• Title/Summary/Keyword: Residual Al

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A Study on the Dielectric Characteristics and Microstructure of $Si_3N_4$ Metal-Insulator-Metal Capacitors ($Si_3N_4$를 이용한 금속-유전체-금속 구조 커패시터의 유전 특성 및 미세구조 연구)

  • 서동우;이승윤;강진영
    • Journal of the Korean Vacuum Society
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    • v.9 no.2
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    • pp.162-166
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    • 2000
  • High quality $Si_3N_4$ metal-insulator-metal (MIM) capacitors were realized by plasma enhanced chemical vapor deposition (PECVD). Titanium nitride (TiN) adapted as a diffusion barrier reduced the interfacial reaction between $Si_3N_4$ dielectric layer and aluminum metal electrode showing neither hillock nor observable precipitate along the interface. The capacitance and the current-voltage characteristics of the MIM capacitors showed that the minimum thickness of $Si_3N_4$ layer should be limited to 500 $\AA$ under the present process, below which most of the capacitors were electrically shorted resulting in the devastation of on-wafer yield. According to the transmission electron microscopy (TEM) on the cross-sectional microstructure of the capacitors, the dielectric breakdown was caused by slit-like voids formed at the interface between TiN and $Si_3N_4$ layers when the thickness of $Si_3N_4$ layer was less than 500 $\AA$. Based on the calculation of thermally-induced residual stress, the formation of voids was understood from the mechanistic point of view.

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Preliminary Study on the Cloud Condensation Nuclei (CCN) Activation of Soot Particles by a Laboratory-scale Model Experiments

  • Ma, Chang-Jin;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • v.8 no.4
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    • pp.175-183
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    • 2014
  • To visually and chemically verify the rainout of soot particles, a model experiment was carried out with the cylindrical chamber (0.2 m (D) and 4 m (H)) installing a cloud drop generator, a hydrotherometer, a particle counter, a drop collector, a diffusing drier, and an artificial soot particle distributer. The processes of the model experiment were as follows; generating artificial cloud droplets (major drop size : $12-14{\mu}m$) until supersaturation reach at 0.52%-nebulizing of soot particles (JIS Z 8901) with an average size of $0.5{\mu}m$-counting cloud condensation nuclei (CCN) particles and droplets by OPC and the fixation method (Ma et al., 2011; Carter and Hasegawa, 1975), respectively - collecting of individual cloud drops - observation of individual cloud drops by SEM - chemical identifying of residual particle in each individual droplet by SEM-EDX. After 10 minutes of the completion of soot particle inject, the number concentrations of PM of all sizes (> $0.3{\mu}m$) dramatically decreased. The time required to return to the initial conditions, i.e., the time needed to CCN activation for the fed soot particles was about 40 minutes for the PM sized from $0.3-2.0{\mu}m$. The EDX spectra of residual particles left at the center of individual droplet after evaporation suggest that the soot particles seeded into our experimental chamber obviously acted as CCN. The coexistence of soot and mineral particle in single droplet was probably due to the coalescence of droplets (i.e., two droplets embodying different particles (in here, soot and background mineral particles) were coalesced) or the particle capture by a droplet in our CCN chamber.

Ultimate Strength Analysis of Stiffened Shell Structures Considering Effects of Residual Stresses (잔류응력을 고려한 보강된 쉘 구조의 극한강도 해석)

  • 김문영;최명수;장승필
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.13 no.2
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    • pp.197-208
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    • 2000
  • Choi et al./sup 1)/ presented the total Lagrangian formulation based upon the degenerated shell element. Geometrically correct formulation is developed by updating the direction of normal vectors and taking into account the second order rotation terms in the incremental displacement field. Assumed strain concept is adopted in order to overcome the shear locking phenomena and to eliminate the spurious zero energy mode. In this paper, for the ultimate strength analysis of stiffened shell structures considering effects of residual stresses, the return mapping algorithm based on the consistent elasto-plastic tangent modulus is applied to anisotropic shell structures. In addition, the load/displacement incremental scheme is adopted for non-linear F.E. analysis. Based on such methodology, the computer program is developed and numerical examples to demonstrate the accuracy and the effectiveness of the proposed shell element are presented and compared with the results in literatures.

