• Bulletin of the Korean Chemical Society
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• v.27 no.9
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• pp.1341-1345
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• 2006

An electrostatic interaction is responsible for the attachment of gold seeds of 1-3 nm onto APTMS (3-aminopropyl trimethoxysilane)-coated silica cores in the formation of gold clusters. A surface plasmon resonance and morphology of gold clusters were significantly affected by the pH of gold colloids prepared by THPC reducing agent. Gold colloids of alkaline pH induced the heterogeneous deposition of gold seeds onto the silica nanoparticles, probably due to the continuous reduction of residual gold ions during the attachment process. Gold colloids of acidic pH induced the monodisperse deposition of gold seeds, consequently leading to the formation of smooth gold layer on the silica nanoparticles surface. The gold nanoshells (core radius = 80 nm) prepared by gold colloids of pH 3.1 exhibited the more red-shift and relatively stronger intensity of plasmon absorption bands, compared with gold nanoshells prepared by alkaline gold colloids of pH 9.7.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.10b
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• pp.159-160
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• 2002

To investigate the humidity effect on tribological behaviors of Si-DLC/DLC multi-layers, the samples were prepared using a system consisted of an ion-gun for deposition DLC films and a balanced magnetron sputter for introducing silicon atoms to Si-DLC films. The Si-DLC/DLC multi-layers were composed of pure DLC films and Si-incorporated DLC films alternatively and had different bilayer numbers. Hardness and residual stress were drastically decreased through the formation of Si-DLC/DLC multi-layers compared to those of the pure and Si-incorporated DLC films. Wear results obtained under the various humidity conditions (<10%, $40{\sim}50%$, and >85%) showed that the pure DLC film was largely depended on the humidity while the Si-DLC and the Si-DLC/DLC multi-layers were little affected by the environmental humidity. Although friction coefficients of all samples were increased with the relative humidity, the multi-layer films showed relatively lower friction coefficients that those of the single films.

• Korean Journal of Materials Research
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• v.8 no.6
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• pp.538-544
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• 1998

The spallation of a thermal barrier coating layer depends on the formation of brittle spinels. thermal expansion mismatch between ceramic and metal. the phase transformation of a ceramic layer and residual stress of coating layer. In this work. the formation mechanism of oxide scale formed by oxidation treatment at 90$0^{\circ}C$ was investigated in order to verify oxidation behavior at the interface between E-beam coated $Zr0_2$-7wt.% $Y_20_3$ and plasma sprayed CoNiCrAIY. Some elements distributed in the bond coating layer were selectively oxidized after oxidation. At the initial time of oxidation. AI-depletion zone and $\alpha$-$Al_O_3$,O, were formed at the bond coating layer by the AI-outward diffusion. After layer grew until critical thickness. spinels. $Cr_20$, and $C0_2CrO_4$ by outward diffusion of Co. Cr, Ni were formed. It was found that the formation of spinels may be related to the spallation of $Zr0_2$-7wt.% $Y_20_3$ during isothermal oxidation.

• Advances in concrete construction
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• v.3 no.4
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• pp.283-293
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• 2015

This paper presents the effects of elevated temperatures of $400^{\circ}C$ and $800^{\circ}C$ on the residual compressive strength and failure behaviour of fibre reinforced concretes and comparison is made with that of unreinforced control concrete. Two types of short fibres are used in this study e.g., steel and basalt fibres. The results show that the residual compressive strength capacity of steel fibre reinforced concrete is higher than unreinforced concrete at both elevated temperatures. The basalt fibre reinforced concrete, on the other hand, showed lower strength retention capacity than the control unreinforced concrete. However, the use of hybrid steel-basalt fibre reinforcement recovered the deficiency of basalt fibre reinforced concrete, but still slightly lower than the control and steel fibres reinforced concretes. The use of fibres reduces the spalling and explosive failure of steel, basalt and hybrid steel-basalt fibres reinforced concretes oppose to spalling in deeper regions of ordinary control concrete after exposure to above elevated temperatures. Microscopic observation of steel and basalt fibres surfaces after exposure to above elevated temperatures shows peeling of thin layer from steel surface at $800^{\circ}C$, whereas in the case of basalt fibre formation of Plagioclase mineral crystals on the surface are observed at elevated temperatures.

• Corrosion Science and Technology
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• v.11 no.1
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• pp.9-14
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• 2012

The formation of the Fe-Al inhibition layer in hot-dip galvanizing is a confusing issue for a long time. This study presents a characterization result on the inhibition layer formed on C-Mn-Cr and C-Mn-Si dual-phase steels after a short time galvanizing. The samples were annealed at $800^{\circ}C$ for 60 s in $N_{2}$-10% $H_{2}$ atmosphere with a dew point of $-30^{\circ}C$, and were then galvanized in a bath containing 0.2 %Al. X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) was employed for characterization. The TEM electron diffraction shows that only $Fe_{2}Al_{5}$ intermetallic phase was formed. No orientation relationship between the $Fe_{2}Al_{5}$ phase and the steel substrate could be identified. Two peaks of Al 2p photoelectrons, one from metallic aluminum and the other from $Al^{3+}$ ions, were detected in the inhibition layer, indicating that the layer is in fact a mixture of $Fe_{2}Al_{5}$ and $Al_{2}O_{3}$. TEM/EDS analysis verifies the existence of $Al_{2}O_{3}$ in the boundaries of $Fe_{2}Al_{5}$ grains. The nucleation of $Fe_{2}Al_{5}$ and the reduction of the surface oxide probably proceeded concurrently on galvanizing, and the residual oxides prohibited the heteroepitaxial growth of $Fe_{2}Al_{5}$.

