewage Sludge Ash (하수슬러지 소각재로부터 Ca-P 형태의 인 회수)

  • Jung, Jinmo;Yoon, Seok-Pyo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.1
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    • pp.29-37
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    • 2018
  • In this study, optimum extraction conditions for phosphorus recovery from sewage sludge ash(SSA) were investigated. For this purpose, an experiment was conducted to determine optimal recovery conditions for Ca-P type phosphorus by using calcium component in the recycled aggregate residue. The phosphorus content of sewage sludge ash was confirmed to be 5.0 %. When $H_2SO_4$ was used as an extract, concentration of 1 N $H_2SO_4$, L/S ratio of 10, and extraction time of 30 min were found to be the optimal extraction conditions. Phosphorus was extracted by using optimal extraction conditions, and then the heavy metals eluted with phosphorus were removed using 1~20 g of cation exchange resin. In 20 g of cation exchange resin, Fe 71.3%, Cu 82.4%, Zn 79.9%, and Cr 15% were removed. After that, the mixing ratio of the calcium extract obtained from the recycled aggregate residue (RAR) was changed to 1:1, 1:5, 1:10. The pH of the SSA to RAR mixture was adjusted to 2, 4, 8 and 12 by the addition of 5 N NaOH to the mixture of 1:5, and the phosphorus was recovered as Ca-P type precipitate. The optimum pH was 8. When recycled aggregate residues were used, the weight of calcium phosphate increased, but the amount of wastewater generated also increased. Therefore, it was concluded that the use of recycled aggregate residue was not economically feasible.