• Title/Summary/Keyword: Removal mechanisms

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Soil Column Experiment to Evaluate Removal of Nutrients in Stormwater Runoff by Soil of Riparian Protection Zone (토양칼럼을 이용한 초기우수 중 염양염류의 수변녹지 토양에서의 제거도 평가)

  • Yoon, Seok-Pyo;Choi, Ji-Yong
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.231-235
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    • 2004
  • To investigate removal effects of nutrients in stormwater runoff by soil of riparian protection zone, soil column experiment was conducted for 20 months. Artificial stormwater runoff containing phosphate and nitrate was applied on the surface of soil column twice a week, and phosphate and nitrate concentrations were measured from the leached water. Soil of riparian protection zone reduced the released amount of infiltrated water to the surrounding water. After infiltration of 1m depth of soil column, average removal rates of phosphate and nitrate were 97.7 % and 74.7 %, respectively. As main mechanisms of phosphate are adsorption to soil particle and utilization by plants, periodical replacement of soil and harvesting of plant at the end of growing season are required. For the removal of nutrients in stormwater runoff by the soil layer, soil of riparian protection zone has higher hydraulic conductivity to infiltrate stormwater. Sandy soil having hydraulic conductivity of about $1{\times}10^{-2}cm/s$ range might be appropriate for this purpose.

The Importance of Reaction Mechanisms in Interpreting the Arsenic Reactive Transport of FeS-coated Sand Column

  • Han, Young-Soo;Demond, Avery H.;Hayes, Kim F.
    • Journal of Soil and Groundwater Environment
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    • v.20 no.5
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    • pp.1-10
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    • 2015
  • FeS, as a natural reduced iron mineral, has been recognized to be a viable reactive material for As(III) sequestration in natural and engineered systems. In this study, FeS-coated sand packed columns were tested to evaluate the As(III) removal capacities under anaerobic conditions at pH 5, 7 and 9. The column obtained As(III) removal capacity was then compared with the capacity result obtained from batch reactors. In the comparison, two different approaches were used. The first approach was used the total As(III) removal capacity which method was proved to be useful for interpreting pH 5 system. The second approach was used to consider sorption non-linearity and proved to be useful for interpreting the pH 9. The results demonstrated that a mechanistic understanding of the different removal processes at different pH conditions is important to interpret the column experimental results. At pH 5, where the precipitation of arsenic sulfide plays the major role in the removal of arsenic, the column shows a greater removal efficiency than the batch system due to the continuous dissolution of sulfide and precipitation of arsenic sulfide. At pH 9, where adsorption mainly governs the arsenic removal, the sorption nonlinearity should be considered in the estimation of the column capacity. This study highlighted the importance of understanding reaction mechanism to predict column performance using batch-obtained experimental results.

Efficacy of Spinal Implant Removal after Thoracolumbar Junction Fusion

  • Kim, Seok-Won;Ju, Chang-Il;Kim, Chong-Gue;Lee, Seung-Myung;Shin, Ho
    • Journal of Korean Neurosurgical Society
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    • v.43 no.3
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    • pp.139-142
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    • 2008
  • Objective: The purpose of this study was to evaluate the efficacy of spinal implant removal and to determine the possible mechanisms of pain relief. Methods: Fourteen patient~with an average of 42 years (from 22 to 67 years) were retrospectively evaluated. All patients had posterior spinal instrumentation and fusion, who later developed recurrent back pain or persistent back pain despite a solid fusion mass. Patients' clinical charts, operative notes, and preoperative x-rays were evaluated. Relief of pain was evaluated by the Visual Analog Scale (VAS) pain change after implant removal. Clinical outcome using VAS and modified MacNab's criteria was assessed on before implant removal, 1 month after implant removal and at the last clinical follow-up. Radiological analysis of sagittal alignment was also assessed. Results: Average follow-up period was 18 months (from 12 to 25 months). There were 4 patients who had persistent back pain at the surgical site and 10 patients who had recurrent back pain. The median time after the first fusion operation and the recurrence of pain was 6.5 months (from 3 to 13 months). All patients except one had palpation pain at operative site. The mean blood loss was less than 100ml and there were no major complications. The mean pain score before screw removal and at final follow up was 6.4 and 2.9, respectively (p<0.005). Thirteen of the 14 patients were graded as excellent and good according to modified MacNab's criteria. Overall 5.9 degrees of sagittal correction loss was observed at final follow up, but was not statistically significant. Conclusion: For the patients with persistent or recurrent back pain after spinal instrumentation, removal of the spinal implant may be safe and an efficient procedure for carefully selected patients who have palpation pain and are unresponsive to conservative treatment.