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Improvement of Water Treatment Efficiency by pH Decreasing Agent (H2SO4) for Droughty Seasons (갈수기 정수장운영관리 사례 - 갈수기 pH저감제(황산)투입에 의한 정수처리효율 향상)

  • Ka, Gilhyun;Kim, Yunyung;Lee, Junho;Ahn, Chihwa;Han, Ihnsup;Min, Byungdae
    • Journal of Korean Society on Water Environment
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    • v.24 no.4
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    • pp.415-422
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    • 2008
  • Drinking water treatment is enhanced by coagulant dosages and chlorine injection because of pH increase in raw water in droughty seasons such as spring and fall. But water quality deterioration is occurred by increase in residual aluminium and disinfection by-products. Coagulation process can be used to control natural organic matter (NOM) during water treatment. The effect of coagulation process appeared to depend on the pH of water rather than coagulant dosages. In this study, for water treatment in high pH season $H_2SO_4$ was applied for pH adjustment at full scale. Before and after pH adjustment by $H_2SO_4$ injection, water quality of drinking water was evaluate. In the result of investigation of total organic carbon (TOC) removal in high pH season, TOC was removed approximately 30~40%, which showed decrease in water treatment efficiency. Also, it is increased both particle numbers and residual Al concentration in the water. After $H_2SO_4$ injection for adjustment to pH<7.5 in settled water, treated water turbidity decreased in 0.047 NTU from 0.059 NTU, and particle numbers of filtered water decreased in 20/mL from 90/mL. On the other side, TOC removal efficiency increased in approximately 10% after adjustment of pH. In the result of decrease in pH in raw water through more coagulants and prechlorine without $H_2SO_4$ injection, trihalomethanes (THMs) concentration increased in $16{\mu}g/L$ from $8{\mu}g/L$.

Explosive loading of multi storey RC buildings: Dynamic response and progressive collapse

  • Weerheijm, J.;Mediavilla, J.;van Doormaal, J.C.A.M.
    • Structural Engineering and Mechanics
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    • v.32 no.2
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    • pp.193-212
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    • 2009
  • The resilience of a city confronted with a terrorist bomb attack is the background of the paper. The resilience strongly depends on vital infrastructure and the physical protection of people. The protection buildings provide in case of an external explosion is one of the important elements in safety assessment. Besides the aspect of protection, buildings facilitate and enable many functions, e.g., offices, data storage, -handling and -transfer, energy supply, banks, shopping malls etc. When a building is damaged, the loss of functions is directly related to the location, amount of damage and the damage level. At TNO Defence, Security and Safety methods are developed to quantify the resilience of city infrastructure systems (Weerheijm et al. 2007b). In this framework, the dynamic response, damage levels and residual bearing capacity of multi-storey RC buildings is studied. The current paper addresses the aspects of dynamic response and progressive collapse, as well as the proposed method to relate the structural damage to a volume-damage parameter, which can be linked to the loss of functionality. After a general introduction to the research programme and progressive collapse, the study of the dynamic response and damage due to blast loading for a single RC element is described. Shock tube experiments on plates are used as a reference to study the possibilities of engineering methods and an explicit finite element code to quantify the response and residual bearing capacity. Next the dynamic response and progressive collapse of a multi storey RC building is studied numerically, using a number of models. Conclusions are drawn on the ability to predict initial blast damage and progressive collapse. Finally the link between the structural damage of a building and its loss of functionality is described, which is essential input for the envisaged method to quantify the resilience of city infrastructure.