• Korean Journal of Soil Science and Fertilizer
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• v.9 no.2
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• pp.93-98
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• 1976

The present paper is a part of a study aimed at gaining information on the origin, mode of deposition, and characteristics of volcanic soils in Jeju. Volcanic activity of Jeju island has extremely influenced on the formation of various soils. Polysequum phenomenon of soils is one of outstanding soil genesis in Jeju. The typical polysequum soils was collected and analyzed by morphological, physico-chemical, mineralogical and micromorphological approaches The results are as follows: 1. The soils consists of polysequa, A and B horizons from volcanic ashes, unconsolidated volcanic sand layer and B(I) horizons from residual basalts. 2. The lithological discontinuity is also very distinct; silt loam from volcanic ashes, sand (II) from volcanic sand and clayey (III) from basalts. 3. Volcanic sand layer seems to be influenced by lava flow. The properties of it are similar to volcanic ashes rather than beneath residuum in micromorphological aspects. In micromorphological, this layer is gradually changed into soils. 4. Dominant clay minerals are allophane in A and B horizons from volcanic ashes and kaoline, vermiculite and illite from residual basalts. 5. The soils are not developed. There is no formation of argillic horizon in subsurface layers.

• Journal of Ocean Engineering and Technology
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• v.25 no.6
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• pp.42-48
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• 2011

The present study makes three original contributions to nanoskinned Ti-6Al-4V materials. The nanoskins were fabricated on Ti-6Al-4V material using various surface treatments: deep rolling (DR), laser shot peening (LSP), and ultrasonic nanocrystal surface modification (UNSM). These surface treatments are newly developed techniques and are becoming more popular in industrial fields. A fatigue strength comparison at up to 106 cycles was conducted on these nanoskinned Ti-6Al-4V materials. Fatigue tests were carried out using MTS under axial loading tension-compression fatigue (R = -1, RT, 5 Hz, sinusoidal wave). The analysis of the crack initiation patterns in the nanoskinned Ti-6Al-4V materials found an interior originating crack pattern and surface originating crack type. Microscopic observation was mainly used to investigate the fatigue fractured sites. These surface modification techniques have been widely adopted, primarily because of the robust grade of their mechanical properties. These are mainly the result of the formation of a large-scale, deep, and useful compressive residual stress, the formation of nanocrystals by the severe plastic deformation (SPD) at the subsurface layer, and the increase in surface hardness.

• 한국초전도학회:학술대회논문집
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• v.9
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• pp.363-368
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• 1999

Y-5a-Cu-O superconductors were prepared by TSMG (Top-Seeded Melt Growth) process with multiseeding technique. By using several seeds at the same time, large samples could be fabricated in a short time with simple heat treatment. However, the samples fabricated by normal multiseeding technique show the rapid decrease of trapped magnetic field value across the grain boundaries because of the residual liquid layer. To remove the residual liquid layer, modified multiseeding was newly suggested. The individual grains were combined as single domain, and did not show deterioration of magnetic property at the boundary. The formation mechanism of a well-combined domain by multiseeding technique was discussed.

• Journal of Powder Materials
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• v.24 no.2
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• pp.87-95
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• 2017

Lithium silicate, a lithium-ion conducting ceramic, is coated on a layer-structured lithium nickel manganese oxide ($LiNi_{0.7}Mn_{0.3}O_2$). Residual lithium compounds ($Li_2CO_3$ and LiOH) on the surface of the cathode material and $SiO_2$ derived from tetraethylorthosilicate are used as lithium and silicon sources, respectively. Powder X-ray diffraction and scanning electron microscopy with energy-dispersive spectroscopy analyses show that lithium silicate is coated uniformly on the cathode particles. Charge and discharge tests of the samples show that the coating can enhance the rate capability and cycle life performance. The improvements are attributed to the reduced interfacial resistance originating from suppression of solid-electrolyte interface (SEI) formation and dissolution of Ni and Mn due to the coating. An X-ray photoelectron spectroscopy study of the cycled electrodes shows that nickel oxide and manganese oxide particles are formed on the surface of the electrode and that greater decomposition of the electrolyte occurs for the bare sample, which confirms the assumption that SEI formation and Ni and Mn dissolution can be reduced using the coating process.

• Journal of Ocean Engineering and Technology
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• v.15 no.4
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• pp.28-37
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• 2001

The water quality in Yongil Bay is getting worse due to the sewage and the waste water from the surrounding industrial complex. The study aims to simulate the current system that is necessary to build ecosystem model for the optium water quality control and clarify the correlation of current system characteristics with water quality in Yongil Bay. To clarify the characteristics of coastal water movement system and verify the applicability of the 3-D model, the current system was simulated using 3-D model baroclinic model which considers tidal current and density effects. As the results of numerical experiments, it is proved the 3-D model is the most applicable on appearing the current system of the stratificated Yongil Bay difference of density. Form the results of simulation considered tidal current only, it can be clarified that the water body flows in the inner bay through the bottom layer and flows out the outer bay through the surface layer in Yongil Bay. And the fresh water from the Hyongsan river and the thermal discharge form POSCO have a little effect on the current system in Yongil Bay, but the diffusion of heat and salt has an important effect upon the formation of the density stratification of the water quality distribution is closely related with the current structure characteristics as well as the tidal residual current system in Yongil Bay.