• Title/Summary/Keyword: Relative dependence

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Acid-Sensitivity and Physical Properties of Polymethylmethacrylate and Polyurethane Films Containing Polymeric Styryl Dye

  • Cho, Jae-Whan;Lee, Sun-Hwa;So, Jung-Hyun;Jaung, Jae-Yun;Yoon, Kee-Jong
    • Fibers and Polymers
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    • v.5 no.3
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    • pp.239-244
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    • 2004
  • Solution-cast films of polymethylmethacrylate (PMMA) and polyurethane (PU) containing polymeric styryl dye up to 5 % by weight were prepared to investigate their acid-sensitivity and mechanical and thermal properties. Original red samples due to styryl dye turned out yellow very rapidly as they were exposed to acid vapor of hydrochloric acid or p-toluenesulfonic acid. According to UV/VIS spectroscopic measurements, characteristic peak intensities near 430 nm and 520 nm increased or decreased relatively with exposed amounts of acid, respectively. Both PMMA and PU samples showed uniform color distribution due to a good miscibility between polymer and dye which can be evidenced by measurements of glass transition temperature. No significant difference in acid-sensitivity was found between PU and PMMA except relative absorbance. However, dependence of their mechanical properties on dye content was somewhat different with PU or PMMA. In case of PMMA, modulus and breaking stress increased up to about 50 % with increasing dye content, whereas those of PU samples showed only slight increase. It was ascribed to whether the matrix polymer was in the glassy or rubbery state.

Electrical Properties of a Single ZnO Nanowire in a four-probe Configuration (단일 ZnO 나노선 4단자 소자의 전기적 특성)

  • Kim, Kang-hyun;Kang, Hae-yong;Yim, Chan-young;Jeon, Dae-young;Kim, Hye-young;Kim, Gyu-Tae;Lee, Jong-Soo;Kang, Woun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.12
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    • pp.1087-1091
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    • 2005
  • Four-probe device of single ZnO nanowire was fabricated by electron beam lithography. Electrical characterizations in a two-probe and a four-probe configuration with a back-gate were carried out to clarify the relative contribution of the contact and the intrinsic part in a ZnO nanowire. I-V characteristic in four-probe measurement showed an ohmic behavior with a high conductivity, 100 S/cm, which was better than those of two-probe measurement by 10 times. At the same values of the current between two-probe and four-probe, the net voltage applied inside the nanowire were extracted with calculated voltages at the contact. Four-probe current-gate voltage characteristics showed bigger tendencies than those of two-probe measurement at low temperatures, indicating the reduced gate dependence in two-Probe measurements by the existence of the contact resistance.

Humidity sensors using porous silicon layer with mesa structure (메사구조를 갖는 다공질 실리콘 습도 센서)

  • Jeon, Byung-Hyun;Yang, Kyu-Yull;Kim, Seong-Jeen
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.25-28
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    • 2000
  • A capacitance-type humidity sensors in which porous silicon layer is used as humidity-sensing material was developed. This sensors was fabricated monolithically to be compatible with the typical IC process technology except for the formation of porous silicon layer. As the sensors is made as a mesa structure, the correct measurement of capacitance is expected because it can remove the effect of the parasitic capacitance from the bottom layer and another junctions. To do this, the sensor was fabricated using process steps such as localized formation of porous silicon, oxidation of porous silicon layer and etching of oxidized porous silicon layer. From completed sensors, capacitance response was measured on the relative humidity of 25 to 95% at room temperature. As the result the measured capacitance showed the increase over 300% at the low frequency of 120Hz, and showed little dependence on the temperature between 10 to $40^{\circ}C$.

