• 제목/요약/키워드: Residual metals

Search Result 290, Processing Time 0.024 seconds

Safety investigation of the moisturizing medium prepared using the Chinese oak mushroom (Lentinula edodes) based on the presence of residual pesticides, heavy metals, and radioactive materials (중국산 표고(Lentinula edodes) 보습배지의 잔류농약, 중금속 및 방사능 안전성 분석)

  • Jang, Eun-Kyoung;Jeong, Sang-Wook;Jang, Hye-Mi;Ban, Seung-Eon
    • Journal of Mushroom
    • /
    • v.20 no.1
    • /
    • pp.22-28
    • /
    • 2022
  • In order to provide basic data for preparing management standards and to verify the safety of the Chinese oak mushroom-derived moisturizing medium-which is synthesized and imported in large quantities-the presence of 321 residual pesticides, 7 heavy metals, and 3 radioactive materials was analyzed in the moisturizer samples. Examination of residual pesticides in seven moisturizing medium samples prepared using the Chinese oak mushroom and three domestic sawdust samples used for mushroom culture revealed the presence of cypermethrin and iprodione in three moisturizer samples, but the contents of these pesticides were below the standard limits. Zn was detected in ten samples, Cu was detected in nine samples, and Ni was detected in four samples, but their contents were below the standard limits. Pb, Cd, Cr, and Hg were not detected in any sample. No radioactive materials were detected in the samples. In addition, fruiting bodies of the oak mushroom were observed in each medium. Examination did not reveal the presence of any residual pesticides or harmful compounds. In this study, the use of the moisturizing medium prepared using the Chinese oak mushroom was found to be safe. As residual pesticides, heavy metals, and radioactivity-even in trace amounts-remain concentrated in the human body, continuous verification of the safety of hazardous substances and pollutants during the systematic cultivation and management of these mushrooms is required.

Residual Metal Evolution with Pattern Density in Cobalt Nickel Composite Silicide Process (코발트 니켈 복합 실리사이드 공정에서 하부 형상에 따른 잔류 금속의 형상 변화)

  • Song, Oh-Sung;Kim, Sang-Yeop
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.6 no.3
    • /
    • pp.273-277
    • /
    • 2005
  • We prepared $0.25\~l.5um$ poly silicon gate array test group with $SiO_2$ spacers in order to employ NiCo composite salicide process from 15nm Ni/15nm Co/poly structure. We investigate the residual metal shape evolution by varying the rapid thermal silicide anneal temperature from $700^{\circ}C\;to\;1100^{\circ}C$. We observed the residual metals agglomerated into maze type and line type on $SiO_2$ field and silicide gate, respectively as temperature increased. We propose that lower silicide temperature would be favorable in newly proposed NiCo salicide in order to lessen the agglomeration causing the leakage and scum formation.

  • PDF

A Round-Robin Analysis of Temperature and Residual Stresses in Dissimilar Metal Weld (이종금속용접부 온도 및 잔류응력의 라운드로빈 해석)

  • Song, Min-Sup;Kang, Sun-Ye;Park, June-Soo;Sohn, Gap-Heon
    • Proceedings of the KSME Conference
    • /
    • 2008.11a
    • /
    • pp.85-87
    • /
    • 2008
  • DMWs are common feature of the PWR in the welded connections between carbon steel and stainless steel piping. The nickel-based weld metal, Alloy 82/182, is used for welding the dissimilar metals and is known to be susceptible to PWSCC. A round-robin program has been implemented to benchmark the numerical simulation of the transient temperature and weld residual stresses in the DMWs. To solve the round-robin problem related to Pressurizer Safety & Relief nozzle, the thermal elasto-plastic analysis is performed in the DMW by using the FEM. The welding includes both the DMW of the nozzle to safe-end and the SMW of the safe-end and piping. Major results of the analyses are discussed: The axial and circumferential residual stresses are found to be -88MPa(225MPa) and -38MPa(293MPa) on the inner surface of the DMW; where the values in parenthesis are the residual stresses after the DMW. Thermo-mechanical interaction by the SMW has a significant effect on the residual stress fields in the DMW.

