• Title/Summary/Keyword: Removal process

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Optimization of operating parameters to remove and recover crude oil from contaminated soil using subcritical water extraction process

  • Taki, Golam;Islam, Mohammad Nazrul;Park, Seong-Jae;Park, Jeong-Hun
    • Environmental Engineering Research
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    • v.23 no.2
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    • pp.175-180
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    • 2018
  • Box-Behnken Design (BBD) under response surface methodology (RSM) was implemented to optimization the operating parameters and assess the removal and recovery efficiencies of crude oil from contaminated soil using subcritical water extraction. The effects of temperature, extraction time and water flow rate were explored, and the results indicate that temperature has a great impact on crude oil removal and recovery. The correlation coefficients for oil removal ($R^2=0.74$) and recovery ($R^2=0.98$) suggest that the proposed quadratic model is useful. When setting the target removal and recovery (>99%), BBD-RSM determined the optimum condition to be a temperature of $250^{\circ}C$, extraction time of 120 min, and water flow rate of 1 mL/min. An experiment was carried out to confirm the results, with removal and recovery efficiencies of 99.69% and 87.33%, respectively. This result indicates that BBD is a suitable method to optimize the process variables for crude oil removal and recovery from contaminated soil.

Methane Production and Nitrogen Removal from Piggery Wastewater in the TPAD Coupled with BNR Process (질소제거공정과 결합한 2상 혐기성 소화공정에서 돈분폐수의 메탄생성 및 질소제거)

  • Park, Noh-Back;Park, Sang-Min;Choi, Woo-Young;Jun, Hang-Bae
    • Journal of Korean Society on Water Environment
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    • v.25 no.1
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    • pp.18-25
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    • 2009
  • Nitrogen removal and methane production from piggery wastewater were investigated in two-phase anaerobic digestion (TPAD) coupled with biological nitrogen removal (BNR) process at $35^{\circ}C$. Methane production rate was about $0.7L/L{\cdot}day$ at organic loading rate (OLR) of $1.2g{\cdot}TCOD/L{\cdot}day$ in methanogenic UASB. Conversion efficiency of the removed TCOD into methane in UASB was as high as 72% and overall TCOD removal efficiency in this system was over 97%. Ammonia nitrogen were stably removed in BNR system and overall efficiency were 98%. With recirculation of the nitrified final effluent to TPAD, nitrogen oxides were completely removed by anaerobic denitrification in the acidogenic reactor, which did not inhibit the acidogenic activities. Overall TN removal efficiency in the TPAD-BNR system was as high as 94%.

Preliminary Study on The Development of Phosphorous Removal Process by Converter and Furnace Slags (제강 전로 및 고로 슬래그를 이용한 인제거 기법에 관한 기초연구)

  • Lee, Seung-hwan;Jang, Jeong-hwa
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.2
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    • pp.137-144
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    • 2004
  • In this study, several series of experiments were conducted to investigate the phosphorus (P) removal process in slag-containing solution using furnace and converter slags. High amount of $OH^-$, $Ca^{2+}$ and alkalinity were discharged from the slags and hydroxyapatites [$Ca_5(PO_4)_3(OH)$] were kept accumulated on the surface of slag. P removal capacity of the slag decreased with the increase of slag dosage. The maximum capacity was found to be 11.25 mg/g at the converter slag. Converter slag adsorbed P more than furnace slag(about four times in average). An experimental study on the effect of pH shows that the percentage removal of P increased upto 30% at the pH range of 56 than that of above pH 8. Langmuir isotherm constants gave a better correlation than Freundlich ones. P removal amount in the presence of $NH^+_4$ was less compared to the one in the absence of $NH^+_4$. Maximum percentage reduction was 23%.