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Pyroelectric Properties of PZT(30/70) Thick film Prepared by Sol-Gel Method (Sol-Gel 법으로 제작된 PZT(30/70) 후막의 초전특성)

  • 송금석;장동훈;강성준;윤영섭
    • Proceedings of the IEEK Conference
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    • 2003.07b
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    • pp.1121-1124
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    • 2003
  • PZT(30/70) thick film was fabricated by using 1,3 propanediol-based sol-gel method. Prepared film of pyroelectric property was investigated by Dynamic method of modulation frequency dependence. Pyroelectric coefficient was obtained about 5.0$\times$10$^{-8}$ C/$\textrm{cm}^2$.K. The figure of merits for voltage responsivity and specific detectivity were 3.4$\times$10$^{-11}$ C.cm/J and 5.9$\times$10$^{-9}$ C.cm/J, respectively, because of relative high-dielectric constant and high-pyroelectric coefficient. Voltage responsivity was increased at low modulation frequency and it was decreased at high modulation frequency. Voltage responsivity was maximum 1.84 V/W at 10 Hz. As Johnson noise is dominant, Noise voltage was increased nearly proportional to f$^{-1}$ 2/. Noise equivalent power and specific detectivity were 2.83$\times$10$^{-7}$ W/Hz$^{1}$2/ and 3.13$\times$10$^{5}$ cm.Hz$^{1}$2//W the same frequency at 80 Hz, respectively.

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Cell Cycle Regulation and Induction of Apoptosis by β-carotene in U937 and HL-60 Leukemia Cells

  • Upadhyaya, K.R.;Radha, K.S.;Madhyastha, H.K.
    • BMB Reports
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    • v.40 no.6
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    • pp.1009-1015
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    • 2007
  • In this communication, we report the efficacy of $\beta$-carotene towards differentiation and apoptosis of leukemia cells. Dose ($20{\mu}M$) and time dependence (12 h) tests of $\beta$-carotene showed a higher magnitude of decrease (significance p < 0.05) in cell numbers and cell viability in HL-60 cells than U937 cells but not normal cell like Peripheral blood mononuclear cell (PBMC). Microscopical observation of $\beta$-carotene treated cells showed a distinct pattern of morphological abnormalities with inclusion of apoptotic bodies in both leukemia cell lines. When cells were treated with $20{\mu}M$ of $\beta$-carotene, total genomic DNA showed a fragmentation pattern and this pattern was clear in HL-60 than U937 cells. Both the cell lines, on treatment with $\beta$-carotene, showed a clear shift in $G_1$ phase of the cell cycle. In addition the study also revealed anti-oxidant properties of $\beta$-carotene since there was reduction in relative fluorescent when treated than the control at lower concentration. Collectively this study shows the dual phenomenon of apoptosis and differentiation of leukemia cells on treatment with $\beta$-carotene.

Dependence of the time resolved anti-Stokes Raman signal on the correlation between pump and Stokes waves (시분해 반스톡스 라만 분광 신호의 스톡스광과 펌프광의 상관관계에 대한 의존성 계산)

  • 고춘수
    • Korean Journal of Optics and Photonics
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    • v.8 no.5
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    • pp.372-376
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    • 1997
  • We study the time resolved anti-Stokes Raman spectroscopy with correlated pump and Stokes waves. When only two pump waves with relative delay are incident into a Raman medium, the Stokes waves generated by stimulated Raman scattering couple with the pump waves to generate anti-Stokes signal. Since the correlation between Stokes and the pump waves are not perfect and not quantified yet, we make a simple model fot it and calculate the normalized anti-Stokes signal intensities as a function of time delay. The broadband light regarded as chaotic field.

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Effect of ε Martensite Content and Strain Amplitude on Damping Capacity of Fe-17%Mn Alloy (Fe-17%Mn 합금의 진동감쇠능에 미치는 ε 마르텐사이트 함량과 진폭변형율의 영향)

  • Jun, Joong-Hwan;Lee, Young-Kook;Choi, Chong-Sool
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.2
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    • pp.112-120
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    • 1996
  • The effects of ${\varepsilon}$ martensite content and strain amplitude on damping capacity of an Fe-17%Mn alloy have been studied to establish damping mechanism of Fe-Mn system corresponding to the magnitude of strain amplitude. In a range of $1{\times}10^{-4}{\sim}3{\times}10^{-4}$ strain amplitude, the damping capacity is linearly proportional to the ${\varepsilon}$ martensite content, which suggests that stacking faults and ${\varepsilon}$ martensite variant boundaries are the principal damping sources. In the range of $4{\times}10^{-4}{\sim}6{\times}10^{-4}$ strain amplitude, however, a maximum damping capacity is observed around 68 vol.% ${\varepsilon}$. This behavior is very similar to dependence of relative area of ${\gamma}/{\varepsilon}$ interface on ${\varepsilon}$ martensite content. This means that in this strain range, ${\gamma}/{\varepsilon}$ interface acts as damping source in addition to the stacking faults and variant boundaries in Fe-17%Mn alloy.

