• Journal of Ocean Engineering and Technology
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• v.19 no.2 s.63
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• pp.53-59
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• 2005

The effect of pH on the corrosion characteristics in the dissimilar friction welded zone of IN713LC-SCM440 in the loaded torsional stress was studied. The corrosion experiment was performed for 120 hours on the specimens with five steps of pH. The surface corrosion pattern of the SCM440 area showed global corrosion and narrow pitting, which was caused by galvanic corrosion between friction welded IN713LC and SCM440, but corrosion did not proceeded from the IN713LC area. The average relative electrode potential gradually tends to decrease with the elapse of the immersion time in the acidity area. The average corrosion current also gradually tend to decrease The corrosion rate showed a larger value when the average relative electrode potential was higher and the average relative current was lower. The corrosion rate showed a larger value when the average relative electrode potential was higher in the acidity area, and it showed large when the average relative electrode potential was lower in the alkalinity area.

• Journal of Ocean Engineering and Technology
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• v.18 no.5
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• pp.50-56
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• 2004

This study is on the constant-current stress corrosion test, related to the load stress, in both the welded and non-welded zones of high tensile strength steel that is used for natural gas transmission. The surface corrosion pattern of the welded zone of API 5L-X65 specimens for natural gas transmission showed general corrosion and narrow pitting, and the pitting was increased with load stress. Initially, the average relative electrode potential and the average relative current of the high tensile strength steel, used for natural gas transmission specimens, were decreased rapidly, and the average relative electrode potential was higher and the average relative current was lower in welded zone, compared to base metal. The average relative electrode potential was decreased with load stress, and the average relative current was somewhat increased by increasing the load stress. The corrosion rate was less in welded zone, compared to base metal, and the corrosion rate was decreased by increasing the load stress.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2004.05a
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• pp.401-407
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• 2004

This study is on the constant-current stress corrosion test related to the load stress in welded zone and non-welded zone of high tensile strength steel for natural gas transmission. The surface corrosion pattern of the welded zone of API 5L-X65 specimens for natural gas transmission showed global corrosion and narrow pitting, and the pitting was increased by increasing the load stress. Initially, the average relative electrode potential and the average relative current of the high tensile strength steel for natural gas transmission specimens was decreased suddenly, and the average relative electrode potential was higher and the average relative current was lower in welded zone than base metal. and the average relative electrode potential was decreased by increasing the load stress, and the average relative current was somewhat increased by increasing the load stress. The corrosion rate was less in welded zone than base metal, and the corrosion rate was decreased by increasing the load stress.

• International Journal of Control, Automation, and Systems
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• v.5 no.5
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• pp.601-605
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• 2007

In this paper, we propose a simple and relative electrode contact monitoring method. By exploiting the power line interference, which is regarded as one of the worst noise sources for bio-potential measurement, the relative difference in electrode impedance can be measured without a current or voltage source. Substantial benefits, including no extra circuit components, no degradation of the body potential driving circuit, and no electrical safety problem, can be achieved using this method. Furthermore, this method can be applied to multi-channel isolated bio-potential measurement systems and home health care devices under a steady measuring environment.

• Proceedings of the KIEE Conference
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• 2007.10a
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• pp.469-470
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• 2007

In this paper, we propose a simple and relative electrode contact monitoring method. By exploiting the power line interference, which is regarded as one of the worst noise sources for bio-potential measurement, the relative difference in electrode impedance can be measured without a current or voltage source. Substantial benefits, including no extra circuit components, no degradation of the body potential driving circuit, and no electrical safety problem, can be achieved using this method. Furthermore, this method can be applied to multi-channel isolated bio-potential measurement systems and home health care devices under a steady measuring environment.

• Journal of Power System Engineering
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• v.9 no.1
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• pp.50-56
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• 2005

The corrosion experiment was performed for 120 hours on the specimens in the natural seawater tank with four steps of the loaded torsional stress. The surface corrosion pattern of SCM440 area was showed global corrosion and narrow pitting, that was cause by galvanic corrosion between friction welded IN713LC and SCM440. But corrosion does not proceeded from IN713LC area. Initially, the average relative electrode potential and corrosion current were decreased suddenly, by and large, it was stabilized gradually tend to decreasing with the elapse of the immersion time. The corrosion rate was decreased by increasing the load stress, but 200 MPa specimen was showed most large value.

