• Title/Summary/Keyword: Residual metals

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A Basic Study of Solidification for the Waste in the illegal(Open) Bumping Landfill (불량매립지 폐기물의 고형화를 위한 기초적 연구)

  • 이재영
    • Journal of Korea Soil Environment Society
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    • v.3 no.1
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    • pp.75-81
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    • 1998
  • In most of studies on solidification/stabilization with waste, small columns have been used to examinate adsorption or leachate. However, these experiments using small apparatus have been limited to apply with the field. In this study, considering an application to the field, a large Lysimeter(100cm$\times$100cm$\times$100cm) used for the simulation. Then, the open dumping waste was mixed directly with bentonite to simulate the stabilization of waste, environmental aspects and several basic tests. As a result, the concentration of heavy metals and contaminated substances changed with bentonite rate. Most of contaminated substances were decreased in leaching with increased mixing rate of bentonite. Especially, the concentration of CODcr removed 25~30%. Also, the residual soil in dumping waste produced approximately 80% of total volume by 40$\times$40mm screen.

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Risk Assessment of Micro and Emerging Contaminants in Domestic Effluent Environment: Targeting on 80 First-class substances assigned by Ministry of Environment (미량 및 신종유해물질의 국내 방류 환경에서의 위해성 평가: 환경부 지정 1순위 80종 대상으로)

  • Lee, Jai-Yeop;Park, Saerom;Kim, Ilho
    • Journal of Korean Society on Water Environment
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    • v.37 no.6
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    • pp.501-509
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    • 2021
  • In 2018, total 263 micro and emerging contaminants were selected as target substances by the Ministry of Environment, and 80 of them were first-class substance including endocrine disruptors, residual Pharmaceuticals and Personal Care Products (PPCPs), residual organic pollutants, pesticides and heavy metals. In this study, in order to evaluate the Hazard Quotient (HQ) of the 80 types in the domestic water environment the concentration of discharged effluent and nearby water environment reported by Korean institutes since 2010 was investigated. There were 45 substances reported to be detected, and Measurement Environment Concentration (MEC) were obtained by collectively converting them into water environment concentration. For biotoxicity, half maximal Effective Dose (EC50) to Daphnia magna, a water fleas species widely adopted in Material Safety Data Sheet (MSDS) was applied. As for the biotoxicity level, the Predicted No-Effect Concentration (PNEC) was obtained by applying the Assessment Factor (AF) and the HQ was derived by dividing it from the MEC. As a result of calculating the HQ, more than 1 substances were Cabamazepine, Mefenamic acid, Acetaminophen, Ibuprofen, Nonylphenol, Nickel, Erythromycin, Acetylslic acid, etc. Meanwhile, perfluorinated compounds were identified as hazardous substances in the water env ironment, with 5 out of 14 species included in the 20 ranks of first-class substance.

Analysis Method of X-Ray Diffraction Characteristic Values and Measured Strain for Steep Stress Gradient of Metal Material Surface Layer (금속재료 표면층의 급격한 응력구배에 대한 X-Ray회절 특성값과 측정된 변형률의 해석방법)

  • Chang-Suk Han;Chan-Woo Lee
    • Korean Journal of Materials Research
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    • v.33 no.2
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    • pp.54-62
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    • 2023
  • The most comprehensive and particularly reliable method for non-destructively measuring the residual stress of the surface layer of metals is the sin2ψ method. When X-rays were used the relationship of εφψ-sin2ψ measured on the surface layer of the processing metal did not show linearity when the sin2ψ method was used. In this case, since the effective penetration depth changes according to the changing direction of the incident X-ray, σφ becomes a sin2ψ function. Since σφ cannot be used as a constant, the relationship in εφψ-sin2ψ cannot be linear. Therefore, in this paper, the orthogonal function method according to Warren's diffraction theory and the basic profile of normal distribution were synthesized, and the X-ray diffraction profile was calculated and reviewed when there was a linear strain (stress) gradient on the surface. When there is a strain gradient, the X-ray diffraction profile becomes asymmetric, and as a result, the peak position, the position of half-maximum, and the centroid position show different values. The difference between the peak position and the centroid position appeared more clearly as the strain (stress) gradient became larger, and the basic profile width was smaller. The weighted average strain enables stress analysis when there is a strain (stress) gradient, based on the strain value corresponding to the centroid position of the diffracted X-rays. At the 1/5 Imax max height of X-ray diffraction, the position where the diffracted X-ray is divided into two by drawing a straight line parallel to the background, corresponds approximately to the centroid position.

