• 제목/요약/키워드: Relative Corrosion Current

검색결과 23건 처리시간 0.019초

천연가스 수송용 API 5L-X65강 용접부의 부식거동에 관한 연구 (On Corrosion Behaviors in Welded Zone of API 5L-X65 Steel for Natural Gas Transmission)

  • 조상근;송한섭;공유식;김영대
    • 한국해양공학회지
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    • 제18권5호
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    • pp.50-56
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    • 2004
  • This study is on the constant-current stress corrosion test, related to the load stress, in both the welded and non-welded zones of high tensile strength steel that is used for natural gas transmission. The surface corrosion pattern of the welded zone of API 5L-X65 specimens for natural gas transmission showed general corrosion and narrow pitting, and the pitting was increased with load stress. Initially, the average relative electrode potential and the average relative current of the high tensile strength steel, used for natural gas transmission specimens, were decreased rapidly, and the average relative electrode potential was higher and the average relative current was lower in welded zone, compared to base metal. The average relative electrode potential was decreased with load stress, and the average relative current was somewhat increased by increasing the load stress. The corrosion rate was less in welded zone, compared to base metal, and the corrosion rate was decreased by increasing the load stress.

천연가스 수송용 API 5L-X65강 용접부의 부식거동에 관한 연구 (A Study on Stress Corrosion Behaviors in Welded Zone of the API 5L-X65 Steel for Natural Gas Transmission)

  • 조상근;송한섭;공유식;김영대
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2004년도 학술대회지
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    • pp.401-407
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    • 2004
  • This study is on the constant-current stress corrosion test related to the load stress in welded zone and non-welded zone of high tensile strength steel for natural gas transmission. The surface corrosion pattern of the welded zone of API 5L-X65 specimens for natural gas transmission showed global corrosion and narrow pitting, and the pitting was increased by increasing the load stress. Initially, the average relative electrode potential and the average relative current of the high tensile strength steel for natural gas transmission specimens was decreased suddenly, and the average relative electrode potential was higher and the average relative current was lower in welded zone than base metal. and the average relative electrode potential was decreased by increasing the load stress, and the average relative current was somewhat increased by increasing the load stress. The corrosion rate was less in welded zone than base metal, and the corrosion rate was decreased by increasing the load stress.

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IN713LC-SCM440 이종재 마찰용접부의 부식특성에 미치는 pH의 영향 (The Effects of pH on the Corrosion Characteristics in Dissimilar Friction Welded Zone of IN713LC-SCM440)

  • 조상근;공유식;김영대
    • 한국해양공학회지
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    • 제19권2호
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    • pp.53-59
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    • 2005
  • The effect of pH on the corrosion characteristics in the dissimilar friction welded zone of IN713LC-SCM440 in the loaded torsional stress was studied. The corrosion experiment was performed for 120 hours on the specimens with five steps of pH. The surface corrosion pattern of the SCM440 area showed global corrosion and narrow pitting, which was caused by galvanic corrosion between friction welded IN713LC and SCM440, but corrosion did not proceeded from the IN713LC area. The average relative electrode potential gradually tends to decrease with the elapse of the immersion time in the acidity area. The average corrosion current also gradually tend to decrease The corrosion rate showed a larger value when the average relative electrode potential was higher and the average relative current was lower. The corrosion rate showed a larger value when the average relative electrode potential was higher in the acidity area, and it showed large when the average relative electrode potential was lower in the alkalinity area.

선박용 디젤엔진 과급기 로터 접합체의 부식특성에 미치는 비틀림응력의 영향 (Effects of Torsional Stress on the Corrosion Characteristics in the Rotor Assembly of Marine Diesel Engine Supercharger)

  • 조상근;공유식;김영대
    • 동력기계공학회지
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    • 제9권1호
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    • pp.50-56
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    • 2005
  • The corrosion experiment was performed for 120 hours on the specimens in the natural seawater tank with four steps of the loaded torsional stress. The surface corrosion pattern of SCM440 area was showed global corrosion and narrow pitting, that was cause by galvanic corrosion between friction welded IN713LC and SCM440. But corrosion does not proceeded from IN713LC area. Initially, the average relative electrode potential and corrosion current were decreased suddenly, by and large, it was stabilized gradually tend to decreasing with the elapse of the immersion time. The corrosion rate was decreased by increasing the load stress, but 200 MPa specimen was showed most large value.

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부식전류 평가를 통한 강박스 부재의 상대적 부식환경 평가 (Relative Corrosion Environment Conditions of Steel Box Members Examined by Corrosion Current Measurement)

  • 진용희;하민균;정영수;안진희
    • 한국구조물진단유지관리공학회 논문집
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    • 제24권6호
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    • pp.171-179
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    • 2020
  • 본 연구에서는 강박스 부재의 국부 부식열화환경을 모니터링하기 위하여 실제 강교량 부재로 사용하는 부재와 동일한 형상의 강박스 모형 시험체를 제작하였으며, 실제 공용 중인 강교량과 동일한 부식환경이 구현된 강박스 모형 시험체를 상부부재, 복부부재, 하부부재로 구분하여 모니터링을 진행하였다. 각 부재에 부식환경 모니터링 센서를 설치하여 부식전류를 계측하였으며, 부식전류량 계측 값으로부터 젖음시간을 계산하여 강박스 부재에 따른 국부적인 부식환경을 평가하였다. 모니터링 결과를 통하여 주위의 대기환경으로 인하여 나타날 수 있는 부식환경과 강박스 부재 표면에 직접적으로 나타날 수 있는 부식환경의 상대적인 차이를 검토하였으며, 강박스 부재들의 상대적 부식환경과 평균부식두께의 관계를 평가하였다.