Ammonia-nitrogen Removal in Sea Water by Using Electrolysis (전기분해법에 의한 해수내의 암모니아성 질소 제거)

  • 이병헌;이제근;길대수;곽순열
    • Journal of Aquaculture
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    • v.10 no.4
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    • pp.435-438
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    • 1997
  • Biological ammonia removal system have been used conventionally for the seawater fish farming. But this process requires long hydraulic retention times and large area. Also it has a trouble of NO3-N accumulation in the system. Therefore, this study was conducted to find out the feasibility of effective nitrogen removal efficiency in the sea water fish farming system by electolysis. As the result, electrolysis system showed a good ammonia and nitrate nitrogen removal and E. coli sterilization efficiencies. Because of the high salinities in the seawater for electron transfer, electrolysis is an effictive water treatment process for seawater fish farming. The relation among ammonia removal efficiency, hydraulic retention time (HRT) and electric wattage (watt) with 10 mm electrod distance isas follow ; log [$NH_4^$+-N(%)]=0.431log(HRT(sec)$\times$Watt)+0.88(r=0.950) And the relation between ammonia removal efficiency and residual chlorine concentration in the seawater is as follow; $$NH_4^+-N(%)=48\cdotlog[Residual\;chlorine(mg/\ell)+28(r=0.892)$$

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Performance Evaluation of Microchip Removal Device Rotating by Conveyor Belt with Neodymium Permanent Magnet (네오디뮴 영구자석을 이용한 컨베이어벨트 구동형 미세칩 포집장치의 성능 평가)

  • Choi, Sung-Yun;Wang, Jun-hyeong;Wang, Duck Hyun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.1
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    • pp.103-109
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    • 2021
  • Fine chips generated by machining have an impact on machine failure and quality of machined products, it is necessary to remove the chips, so the microchip collection and removal device by rotating conveyor belt with neodymium permanent magnets was developed. In this research, to solve the problem for reducing the existing microchips in the tank, a micro-chip removal device by rotating conveyor belt with neodymium permanent magnets developed. In the development of micro-chip removal device, 3D CATIA modeling was used, and the flow analysis and the electromagnetic force analysis were performed with COMSOL Multiphysics program. To evaluate the performance of the prototypes produced, design of experiments (DOE) is used to obtain the effect of neodymium conveyor movement speed on chip removal for the ANOVA analysis of recovered powders. An experiment was conducted to investigate the effect of the conveyor feed rate on the chip removal performance in detail. As a result of the experiment, it was confirmed that the slower the feeding speed of the fine chip removing device, the more efficient the chip removal.

Enhanced alizarin removal from aqueous solutions using zinc Oxide/Nickel Oxide nano-composite

  • Basma E. Jasim;Ali J. A. Al-Sarray;Rasha M. Dadoosh
    • Analytical Science and Technology
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    • v.37 no.1
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    • pp.39-46
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    • 2024
  • Alizarin dye, a persistent and hazardous contaminant in aquatic environments, presents a pressing environmental concern. In the quest for efficient removal methods, adsorption has emerged as a versatile and sustainable approach. This study focuses on the development and application of Zinc Oxide/Nickel Oxide (ZnO/NiO) nano-composites as adsorbents for alizarin dye removal. These semiconducting metal oxide nano-composites exhibit synergistic properties, offering enhanced adsorption capabilities. Key parameters affecting alizarin removal, such as contact time, adsorbent dosage, pH, and temperature, were systematically investigated. Notably, the ZnO/NiO nano-composite demonstrated superior performance, with a maximum alizarin removal percentage of 76.9 % at pH 6. The adsorption process followed a monolayer pattern, as suggested by the Langmuir model. The pseudo-second-order kinetics model provided a good fit to the experimental data. Thermodynamic analysis indicated that the process is endothermic and thermodynamically favorable. These findings underscore the potential of ZnO/NiO nano-composites as effective and sustainable adsorbents for alizarin dye removal, with promising applications in wastewater treatment and environmental remediation.