Study on international accreditation for residue analysis laboratory (잔류물질분석의 국제공인시험기관 인정 관련 고찰)

  • Kim, MeeKyung;cho, Byung-Hoon;Kim, Dong-Gyu;Yun, Seon Jong;Lim, Chae-Mi;Park, Su-Jeong;Kim, Heuijin;Kim, Yeon Hee;Kim, Soo-Yeon;Yun, So Mi;Kwon, Jin-Wook;Son, Seong-Wan;Chung, Gab-Soo;Lee, Joo-Ho;Kang, Mun-Il
    • Korean Journal of Veterinary Research
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    • v.46 no.4
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    • pp.295-304
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    • 2006
  • Residual materials such as veterinary drugs, environmental contaminants, and pesticides are affecting food safety. High resolution techniques and quality controls are needed to analyze these materials from part per million to part per trillion quantities in food. In order to achieve quality results, standardized methods and techniques are required. Our laboratories were prepared to obtain a certificate of accreditation for ISO/IEC 17025 in the analytical criteria of animal drugs, dioxins, pesticides, and heavy metals. ISO together with IEC has built a strategic partnership with the World Trade Organization with the common goal of promoting a free and fair global trading system. ISO collaborates with the United Nations Organization and its specialized agencies and commissions, particularly those involved in the harmonization of regulations and public policies including the World Health Organization and CODEX Alimentarius for food safety measurement, management and traceability. Our goal was to have high quality analysts, proper analytical methods, good laboratory facilities, and safety systems within guidelines of ISO/IEC 17025. All staff members took requirement exams. We applied proficiency tests in the analysis of veterinary drugs (nitrofuran metabolites, sulfonamide and tetracyclines), dioxins, organophosphorus pesticides, and heavy metals (Cd, Pb, As) to the Food Analysis Performance Assessment Scheme (FAPAS) at Central Science Laboratory, Department for Environment Food and Rural Affairs (DEFRA), England. The results were very satisfactory. All documents were prepared, including system management, laboratory management, standard operational procedures for testing, reporting, and more. The criteria encompassed the requirements of ISO/IEC 17025:1999. Finally, the Korea Laboratory Accreditation Scheme (KOLAS) accredited our testing laboratories in accordance with the provisions of Article 23 of the National Standards Act. The accreditation will give us the benefit of becoming a regional reference laboratory in Asia.

Heavy Metal Contamination around the Abandoned Au-Ag and Base Metal Mine Sites in Korea (국내 전형적 금은 및 비(base)금속 폐광산지역의 중금속 오염특성)

  • Chon Hyo-Taek;Ahn Joo Sung;Jung Myung Chae
    • Economic and Environmental Geology
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    • v.38 no.2 s.171
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    • pp.101-111
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    • 2005
  • The objectives of this study we to assess the extent and degree of environmental contamination and to draw general conclusions on the fate of toxic elements derived from mining activities in Korea. 인t abandoned mines with four base-metal mines and four Au-Ag mines were selected and the results of environmental surveys in those areas were discussed. In the base-metal mining areas, the Sambo Pb-Zn-barite, the Shinyemi Pb-Zn-Fe, the Geodo Cu-Fe and the Shiheung Cu-Pb-Zn mine, significant levels of Cd, Cu, Pb and Zn were found in mine dump soils developed over mine waste materials, tailings and slag. Furthermore, agricultural soils, stream sediments and stream water near the mines were severely contaminated by the metals mainly due to the continuing dispersion downstream and downslope from the sites, which was controlled by the feature of geography, prevailing wind directions and the distance from the mine. In e Au-Ag mining areas, the Kubong, the Samkwang, the Keumwang and the Kilkok mines, elevated levels of As, Cd, Cu, Pb and Zn were found in tailings and mine dump soils. These levels may have caused increased concentrations of those elements in stream sediments and waters due to direct dis-charge downstream from tailings and mine dumps. In the Au-Ag mines, As would be the most characteristic contaminant in the nearby environment. Arsenic and heavy metals were found to be mainly associated with sulfide gangue minerals, and mobility of these metals would be enhanced by the effect of oxidation. According to sequential extraction of metals in soils, most heavy metals were identified as non-residual chemical forms, and those are very susceptible to the change of ambient conditions of a nearby environment. As application of pollution index (PI), giving data on multi-element contamination in soils, over 1.0 value of the PI was found in soils sampled at and around the mining areas.

Purification and Characterization of Cyclodextrin Glucanotransferase from Paenibacillus sp. JK-12

  • Kang, Yong;Kim, Sung-Koo;Jun, Hong-Ki
    • Preventive Nutrition and Food Science
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    • v.7 no.3
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    • pp.310-316
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    • 2002
  • Extracellular cyclodextrin glucanotransferase (CGTase) from Paenibacillus sp. JK-12 was purified through sev-eral purification steps consisting of ammonium sulfate precipitation and chromatographies on DEAE-sephadex A-50 and Mono QIM HR5/5. The purified CGTase exhibited a single band on SDS-PAGE and was estimated to be approximately 82 kDa. The isoelectric point of the enzyme was 7.2 as determined by isoelectric focusing. The CGTase from Paenibacillus sp. JK-12 had a transglucosylation activity at the C-2 position of L-ascorbic acid. The optimum pH and temperature for the CGTase activity were 8.0 and 5$0^{\circ}C$, respectively. The enzyme activity was stable from pH 6.0 to 9.() and at temperatures up to 55$^{\circ}C$ at pB 8.0, having 80% residual activity. The activity of the CGTase was strongly resistant to metals such as A $g^{+}$ and $Ba^{2+}$ but slightly inhibited by H $g^{+}$, N $i^{2+}$ and $Mg^{2+}$. The enzymeproduced $\alpha$ -cyclodextrin ($\alpha$-CD) and $\beta$-CD as the main products from starch, but not ${\gamma}$-CD.X>-CD.