Redox Reaction of Poly(ethyleneterephthalate) Polymer in Aprotic Solvent

  • Choi, Chil-Nami
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제10권S_1호
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    • pp.47-53
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    • 2001
  • We carroed our to measure the variations of potential with current density (polarization curves) for poly(ethyleneterephthalate). The results were particularly examined to identify the influences on corrosion potential and corrosion rate of various factors including temperature, pH, exposure time, salt, and enzyme. The Tafel slope for anodic dissolution was determined by the polarization effect depending on these conditions. The optimum conditions were established for each case. The second anodic current density peak and maximum passive current density were designated as the relative corrosion sensitivity$(I_r/I_f)$. The mass transfer coefficient value$(\alpha)$ was determined with the Tafel slope for anodic dissolution based on the polarization effect with optimum conditions.

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주조용 Al합금의 내식성에 관한 전기화학적 평가 (An Electrochemical Evaluation on the Corrosion Resistance of a Al Alloy)

  • 윤대현;이명훈;김기준;문경만
    • Journal of Advanced Marine Engineering and Technology
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    • 제29권5호
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    • pp.495-501
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    • 2005
  • Al is a active metal that owes its resistance to a thin, protective, barrier oxide surface layer, which is stable in air and neutral aqueous solution. Thus Al alloys are widely used in architectural trim. cold & hot-water storage vessels and piping. However Al and most of its alloy may corrode with some forms such as pitting corrosion, intergranular corrosion and galvanic corrosion in the case of exposure to various industrial and marine atmosphere. Therefore a correct evaluation of corrosion resistance for their Al and Al alloys may be more important in a economical point of view. In this study. a relative evaluation of corrosion resistance for three kinds of Al alloys such as ALDC2, ALDC3, and ALDC8 series was carried out with electrochemical method. There is a tendency that corrosion potential is shifted to positive or negative direction by alloying components regardless of corrosion resistance. Moreover the data of corrosion properties obtained from cathodic Polarization curve, cyclic voltammogram and AC. DC impedance respectively showed a good correspondence each other against the corrosion resistance but variation of corrosion potential. passivity current density of anodic polarization curve and corrosion current density by Tafel extrapolation and Stern-Geary method didn't correspond with not only each other but also considerably the data of corrosion properties discussed above. Therefore it is suggested that an optimum electrochemical evaluation for corrosion resistance of Al alloy is to calculate the diffusion limiting current density of cathodic polarization curve, impedance of AC or DC and polarization resistance of cyclic voltammogram.

인가전류밀도에 따른 플라즈마 전해산화코팅된 AZ91 마그네슘 합금의 내식성 변화 (Influence of Current Density on Corrosion Properties of AZ91 Mg Alloy Coated by Plasma Electrolytic Oxidation Method)

  • 이병욱;황인준;이재식;고영건;신동혁
    • 대한금속재료학회지
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    • 제49권8호
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    • pp.601-607
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    • 2011
  • The study investigated the influence of current density on the corrosion-protection properties of an AZ91 Mg alloy subjected to plasma electrolytic oxidation coating. The present coatings were carried out under an AC condition at three different current densities, i.e., 100, 150, and $200mA/cm^2$. From microstructural observations, the micro cracks connecting each micro pore were pronounced on the oxide surface of the samples coated at current densities higher than $150mA/cm^2$ since increasing the current density in this study led to an increment in the relative volume fraction of the MgO compound. Based on potentio dynamic polarization and immersion tests, the sample coated at a current density of $100mA/cm^2$ showed superior corrosion resistance.

The effect of temperature and relative humidity on concrete slab specimens with impressed current cathodic protection system

  • Jeong, Jin-A;Jin, Chung-Kuk
    • Journal of Advanced Marine Engineering and Technology
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    • 제37권3호
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    • pp.260-265
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    • 2013
  • Impressed current cathodic protection (ICCP) system is one of the most promising corrosion protection methods. The Effect of ICCP system can be changed at diverse conditions. Particularly, temperature and relative humidity plays a crucial role in CP (Cathodic Protection) effect. Thus, in this study, the influence of temperature and relative humidity on concrete specimens was investigated. Specimens were concrete slab type with a base of $400mm{\times}400mm$ and height of 70mm. To enhance the effect of CP system, seawater was used as an electrolyte. Used anode for ICCP system was mixed metal oxide (MMO) titanium. Test factors were natural potential, CP potential, CP current, and 4-hour depolarization potential. From this study, it could be confirm that CP potential and current were highly influenced by temperature and relative humidity.

Redox Reaction on Polarization Curve Variations of Polymer with Enzymes

  • Park, Chil-Nam
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제4권3호
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    • pp.165-171
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    • 2000
  • Experiments were carried out to measure variations in the oxidation potential and current density using the polarization curves of polycarbonate. The results were then examined to identify the influences affecting the oxidation potential related to various conditions, such as temperature, pH, and oxydase(citrate and lipase). The lines representing the active anodic and cathodic dissolution shifted only slightly in the potential direction relative to temperature, pH, and the effect of the enzyme. The Tafel slope for the anodic and cathodic dissolution was determined such that the reversibility polarization was indicated as being effected by various conditions. The slope of the polarization curves describing the active-to-passive transition region shifted noticeably in their direction. Also, by varying the conditions, the optimum conditions for the most ready transform were identified, including temperature, pH, oxidation rate, and resistance of oxidation potential. The critical oxidation sensitivity(I(sub)r/I(sub)f) of the anodic current density peak and maximum passive current density was also determined, which is used in measuring the critical corrosion sensitivity of a polycarbonate.

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