• Journal of the Korean Chemical Society
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• v.43 no.4
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• pp.407-411
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• 1999

Studies have been carried out on the fabrication of PPy/GC and PPy/Pt electrode modified with polypyrrole film and determination of Cr(VI) by using 3-electrode system with modified electrodes. Modified electrodes were able to easily fabricated by cyclic voltammetry scanned from +1.0V to -1.0V(vs. Ag/AgCl) at 50 mV/sec. Film thickness could be controlled at same condition by the number of cycling up to 26 times. Reduction behaviour of Cr(VI) at PPy/GC electrode could be seen at wide potential ranges from +0.6V to -0.5V(vs. Ag/AgCl), and maximum reduction peak potential of the ion was observed at -0.25V(vs.Ag/AgCl). Calibration graph at its potential was linear from 0.1 ppm to 80.O ppm. Slope factor and relative coefficient were 1.75 mA/ppm and 0.998, respectively. Reduction behaviour of Cr(VI) at PPy/Pt electrode was similar to PPy/GC electrode, Calibration graph was linear from l.0 ppm to 60.0 ppm. Slope factor and relative coefficient were 0.5mA/ppm and 0.923, respectively. But PPy/GC modified electrode had about 3 times higher sensitivity than PPy/Pt modified electrode. Reduction behaviour of Cu(II), As(IlI), Pb(II), and Cd(II) couldn't be seen at PPy/GC electrode,Its metals had not lnterfered with Cr (VI) determination.

• Analytical Science and Technology
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• v.8 no.4
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• pp.649-654
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• 1995

The reactivity of superoxide ion($O{_2}^{-.}$) with halogenated substrates is investigated by cyclic voltammetry and rotated ring-disk electrode method in aprotic solvents. The more positive the reduction potential of the substituted nitrile, the more facile is nucleophilic displacement by $O{_2}^{-.}$. The reaction rates of halogenonitriles with $O{_2}^{-.}$ vary according to the leaving-group propensity of halide (Br>Cl>F). The relative reaction rates of other substituted nitriles are in the order of electron-withdrawing propensity of the substituent group (CN> $C(O)NH_2$ >Ph, $CH_2CN$). The reaction of $O{_2}^{-.}$ with dihalocarbons indicates that five-membered rings can be rapidly formed by the cyclization of substrate and $O{_2}^{-.}$, and the relative rates of cyclization depend on the number of methylenic carbons {$Br(CH_2)_nBr$, [n=1<2<3>4>5]}. Mechanisms are proposed for the reaction of $O{_2}^{-.}$ with halogenated substrates.

• Journal of the Korean institute of surface engineering
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• v.49 no.1
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• pp.87-91
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• 2016

The development of high performance transparent electrode with flexibility have been required for flexible electronics. Here, we demonstrate the silver nanowire and reduced graphene oxide hybrid transparent electrode for replacing brittle indium-tin-oxide electrode by spray coating technique and plasma reduction. The spray coating system is applied to deposit silver nanowire and over coated graphene oxide films and it has a great potential to scale-up. The resistance of silver nanowire transparent electrode is reduced by 10% and the surface roughness is decreased after graphene oxide coating. The over-coated graphene oxide is successfully reduced by $H_2$ plasma treatment and it is effective in increasing the environmental stability of electrode. The lifetime of silver nanowire and reduced graphene oxide hybrid electrode at $85^{\circ}C$ of Celsius degree of temperature and 85% of relative humidity has much increased.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.16 no.3
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• pp.239-245
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• 1983

Electrochemical adsorption always was accompanied with solvent displacement and relative size factor(x) of adsorbate and solvent and hydrogen coverage(${\theta}$) on the lead anodic film electrode formed in phosphoric acid in NaCl solution and the sea water at $15{\sim}35^{\circ}C$ were studied by means of constant current-potential method and potentiodynamic cathodic polarization method. In this experiment, various constants and thermodynamic quantities calculated from the hydrogen coverage were also described to explain the reactivities of di-iso-butylnitrosoamine(DBNA) and proton ($H^+$) according to the changes of interactions between solute and solvent in the bulk phase and interphase. It was investigated that the average values of relative size factor and the coverage of hydrogen atoms studied with the electrode of lead anodic film formed in phosphoric acid solution in 60mM DBNA+0.5M NaCl and in 60mM DBNA+$6\%0$ sea water were about 11.0 and 0.2 respectively. Hydrogen evolution was electrochemical mechanism because of substitutional adsorption of aromatic substance with their delocalization of electrons, but in the case of non-charge transfer adsorption of aliphatic substance(DBNA) interacting relatively little with the electrode, it was combination mechanism.