A Study on the Actual Condition of Microplastic Contamination in Mackerel

  • Kwon, Woo-Taeg;Kim, Kui-Sung;Lee, Woo-Sik;Kwon, Lee-Seung;Rha, Young-Ah
    • Culinary science and hospitality research
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    • v.24 no.2
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    • pp.119-127
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    • 2018
  • The purpose of this study is to investigate the contamination level of micro plastics in Korean mackerel and to investigate the detection method of micro plastics in fish. This study analyzed the detection and composition of micro plastics using natural mackerel and wild mackerel. 30% hydrogen peroxide and surfactant were added to GF/C filter paper in order to detect micro plastics in the sea. If micro plastics are exposed to the ocean for a long time, accumulation of heavy metals in the water will make pollutant bioaccumulation more serious. Microscopic consequences The risk to human health of plastics has already been studied by many researchers and the risks to human health already caused by marine microorganisms and zooplankton are becoming clear. The conclusion of this study is that there is a difference between the length and height of the mackerel when it is cooked from the standpoint of food in terms of practical implications. The conclusion of this study is that the probability of micro-plastic-contaminated mackerel to reach and be consumed by end-consumers is low in academic implications. Residual contaminants adsorbed on micro plastics are absorbed by digestive organs and cause disruption, and further research on micro plastics is needed in the future.

Analysis of Trace Metal in Agricultural Products (농산물 중의 미량금속함량 분석)

  • 박정숙;나환식
    • The Korean Journal of Food And Nutrition
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    • v.13 no.6
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    • pp.595-601
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    • 2000
  • The seven trace metals contents of agricultural products in Kwang-ju were investigated to provide the basic data for its residual limits. Ten kinds of agricultural products (onion, welsh onion, garlic, lettuce, cabbage, pepper, spinach, radish, pear, peach) collected within from Kwang-ju in 1999 were analyzed by Mercury Analyzer for mercury. Inductively Coupled Plasma spectrometer and Atomic Absorption spectrophotometer equipped with Vapor Generation Accessory for Cu, Cd, Mn, Pb, Zn and As. Hg contents were not detected in all samples and As content were detected N.D. ∼0.005 ppm. Cd and Pb contents were detected N.D ∼0.088 ppm and N.D.∼0.096 ppm, respectively, Cu, Mn and Zn contents were 0.109∼1.072 ppm. 0.829∼6.195 ppd and 0.731∼6.176 ppm, respectively. The trace metal concentrations of the agricultural products in Kwang-ju called clean area were within the background level which growth is facilitated.

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Combustion Generated Fine Particles, Trace Metal Speciation, and Health Effects

  • Linak, William P.
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.195-195
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    • 2003
  • Combustion generated fine particles, defined as those with aerodynamic diameters less than 2.5 m, have come under increased regulatory scrutiny because of suspected links to adverse human health effects. Transition metals are of particular interest due to the results of a number of studies that have shown cardiopulmonary damage associated with exposure to these elements and their presence in coal, residual fuel oils, sewage sludge, and other combusted fuels and wastes. This lecture will review results from multi-di sciplinary studies being conducted at EPA and elsewhere examining the physical, chemical, and toxicological characteristics of combustion generated particles. The research describes how collaborative work between combustion engineers and health scientists can provide insight on how combustion processes affect particle properties and subsequent health effects as measured by a combination of in-vitro and in-vivo studies using a variety of animal models. The focus of this lecture is on the interdisciplinary approach required to address the problem. Difficulties are discussed. Engineering aspects involved in this approach are described in detail. Physical and chemical characterizations are performed using a variety of analytical approaches including new techniques of x-ray absorption fine structure (XAFS) spectroscopy and x-ray absorption near-edge structure (XANES) deconvolution of these spectra to gather metal speciation information.

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Fuzzy Logic Controller Design By Means Of Characteristic Design Parameters in a LASER Surface Hardening Process (단순화된 설계인자에 의한 레이저표면경화공정의 퍼지제어기 설계)

  • 박영준;김재훈;조형석
    • 제어로봇시스템학회:학술대회논문집
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    • 2000.10a
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    • pp.292-292
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    • 2000
  • Since high-power CO$_2$ Laser can be make a high densed energy to Local processing area, manufacturing processes using the laser can be processed for very Localized areas at a very fast rate with minimal or no distortion. Accordingly, the laser has been widely used in the fields of thermal manufacturing processes such as welding, fusion cutting, grooving, and heat treatment of metals. In particular, interest in the laser heat treatment process has grown tremendously in the past few years. In this process, maintaining the uniform hardening depth is important problem to obtain good quality products and to reduce heat induced distortion and residual stress. For achieving this objective, we introduced a new design technique of a fuzzy logic controller that greatly simplified the design procedure by defining several simplified design parameters. In the design procedure, the major design parameters of the controller are characterized by identifying several common aspects. From a series of simulation results, we found that the proposed design technique can be effectively used to design of a fuzzy logic controller for the LASER surface hardening process.

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