Phytoremediation of Organophosphorus and Organochlorine Pesticides by Acorus gramineus

  • Chuluun, Buyan;Iamchaturapatr, Janjit;Rhee, Jae-Seong
    • Environmental Engineering Research
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    • v.14 no.4
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    • pp.226-236
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    • 2009
  • The performance of phytoremediation has proven effective in the removal of nutrients and metals from aqueous systems. However, little information is available regarding the behavior of pesticides and their removal pathways in aquatic environments involving plant-uptake. A detailed understanding of the kinetics of pesticide removal by plants and information on compound/plant partition coefficients can lead to an effective design of the phytoremediation process for anthropogenic pesticide reduction. It was determined that the reduction rates of four organophosphorus (OP) and two organochlorine (OC) pesticides (diazinon, fenitrothion, malathion, parathion, dieldrin, hexachlorobenzene [HCB]) could be simulated by first-order reaction kinetics. The magnitude of k was dependent on the pesticide species and found within the range of 0.409 - 0.580 $d^{-1}$. Analytical results obtained by mass balances suggested that differential chemical stability, including diversity of molecular structure, half-lives, and water solubility, would greatly influence the removal mechanisms and pathways of OPs and OCs in a phytoreactor (PR). In the case of OP pesticides, plant accumulation was an important pathway for the removal of fenitrothion and parathion from water, while pesticide sorption in suspended matter (SM) was an important pathway for removal of dieldrin and HCB. The magnitude of the pesticide migration factor (${\Large M}_p^{pesticide}$) is a good indication of determining the tendency of pesticide movement from below- to above-ground biomass. The uncertainties related to the different phenomena involved in the laboratory phyto-experiment are also discussed.

A Study on the Effect of Bioceramics as Biochemosorption Material in Sequencing Batch Reactor (연속회분식 반응조에서 생화학흡착제로서 바이오세라믹의 영향에 관한 연구)

  • Lee, Seunghwan;Islam, M.S.;Kang, Meea
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.3
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    • pp.367-375
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    • 2006
  • Sequencing Batch Reactor (SBR) is well adopted for community wastewater treatment for its simplicity, performance and various advantageous treatment options. SBR is now drawing attention for its process modification such as coupled with membrane bioreactor, reverse osmosis or applying different media to achieve high removal efficiency. This study focused on the improved efficiency of carbon, nitrogen and phosphorous removal by applying zeolite materials called bioceramics to the SBR. Two laboratory-scale SBR units were operated in the same operating conditions - one with bioceramics called Bioceramic SBR (BCSBR) and the other without bioceramics used as control. Routine monitoring of COD, TP, $NH_3-N$, $NO_3-N$ was performed throughout this study. COD removal was about 80% to 100% and phosphorous removal was about 60% in the process whereas $NH_3-N$ removal efficiency was found to be 99.9% in the BCSBR unit. Addition of bioceramics also improved sludge characteristics such as sludge dewaterability, specific gravity and particle size. BCSBR can withstand high ammonia shock loading leading to the better treatment capacity of high ammonia containing wastewater. The cause of improved removal efficiencies within the biological reactor could be attributed to the biochemosorption mechanisms of bioceramics. Absorption/adsorption or desorption capacity of bioceramics was tested through laboratory experiments.

Sensitivity Analyses for Maximum Heat Removal from Debris in the Lower Head

  • Kim, Yong-Hoon;Kune Y. Suh
    • Nuclear Engineering and Technology
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    • v.32 no.4
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    • pp.395-409
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    • 2000
  • Parametric studies were performed to assess the sensitivity in determining the maximum in-vessel heat removal capability from the core material relocated into the lower plenum of the reactor pressure vessel (RPV)during a core melt accident. A fraction of the sensible heat can be removed during the molten jet delivery from the core to the lower plenum, while the remaining sensible heat and the decay heat can be transported by rather complex mechanisms of the counter-current flow limitation (CCFL) and the critical heat flux (CHF)through the irregular, hemispherical gap that may be formed between the freezing oxidic debris and the overheated metallic RPV wall. It is shown that under the pressurized condition of 10MPa with the sensible heat loss being 50% for the reactors considered in this study, i.e. TMI-2, KORI-2 like, YGN-3&4 like and KNGR like reactors, the heat removal through the gap cooling mechanism was capable of ensuring the RPV integrity as much as 30% to 40% of the total core mass was relocated to the lower plenum. The sensitivity analysis indicated that the cooling rate of debris coupled with the sensible heat loss was a significant factor The newly proposed heat removal capability map (HRCM) clearly displays the critical factors in estimating the maximum heat removal from the debris in the lower plenum. This map can be used as a first-principle engineering tool to assess the RPV thermal integrity during a core melt accident. The predictive model also provided ith a reasonable explanation for the non-failure of the test vessel in the LAVA experiments performed at the Korea Atomic Energy Research Institute (KAERI), which apparently indicated a cooling effect of water ingression through the debris-to-vessel gap and the intra-debris pores and crevices.