  • PDF

Concentration and Geochemical Phases of Heavy Metals in Marine Sediments in the Vicinity of the Coal-fired Power Plant of Korea (석탄화력발전소 주변해역 퇴적물 내의 중금속원소의 함량과 지화학적 존재형태)

  • Lee, Doo-Ho;Jeong, Yeon-Tae
    • Journal of Environmental Impact Assessment
    • /
    • v.9 no.4
    • /
    • pp.301-314
    • /
    • 2000
  • Marine surface sediments in the vicinity of Samcheonpo coal-fired power plant were analyzed by a total analysis($HF+HNO_3+HClO_4$) and sequential extraction procedure for heavy metals in order to investigate the total concentrations and geochemical phases of heavy metals. The result showed that the concentrations of Cr, Cu, Fe and Zn were within ranges typical for coastal areas, which reflected the mineralogical composition of the sediments in the studied area. However, the distributions of Cd, Co, Mn, Ni and Pb were rather different from the former, indicating that these heavy metals had a different origin, or that they were affected by a different geochemical mechanism. Chemical partitioning of heavy metals using sequential extraction procedure revealed that Cu, Fe, Pb, Zn were significantly bound to the residual phases of the sediments, whereas carbonate phases contained considerable amounts of Mn. The significant association of Pb with the exchangeable fraction also indicated that Pb was more mobile and bioavailable than Cu, Fe, Mn, Zn.

  • PDF

휴ㆍ폐광산지역 폐재의 중금속 존재형태에 따른 오염순위 설정에 관한 연구.

  • 김휘중;양재의;김동진;박병길;전상호
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2002.09a
    • /
    • pp.75-80
    • /
    • 2002
  • Enormous volumes of mining wastes from the abandoned and closed mines are disposed without a proper treatment at Southeastern part of Kangwon Province. Erosion of these wastes contaminates soil, surface water, and sediments with heavy metals. Objectives of this research were to fractionate heavy metals in the mine waste and to assess the potential S. P. A. G.(Soil Pollution Assesment Guidance) of each metal fraction. Mine wastes analyzed for physical and chemical properties. pH of wastes ranged from 3.3 to 8.0. Contents of total N and loss on ignition matter were in the ranges of 0.2~5.6%, and 0.8~15.3%, respectively. Heavy metals in the wastes were higher in the coal mines than those in the other mine wastes. Total concentrations of metals in the wastes were in the orders of Pb > Zn > Cu > Cd, exceeded the corrective action level of the Soil Environment Conservation Law and higher than the natural abundance levels reported from uncontaminated soils. Relative distribution of heavy metal fractions was residual > organic > reducible > carbonate > adsorbed, reversing the degree of metal bioavailability. Mobile fractions of metals were relatively small compared to the total concentrations. Soil Pollution Assesment Guidance(SPAG) values were ranged from 0.08 to 9.14 based on labile fraction of metal concentrations. SPAG values of labile concentration were lower than those of total concentration.

  • PDF

Evaluation of Electrokinetic Removal of Heavy Metals from Tailing Soils

  • Kim, Soon-Oh;Kim, Kyoung-Woong;Yun, Seong-Taek
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2002.09a
    • /
    • pp.40-43
    • /
    • 2002
  • Electrokinetic remediation was studied for the removal of toxic heavy metals from tailing soils. This study emphasized the dependency of removal efficiency upon heavy metal speciation, as demonstrated by different extraction methods (sequential extraction, total digestion, and 0.1 N HC1 extraction). The tailing soils examined showed different physicochemical characteristics, in view of initial pH, particle size distribution, and major mineral constituents, and contained high concentrations of target metal contaminants in various forms. The electrokinetic removal efficiency of heavy metals was significantly influenced by their partitioning prior to treatment, and by the pHs of the tailing soils. The mobile and weakly bound fractions of heavy metals, such as exchangeable fraction, were easily removed by electrokinetic treatment (more than 90% in removal efficiency), whereas immobile and strongly bound fractions, such as organically bound and residual fractions, were not effectively removed (less than 20% in removal efficiency).

  • PDF

Application of Zeolite with Different Cation Exchange Capacity for the Stabilization of Heavy Metals in Upland Soil (양이온교환용량이 다른 제올라이트 처리에 따른 밭토양 내 중금속 안정화 평가)

  • Gu, Bon-Wun;Kim, Mun-Ju;Park, Seong-Jik
    • Journal of The Korean Society of Agricultural Engineers
    • /
    • v.59 no.5
    • /
    • pp.41-49
    • /
    • 2017
  • This study was aimed to investigate the influence of cation exchange capacity (CEC) and application amounts of zeolite on the stabilization of heavy metals (As, Ni, Pb, and Zn) in upland soils. The upland soils were sampled from field near mines located in Gyeonggi Province. The CEC of zeolite was treated at three different levels, ie, low, medium, and high, while zeolite was amended with soils at the ratio of 0.1 % and 0.5 % as to soil weight. A sequential extraction was performed for the soil sampled at 1, 2 4, and 8 week after zeolite was added to the soil. The concentrations of Pb and Zn appeared to be high in the sampled soils. The mobility of heavy metals obtained from sequential experiments was as follows: Pb > Zn > Ni >As. Addition of zeolite to contaminated soils effectively reduced exchangeable and carbonate fractions but increased organic and residual fraction, indicating that zeolite is effective for immobilizing heavy metals in soils. The influence of incubation time on the metal stabilization was rather pronounced as compared to the application amount and CEC of zeolite.

