• Title/Summary/Keyword: Reinforcing Agent

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Reinforcing Efficiencies of Two Different Cellulose Nanocrystals in Polyvinyl Alcohol-Based Nanocomposites

  • Park, Byung-Dae;Causin, Valerio
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.4
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    • pp.250-255
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    • 2013
  • As a renewable nanomaterial, cellulose nanocrystal (CNC) isolated from wood grants excellent mechanical properties in developing high performance nanocomposites. This study was undertaken to compare the reinforcing efficiency of two different CNCs, i.e., cellulose nanowhiskers (CNWs) and cellulose nanofibrils (CNFs) from hardwood bleached kraft pulp (HW-BKP) as reinforcing agent in polyvinyl alcohol (PVA)-based nanocomposite. The CNWs were isolated by sulfuric acid hydrolysis while the CNFs were isolated by 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation. Based on measurements using transmission electron microscopy, the individual CNWs were about $6.96{\pm}0.87nm$ wide and $178{\pm}55nm$ long, while CNFs were $7.07{\pm}0.99nm$ wide. The incorporation of CNWs and CNFs into the PVA matrix at 5% and 1% levels, respectively, resulted in the maximum tensile strength, indicating different efficiencies of these CNCs in the nanocomposites. Therefore, these results suggest a relationship between the reinforcing potential of CNCs and their physical characteristics, such as their morphology, dimensions, and aspect ratio.

An Outlook of the Oriental and Western Medical Diagnosis and Treatment on Gastric Cancer (위암(胃癌)의 동서의학적(東西醫學的) 진치(診治) 개황(槪況))

  • Kim, Byeong-Ju;Moon, Goo
    • The Journal of Korean Medicine
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    • v.17 no.2 s.32
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    • pp.100-116
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    • 1996
  • Gastric cancer shows the most high friquency in cancers that occurs in Korea. The western medicine treatment for gastric cancer has radiation and surgery, chemical treatment. While, oriental medicine cures the gastric cancer by herb-drugs, acupunture , moxa and srigma. With just one way of treating gastric cancer can't be effective remedy. Because each medicine has a strength and weakness. Thus, it is effective treatment when two medicine combins and supplement each other. We got the following result about a trend of oriental and westernal combination treatment for gastric cancer through studing records. 1. The western medicine treats gastric cancer patient with surgery first and right after surgery. They need on assembly treatent such as chemical and immune treatment. In oriental medicine, they treats gastric cancer patients with differentiation of symptone and signs and treatment(辨證施治)[for example:incoordination between liver and stomach(肝胃不和), insufficiency of spleen and stomach(脾胃虛弱), stagnation of blood stasis and toxic agent(瘀毒內阻), deficiency of yin by stomach heat(胃熱傷陰), reinforcing both qi and blood(氣血雙虧), stagnation of damp-phlegm(痰濕凝結)] and cure for them by acupuncture and stigma, too. 2. In combination with oriental and western medical treatment principle of gastric cancer by each stage is as follows. First stage and second stage gastric cancer is cured with radical surgery mainly. After operation, the herb of invigoration of the spleen(健脾), coordination of the stomach(和胃), and smoothing the liver and regurating the circulation of qi(疏肝理氣), is used for good gastroenteric condition. The second stage patients can be concidered using in combination with chimical treatment. The third stage gastric cancer is treated with radical surgery or with temporizing surgery. After those surgery, herb-drugs treatment is used jointly. The fourth stage patients who have no extensively metastasis or local contraindication can undergo temporizing and curcuit surgical operation. Herb-drugs and chemical treatments are used together for patients after operating. If he has operating contraindication, he would be treated with herb-drugs and chemical treatment. 3. In case of using in combination with oriental and western medical treatment as follows. As for herb-drugs with chemical treatment, reinforcing both qi and blood(補益氣血), invigorate the spleen and the stomach(健脾和胃), reinforcing liver and kidney(滋補脾腎), clear out the heat and relieve the toxic agent(淸熱解毒), can be used and with radiation treatment, clear out the heat and relieve the toxic agent(淸熱解毒), promoting the production body fluid and moisturizing the vicera(生津潤燥), reinforcing both qi and blood(補益氣血), invigorate the spleen and the stomach (健脾和胃), reinforcing liver and kidney(滋補肝腎) etc, can be used. 4. According to the research of oriental and western medical combination treatment are the 5-year-survival degree with oriental and western medicine combination treatment was for better than that just with oriental or western medical treatment. Especially, it has good effect on the third, fourth stage gastric cancer. That is, the middle and the end of stage gastric cancer. 5. The merits of oriental and western medicine combination treatment are lengthers one's life and diminish the bad effect of chemical treatment and radiation treatment be near completion, prevent from relapsing, maintain the balance in their eveirenment of body and improve immunity.