Radioiodine Therapy For Differentiatd Thyroid Cancer (분화성 갑상선암의 방사성옥소 치료)

  • Hong, Sung-Woon
    • The Korean Journal of Nuclear Medicine
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    • v.34 no.4
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    • pp.265-275
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    • 2000
  • The thyroid gland is an interesting endocrine organ where a spectrum of tumors with different behavior arise. At one end of spectrum there is differentiated thyroid carcinoma (DTC) with excellent prognosis, whereas at the other end of the spectrum is anaplastic thyroid cancer which has universally poor outcome. Radioiodine (I-131) therapy has been in use for the treatment of thyroid diseases since 1946. It was introduced by Seidlin et al. 1) Although the use of I-131 has been vouge for a long time, its use in therapy for well differentiated thyroid cancer is still controversial 2). This is because, thyroid cancers (TC) are generally slow growing tumors, with low mortality and normal spans of survival. To record recurrence and mortality, long term follow up studies over a period of two to three decades are needed to establish definite conclusions on the acceptable mode of treatment The incidence of the disease being very low a large number of cases needed to establish a meaningful statistical data is lacking as most published reports feat with small series. Here again in the problem encountered are the differing protocols for treatment with I-131, the indications for treatment which may include or exclude ablation of residual thyroid tissue, cervical nodal and distal metastases. The dosage of I-131 used for ablation of residual thyroid tissue and metastatic disease also vary. The most reliable conclusion regarding I-131 treatment are obtained from studies reported on a large series of patients followed over a period of 2 decades or more from a single institute with a more or less unchanged protocol of management.

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Tailoring the Dielectric and Mechanical Properties of Si3N4 Ceramics (질화규소 세라믹의 유전 및 기계적 특성 제어에 관한 연구)

  • Lee, Seung Jun;Yong, Seok-Min;Park, Jin-Woo;Choi, Jaeho;Baek, Seungsu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.21 no.6
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    • pp.760-766
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    • 2018
  • The present study investigates the effect of PMMA and BN content on microstructure, mechanical and dielectric properties of silicon nitride($Si_3N_4$) ceramics in $Y_2O_3-Al_2O_3$ additive system. The total additive content was fixed at 8 wt.% and the amount of PMMA varies from 0 to 40 wt.% and BN varies from 0 to 36 wt.%, respectively. The crystalline phases of the samples were determined by X-ray diffraction analysis. All the sintered sample shows complete transformation of ${\alpha}$ to ${\beta}-Si_3N_4$ during the sintering process indicated that the phase transformation was unaffected by the PMMA or BN content. However, the microstructure shows that the residual porosity increased with increasing PMMA and BN content. In addition, the flexural strength and the dielectric constant decrease with addition of PMMA and BN due to the residual porosity. This article provides empirical study of design parameters for $Si_3N_4$-based radome materials.

Comparative Study on Various Ductile Fracture Models for Marine Structural Steel EH36

  • Park, Sung-Ju;Lee, Kangsu;Cerik, Burak Can;Choung, Joonmo
    • Journal of Ocean Engineering and Technology
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    • v.33 no.3
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    • pp.259-271
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    • 2019
  • It is important to obtain reasonable predictions of the extent of the damage during maritime accidents such as ship collisions and groundings. Many fracture models based on different mechanical backgrounds have been proposed and can be used to estimate the extent of damage involving ductile fracture. The goal of this study was to compare the damage extents provided by some selected fracture models. Instead of performing a new series of material constant calibration tests, the fracture test results for the ship building steel EH36 obtained by Park et al. (2019) were used which included specimens with different geometries such as central hole, pure shear, and notched tensile specimens. The test results were compared with seven ductile fracture surfaces: Johnson-Cook, Cockcroft-Latham-Oh, Bai-Wierzbicki, Modified Mohr-Coulomb, Lou-Huh, Maximum shear stress, and Hosford-Coulomb. The linear damage accumulation law was applied to consider the effect of the loading path on each fracture surface. The Swift-Voce combined constitutive model was used to accurately define the flow stress in a large strain region. The reliability of these simulations was verified by the good agreement between the axial tension force elongation relations captured from the tests and simulations without fracture assignment. The material constants corresponding to each fracture surface were calibrated using an optimization technique with the minimized object function of the residual sum of errors between the simulated and predicted stress triaxiality and load angle parameter values to fracture initiation. The reliabilities of the calibrated material constants of B-W, MMC, L-H, and HC were the best, whereas there was a high residual sum of errors in the case of the MMS, C-L-O, and J-C models. The most accurate fracture predictions for the fracture specimens were made by the B-W, MMC, L-H, and HC models.