The Characteristics of the Treatment of Pollutants ($SO_2$, NOx) Using Surface Discharge Induced Plasma Chemical Process (SPCP를 이용한 오염물질 ($SO_2$, NOx) 처리 특성)

  • 봉춘근;부문자
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.4
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    • pp.333-342
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    • 1998
  • Plasma process has great possibilities to remove SOx, NOx simultaneously with high treatment efficiency and is expected to be suitable for small or middle plants. It was accomplished to evaluate SO2, NOx control possibility and achieve basic data to control pollutants by use of Surface Discharge Induced Plasma Chemical Process (SPCP) in this study. O3 generation characteristics by discharge of a plate was proportional to O2 concentration and power consumption and inversely proportional to temperature and humidity, In case of dry air, NOx was highly generated by N2 and O2 in air during the plasma discharge process but it was decreased considerably as H2O was added. SO2 removal efficiency was very high, and removal rate was 170,350 mEA at 30,50 watt respectively in flue gas which is usually contain HIO. NOx removal efficiency was about 57% at 40 watt power consumption with 7.5% humidity. It is estimated that H2O has an important role in reaction mechanism with pollutants according to plasma discharge.

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Impact of Current Density, Operating Time and pH of Textile Wastewater Treatment by Electrocoagulation Process

  • Hossain, Md. Milon;Mahmud, Md. Iqbal;Parvez, Md. Shohan;Cho, Haeng Muk
    • Environmental Engineering Research
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    • v.18 no.3
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    • pp.157-161
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    • 2013
  • Treatment of textile wastewater by the electrocoagulation (EC) process is being investigated by this experimental study. The objective of this experiment is to observe the efficiency of the EC process in removing chemical oxygen demand (COD) and turbidity. In this experiment an iron electrode is used in the EC process, and different working parameters such as pH, current density and operating time were studied in an attempt to achieve a higher removal capacity. The results show that the maximum COD removal occurred at neutral pH at operating time 30 min. COD and turbidity removal reaches at maximum, with optimum consumption of electrodes, between current density 85-95 $A/m^2$, and only trace amounts of metals were determined in the EC treated effluent.

The study of chemical treatment of pulp mill bleaching waste liquor using lime (석회를 이용한 펄프공장 폐액의 화학적 처리에 관한 연구)

  • 정병곤;이헌모;윤종호
    • Journal of environmental and Sanitary engineering
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    • v.12 no.2
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    • pp.23-28
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    • 1997
  • This study was conducted to know the possibility of reducing lime dosage by recycling sludge from bleaching wastewater lime coagulation settlement treatment at pulp mill process. In case of bleaching wastewater at the pulp mill process, when the lime dosage was increased, the removal efficiency of TSS(Total Suspended Solids) was increased, proportionally, but the organic removal efficiency was increased very slowly. It was concluded that sludge recycling at the lime coagulation settlement process was effective method to reduce the requirement of lime dosage. At the lime coagulation settlement process with sludge recycling, when the recycling number was increased, the organic removal efficiency was decreased, sharply. It was evaluated that the pH could be the basic standard for lime supplement by sludge recycling.

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Effect of Process Parameters of UV Enhanced Gas Phase Cleaning on the Removal of PMMA (Polymethylmethacrylate) from a Si Substrate

  • Kwon, Sung Ku;Kim, Do Hyun
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.4
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    • pp.204-207
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    • 2016
  • Experimental study of UV-irradiated O2/H2 gas phase cleaning for PMMA (Polymethylmethacrylate) removal is carried out in a load-locked reactor equipped with a UV lamp and PBN heater. UV enhanced O2/H2 gas phase cleaning removes polymethylmethacrylate (PMMA) better at lower process pressure with higher content of H2. O2 gas compete for UV (184.9 nm) absorption with PMMA producing O3, O(1D) and lower dissociation of PMMA. In our experimental conditions, etching reaction of PMMA at the substrate temperature between 75℃ and 125℃ had activation energy of about 5.86 kcal/mol indicating etching was controlled by surface reaction. Above the 180℃, PMMA removal was governed by a supply of reaction gas rather than by substrate temperature.