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A Study on the Physical Properties of Reinforcing Fillers with Dual Phase Structure (이중상 구조를 가진 보강성 충전제의 물리적 특성 연구)

  • Lee, Seag;Park, Nam Cook
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.608-613
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    • 1998
  • The purpose of this experiment was the physical properties of rubber compounds with DPCB and pure carbon black. Si-O peak in the silcia surface was observed at the range of wavenumber from 1,100 to 1,200 in the DPCB by FT-IR analysis. Cure rate of rubber compounds containing DPCB and organic silane coupling agent were (Si69) delayed compared with those containing pure carbon black. 300% modulus and interaction coefficient of DPCB with silane coupling agent were higher than those of pure carbon black and PICO weight loss amount showed constant value. It was found that $0^{\circ}C$ tan$\delta$ of rubber compounds with DPCB was larger than those of pure carbon black at 2.0% silane coupling agent based on 50 phr DPCB and $60^{\circ}C$ tan$\delta$ of rubber compounds with DPCB decreased as increasing the usage coupling agent. Consequently, it is postulated that DPCB is strong candidate material for lowering rolling resistance under constant abrasion resistance.

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Analysis on Shrinkage Properties of High Performance Concrete According to Mock-Up Test (고성능 콘크리트의 Mock-Up 시험에 의한 수축특성 분석)

  • Koh Kyoung Taek;Jin Hu Lin;Ryu Gum Sung;Hwang Yin Seong;Kim Do Gyum;Han Cheon Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.545-548
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    • 2004
  • This paper is to investigate the shrinkage properties of high performance concrete (HPC) with mixture adjustment by using mock-up specimens. HPC with mixture adjustment needed a higher dosage of SP agent due to fluidity reduction and a larger dosage of AE agent due to the reduction of air content. Setting time of HPC with mixture adjustment exhibited earlier than that of control HPC by as much as 6 hours. HPC with mixture adjustment gained more than 70MPa of compressive strength. Autogenous shrinkage of Control HPC was found to be $-340\times40^{-6}$ at 49days when the expansion value by thermal effect was excluded and HPC with mixture adjustment $-175\times10^{-6}$, which was the half of the value of control HPC. Drying shrinkage of center section of HPC with mixture adjustment showed similar tendency with autogenous shrinkage because of no internal moisture movement, while surface section had larger drying shrinkage. The specimen embedded with reinforcing bar had smaller deformation caused by confinement of reinforcing bar.

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A Study on Anti-Corrosion Effect of Powder Self Water Proof Admixture Mixed Corrosion Inhibitor for Reinforcing Steel (철근부식억제형 구체방수재의 방청효과에 관한 연구)

  • 신도철;손형호;김원화
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.409-414
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    • 2002
  • This study is intended to develop the self water proof admixture for durability concrete by anti-corrosion inhibitor. Chloride induced corrosion of reinforcement is one of the main factor which cause the deterioration of concrete structure. When the substitute anti-corrosion agents for a part of self waterproofing agent, the corrosion-proof increases for the increased water proofing capacity. And proper self waterproofing agent by cement weight in concrete was generally positive effect to concrete compressive strength, slump, freezing and thawing resistance. Also, permeability and absorption show a straight decrease when self waterproofing agent is added.

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A Study on the Surface-Treatment Agent as Concrete Repair Materials (콘크리트 보수재료로서 도포형 표면강화물질 검토)

  • 김도겸;고경택;김성욱;류금성;이장화
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.497-502
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    • 2001
  • We examined the silicate-based material to develop the surface-treatment agent, which would be used to restore performance of the deteriorated concrete and to inhibit corrosion of the reinforcing bar. As a part of the study, we carried out experiments of the penetration and strengthening properties of concrete treated by the considering agent. The variables of experiment, were the type of silicates, the ratio of distilled water-silicate, the usage of surface-strengthening material, and the usage of biochemical material. The penetrating ability of concrete is assessed by viscosity and surface tension. Also assessments of strengthening effects of concrete are performed on compressive strength, absorption, and water permeability tests.