An Efficient Game Theory-Based Power Control Algorithm for D2D Communication in 5G Networks

  • Saif, Abdu;Noordin, Kamarul Ariffin bin;Dimyati, Kaharudin;Shah, Nor Shahida Mohd;Al-Gumaei, Yousef Ali;Abdullah, Qazwan;Alezabi, Kamal Ali
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.15 no.7
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    • pp.2631-2649
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    • 2021
  • Device-to-Device (D2D) communication is one of the enabling technologies for 5G networks that support proximity-based service (ProSe) for wireless network communications. This paper proposes a power control algorithm based on the Nash equilibrium and game theory to eliminate the interference between the cellular user device and D2D links. This leadsto reliable connectivity with minimal power consumption in wireless communication. The power control in D2D is modeled as a non-cooperative game. Each device is allowed to independently select and transmit its power to maximize (or minimize) user utility. The aim is to guide user devices to converge with the Nash equilibrium by establishing connectivity with network resources. The proposed algorithm with pricing factors is used for power consumption and reduces overall interference of D2Ds communication. The proposed algorithm is evaluated in terms of the energy efficiency of the average power consumption, the number of D2D communication, and the number of iterations. Besides, the algorithm has a relatively fast convergence with the Nash Equilibrium rate. It guarantees that the user devices can achieve their required Quality of Service (QoS) by adjusting the residual cost coefficient and residual energy factor. Simulation results show that the power control shows a significant reduction in power consumption that has been achieved by approximately 20% compared with algorithms in [11].

The Mechanical Properties and Biocompatibility of Functionally Graded Coatings(FGC) of Hydroxyapatite(HA) and Metallic Powders - Functionally Gradient Coatings of Thermal Spray in Air- (Hydroxyapatite (HA)와 금속 분말 경사 코팅의 기계적 특성 및 생체 적합성 - 대기 열용사 경사코팅 -)

  • Kim, Eun-Hye;Kim, Yu-Chan;Han, Seung-hee;Yang, Seok-Jo;Park, Jin-Woo;Seok, Hyun-Kwang
    • Korean Journal of Metals and Materials
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    • v.47 no.1
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    • pp.13-20
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    • 2009
  • This work presents functionally graded coatings (FGC) of hydroxyapatite (HA) and metallic powders on Ti-6Al-4V implants using plasma spray coating method. HA has been the most frequently used coating material due to its excellent compatibility with human bones. However, because of the abrupt changes in thermomechanical properties between HA and the metallic implant across an interface, and residual stress induced on cooling from coating temperture to room temperature, debonding at the interface occurs in use sometimes. In this work, FGC of HA and Ti or Ti-alloy powders is made to mitigate the abrupt property changes at the interface and the effect of FGC on residual stress release is investigated by evaluating the mechanical bond strength between the implant and the HA coating layers. Thermal annealing is done after coating in order to crystallize the HA coating layer which tends to have amorphous structure during thermal spray coating. The effects of types and compositional ratio of metallic powders in FGC and annealing conditions on the bond strength are also evaluated by strength tests and the microstructure analysis of coating layers and interfaces. Finally, biocompatibility of the coating layers are tested under ISO 10993-5.