Application of aqueous carbonated slags in the immobilization of heavy metals in field-contaminated soils

  • Choi, Jiyeon;Shin, Won Sik
    • Environmental Engineering Research
    • /
    • v.25 no.3
    • /
    • pp.356-365
    • /
    • 2020
  • The aqueous carbonation efficiencies of basic oxygen furnace (BOF) and ladle slags at various pressures, temperatures, and liquid-to-solid (L/S) ratios were investigated to determine optimum conditions. The maximum CO2 carbonated concentrations in slag (0.584 mmol/g for BOF slag and 1.038 mmol/g for ladle slag) was obtained at 10 bars, 40℃, and L/S = 5 mL/g-dry. The L/S ratio was the most critical parameter for carbonation. The effect of carbonated slag amendment on the immobilization of heavy metals in two field-contaminated soils was also investigated. The immobilization efficiencies evaluated by using the toxicity characteristic leaching procedure (TCLP) and the Standards, Measurements and Testing Programme (SM&T) were above 90% for both raw and carbonated slags for all soils. The TCLP-extractable heavy metals concentrations were below the criteria (5.0, 1.0 and 5.0 g/L for Pb, Cd, and Cr, respectively) after immobilizations with both slags except for Pb in soil B. The SM&T analysis showed the decrease in the exchangeable phase but the increase in residual phase after immobilization with raw and carbonated slags. The results of this study imply the promising potential of the carbonated slags on the immobilization of heavy metals in the field-contaminated soils.

Treatment Characteristics of Plating Wastewater Containing Freecyanide, Cyanide Complexes and Heavy Metals (II) - Effect of Aldehyde Compounds and Polysulfide - (도금폐수내 유리시안과 착염시안 및 중금속의 처리특성 (II) - aldehyde와 polysulfide첨가에 따른 영향 -)

  • Jung, Yeon-Hoon;Lee, Soo-Koo
    • Journal of Korean Society on Water Environment
    • /
    • v.26 no.4
    • /
    • pp.687-690
    • /
    • 2010
  • The objective of this study is to investigate the effect of aldehyde compounds and ploysulfide as accelerating agents on removal of heavy metals and CN in plating wastewater. As a results of the experiments, the removal efficiency of cyanide using the formaldehyde type of aldehydes was the highest at pH 9. Next types were sodium formaldehyde bisulfite addut> paraldehyde> paraformaldehyde. Also, optimum pH and dosage for treating the residual heavy metals by using polysulfide were pH 9 and 30 mg/L, respectively. The removal efficiencies of cyanide, chromium, zinc and copper were above 96.7% at optimum condition.

Effects of structure and morphology of anodized Al thin film on magnetic properties (알루미늄 양극산화 피막의 구조 및 형상이 자기적 특성에 미치는 영향)

  • 권용덕;박용수
    • Journal of the Korean institute of surface engineering
    • /
    • v.26 no.2
    • /
    • pp.45-54
    • /
    • 1993
  • In this study, magnetic properties of anodized Al film deposited with ferro-magnetic metals in the capacity of perpendicular magnetic recording media were measured and evaluated to find out the role of structure and morphology of the oxide films on magnetic characteristics. The object of this work was to present the conditions of magnetic thin film formation with more superior magnetic property. Anodizing was carried out under various conditions, and then the anodized film were electro-deposited with Co, Ni, Fe and their alloys. Coercive force and residual magnetization in perpendicular direction increased as the pore length of anodized film increased. It was attributed to the increase of the amount of depoisted metals and the ratio of length/diameter of pores. Morphology of anodized films in phosperic acid was not similar to that of sulfuric acid, and thin films in the former solution had perpendcular magnetic anisostropy because of large diameter, irregular length and distribution of the pores. It was found that magnetic properties of the thin films, which had doubled layer of two metals, were dominated by the metal electrodeposited on the surface of the anodized oxide films.

  • PDF