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Development of a GPS Baseline Analysis Software for L1 Carrier Phase Using LAMBDA Method (LAMBDA 기법을 활용한 L1 반송파의 GPS 기선해석 프로그램 개발)

  • 박정현;이용욱;권재현;강준묵
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.21 no.2
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    • pp.173-180
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    • 2003
  • As the utility value of GPS in surveying field is on the increase after the conversion into the world geodetic system, most of the baseline processing programs seeking the relative baseline vector for the roving point based on the base point are dependent on the foreign software, and such dependence remains a stumbling block to its wide application. In this study an algorithm was established settling ambiguity through LAMBDA techniques and the baseline processing program was developed for Ll carrier phase using visual c++ 6.0, which is an object-oriented language. And the developed program proved that it maintained a difference of less than 4.9 cm over the short baseline of 4.9 km or shorter when compared with other commercialized programs.

Numerical Study of AGN Jet Propagation with Two Dimensional Relativistic Hydrodynamic Code

  • MIZUTA AKIRA;YAMADA SHOICHI;TAKABE HIDEAKI
    • Journal of The Korean Astronomical Society
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    • v.34 no.4
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    • pp.329-331
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    • 2001
  • We investigate the morphology of Active Galactic Nuclei(AGN) jets. AGN jets propagate over kpc $\~$ Mpc and their beam velocities are close to the speed of light. The reason why many jets propagate over so long a distance and sustain a very collimated structure is not well understood. It is argued that some dimensionless parameters, the density and the pressure ratio of the jet beam and the ambient gas, the Mach number of the beam, and relative speed of the beam compared to the speed of light, are very useful to understand the morphology of jets namely, bow shocks, cocoons, nodes etc. The role of each parameters has been studied by numerical simulations. But more research is necessary to understand it systematically. We have developed 2D relativistic hydrodynamic code to analyze relativistic jets. We pay attention to the propagation velocity which is derived from 1D momentum balance in the frame of the working surface. We show some of our models and discuss the dependence of the morphology of jets on the parameter.

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Monitoring of Initial Stages of Atmospheric Zinc Corrosion in Simulated Acid Rain Solution under Wet-dry Cyclic Conditions

  • EL-Mahdy, Gamal A.;Kim, Kwang B.
    • Corrosion Science and Technology
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    • v.3 no.6
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    • pp.251-256
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    • 2004
  • Exposure of zinc samples in simulated acid rain solution (SARS) was investigated under a periodic wet-dry conditions using an AC impedance technique. The periodic wet and dry exposure consisted of the immersion of zinc samples in SARS for one hour followed by exposure to 7 hours drying at 60% RH. Phases of the corrosion products were indentified by X-ray diffraction (XRD). The influence of relative humdiity (RH), temperature, and surface inclination on the atmospheric corrosion of zinc is described. The reciprocal of polarization resistance (1/Rp) decreases rapidly during the initial stages then slowly and eventually attains a steady state as exposure time progresses. The average of reciprocal of polarization resistance per cycle, (ARPR) was calculated and found to decrease as number of exposure cycle increases. An increase of temperature enhances the corrsion rate of zinc. The values of ARPR, of a sample inclined at 30 o are lower than those for a sample oriented horizontally. The experiment result shows a pronounced dependence of reciprocal of polarization resistance on RH. Exposure in the presence of carbonate anions gives rise to more protective corrosion products than in nitrate anion solution. The corrosion mechanism during the initial stages of atmospheric zinc corrosion under wet-dry cyclic conditions is suggested.