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A Study on the Die Set Design for Multi-Hole Extrusion Process Using Taguchi Method (다구찌 방법을 이용한 다발압출 금형설계에 관한 연구)

  • 조성진;이재원
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.11a
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    • pp.322-325
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    • 2000
  • In the previous report1), the grinding characteristics of quartz were investigated. In this paper, the grinding mechanisms of brittle materials including ceramics and quartz are modeled and a new parameter SDR(Surface roughness Direction Ratio) is proposed to characterize the grinding mechanisms of such materials. A set of experiments were performed to verify the effectiveness of the suggested parameter. The experimental results indicate that the plastic deformation is the dominant material removal mode at the grinding conditions which show the higher value of SDR. In the case of quartz, the material was removed by brittle fracture in a lower value of SDR and by plastic deformation in a higher value of it. SDR is not affected by wheel mesh size when brittle fracture occured. But in the plastic deformation case, SDR value increases with wheel mesh size.

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Mechanisms, Experimental Results, Empirical Correlations and Analytic Models of Beat Transfer in Containment Building Following a LOCA (냉각재 상실 사고시 격납 용기내에 있어서의 열전달에 관한 기구, 실험결과, 선험 관계식 및 해석적 모형들에 관한 고찰)

  • Jong Ho Choi;Soon Heung Chang
    • Nuclear Engineering and Technology
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    • v.15 no.2
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    • pp.123-134
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    • 1983
  • Estimates of the rate of heat removal from the containment atmosphere following a loss of colant accident (LOCA) are important to the prediction of containment peak pressure and temperature which are essential parameters in designing the containment building. An overall survey and discussion of mechanisms, experimental results, empirical correlations and analytical models that are relevant to the heat transfer inside the containment have been made. As a result of this review, the current state of the knowledge about tile containment heat transfer can be understood and it is known that more investigations are needed to avoid the misuse of various correlations.

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Development of a Mathematical Model for Simulating Removal Mechanisms of Heavy Metals using Biocarrier Beads (미생물 담체를 이용한 납 제거기작 모의를 위한 수학적 모델의 개발)

  • Seo, Hanna;Lee, Minhee;Wang, Sookyun
    • Journal of Soil and Groundwater Environment
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    • v.18 no.4
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    • pp.8-18
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    • 2013
  • Biocarrier beads with dead biomass, Bacillus drentensis, immobilized in polymer polysulfone were synthesized to remove heavy metals from wastewater. To identify the sorption mechanisms and theoretical nature of underlying processes, a series of batch experiments were carried out and a mathematical model was developed to quantify the biosorption of Pb(II) by the biocarrier beads. A series of mass balance equations for representing mass transfer of metal sorbents in biocarrier beads and surrounding solution were established. Major model parameters such as external mass transfer coefficient and maximum sorption capacity, etc. were determined from pseudo-first-order kinetic models and Langmuir isotherm model based on kinetic and equilibrium experimental measurements. The model simulation displays reasonable representations of experimental data and implied that the proposed model can be applied to quantitative analysis on biosorption mechanisms by porous granular beads. The simulation results also confirms that the biosorption of heavy metal by the biocarrier beads largely depended on surface adsorption.

Prevention and Solution of the Fracture of Nickel-Titanium Endodontic Instruments (니켈티타늄 전동파일 파절의 예방 및 처치)

  • Kim, Hyeon-Cheol
    • The Journal of the Korean dental association
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    • v.54 no.8
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    • pp.640-650
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    • 2016
  • Nickel-Titanium (NiTi) rotary instruments have brought a big step toward "efficient" practice of endodontic procedure. The rotary files help clinicians to reduce their working time and also increase the clinical success rate with minimal procedural errors. However, NiTi instruments still have a few drawbacks including unpredictable fatigue fracture. Clinicians may reduce the potential risk of instruments fracture by following some clinical guidelines for rotary instruments. In some clinical cases of instruments fracture, we may try to remove the instruments' fragments or bypass the fragment to reach the apical canal. In some limited cases, the fractured instruments' fragments would not jeopardize the clinical prognosis of root canal treatment. Nevertheless, it is impossible to be overemphasized that the prevention of file fracture is much easier than the removal of fracture fragment. Clinicians need to understand the fracture mechanisms and, in clinic, need to discard the used instruments timely.

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