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Development of Deterioration Restraining Agent Using Polycondensed Silicate and Monomers (실리케이트와 모노머합성을 통한 콘크리트 열화억제제 개발)

  • Kim, Do-Gyeum;Cho, Myeng-Suk;Song, Young-Chul;Kwak, Ju-Ho;Ryu, Gum-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.563-566
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    • 2005
  • Concrete structures have been damaged by salt, carbonization, freezing and thawing and the others. Therefore, it is needed to protect durability and performance according to the appropriate materials and methods in the concrete structures. In general, several types of polymer and silicate are used as protecting deterioration agents of concrete structures, but these agents have many problems because of low durability and properties. In this study, It developed the deterioration restraining agent using polycondensed silicate and monomer that can block a deterioration cause such as $CO_2$ gas, salt and water from the outside and enhance waterproofing ability by reinforcing the concrete surface when applying it to concrete structures. Also, it developed the systems for improving concrete performance using a deterioration restraining agent.

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Mortar Characteristics for Reinforcement of Ancient Tomb Murals Using Oyster Shells

  • Lee, Hwa Soo;Yu, Yeong Gyeong;Han, Kyeong Soon
    • Journal of Conservation Science
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    • v.34 no.4
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    • pp.295-303
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    • 2018
  • The application of reinforcing agents with hydraulic property and strength development characteristics was studied under conditions similar to those of mural-painting mortar made with oyster shell powder. Reinforcement mortar made with oyster shell powder showed hydraulic properties and strength to supplement the weaknesses of natural hydraulic lime(NHL); this confirmed its possibility as a wall-reinforcing material with enough strength for preserving mural paintings. Reinforcement mortar 1 showed hydraulic property and general characteristics of lime mortar, such as consistency and viscosity, as well as lower strength and higher whiteness compared to an NHL product. For Reinforcement mortar 2, the original wall sample characteristics were reflected by mixing more shell produced through calcination; and it showed similar strength to that of Reinforcement mortar 1 as well as high whiteness. In measuring the contraction ratio of reinforcement mortar samples, Reinforcement mortar 1 and 2 showed more stability in property change compared to the NHL Group.

Nanofiller as Crosslinker for Halogen-Containing Elastomers

  • Sahoo, N.G.;Kumar, E.Shiva;Das, C.K.;Panda, A.B.;Pramanik, P.
    • Macromolecular Research
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    • v.11 no.6
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    • pp.506-510
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    • 2003
  • A Zn ion-coated nanosilica filler has been developed and tested, in chlorosulfonated polyethylene (CSPE) and polychloroprene (CR), as a vulcanizing activator, cum was reinforcing filler. In this study, ZnO was replaced by the Zn ion-coated nanosilica filler with an aim of studying the dual role of this nanofiller in CSPE and CR. In the case of CSPE vulcanizates, the presence of MgO deteriorated the state and rate of cure when the Zn ion-coated nanosilica filler was used, but in the case of CR it improved the state of cure and enhanced the modulus and tensile strength. The Zn ion-coated filler proved to be a better reinforcing-cum-curing agent than was externally added ZnO and NA-22 also proved to be a better curative in the presence of the Zn ion-coated nanosilica filler for both CSPE and CR.

Bond Properties of CFRP Rebar in Fiber Reinforced High Strength Concrete with Surface Treatment Methods of Reinforcing Fibers (보강섬유의 표면처리에 따른 섬유보강 고강도콘크리트와 CFRP 보강근의 부착특성)

  • Park, Chan-Gi;Won, Jong-Pil;Cha, Sang-Sun
    • Journal of the Korea Concrete Institute
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    • v.21 no.3
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    • pp.275-282
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    • 2009
  • The effects of surface treatment method of reinforcing fiber on the bonding strength between carbon fiber reinforced polymer rebar (CFRP rebar) and high strength concrete have been evaluated in this study. The structural PVA fiber is coated with a proprietary hydrophobicoiling agent and crimped type polyolefin based structural synthetic fiber is deformed with a geometrical modification were used for the reinforcing fiber. The compressive tests have been performed to evaluate the strength property of high strength concrete depending on the surface treatment method of fiber. The bonding property between the high strength concrete and the CFRP rebar was evaluated by means of direct bonding test. The test results indicated that the surface treatment method of fiber effect on the bonding behavior of high strength concrete and CFRP rebar. Also, as the development and propagation of splitting cracks were controled by adding fibers into the high strength concrete, the bonding behavior, bond strength and relative bonding strength of CFRP rebar and high strength concrete were significantly improved.