• Transactions of the Korean hydrogen and new energy society
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• v.27 no.4
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• pp.462-469
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• 2016

This paper presents the results of thermodynamic cycle analysis and performance tests of alternative mixtures in low temperature applications. Two near-azeotropic binary mixtures R-152a/R-1270 (35:65 by wt.%) and R-290/E170 (35:65 by wt.%) are considered in this study. They have zero ODP (Ozone Depletion Potential) and much lower GWP (Global Warming Potential) than R-404A which is an alternative of R-502. Refrigeration cycle characteristics such as cooling capacity, coefficient of performance, suction and discharge pressures and temperatures are compared to those for the baseline refrigerants (R-502 and R-404A) cycles. The performance tests are conducted at the evaporation and condensation temperatures of $5^{\circ}C$ and $45^{\circ}C$, subcooling and superheating temperatures of $5^{\circ}C$, respectively. Performance comparisons between baseline and alternative refrigerants are conducted on the same cooling capacity. The system performance of newly proposed refrigerant mixtures show promising results.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.2
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• pp.730-740
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• 1996

Boiling heat transfer coefficients of pure refrigerants (R22, R32, R134a, R125, R290, and R600a) and refrigerant mixtures (R32/Rl34a, R290/ R600a, and R32/R125) are measured experimentally and compared with Chen's correlation. The test section is a seamless stainless steel tube with inner diameter of 7.7mm and uniformly heated by applying electric current directly to the tube. Heat fluxes range from 10 to 30kW$^2$. Mass fluxes are set to 424 ~ 742kg/m$^{2}$s for R22, R32, R134a, R32/R134a, and R32/Rl25 ; 265 ~ 583kg/m$^{2}$s for R290, R600a, and R290/R600a. Heat transfer coefficients depend strongly on heat flux at a low quality region and become independent as quality increases. Convective boiling term in the Chen's correlation predicts experimental data of the pure refrigerants fairly well (relative error of 12.1% for the data of quality over 0.2). The correlation for pure substances overpredicts the heat transfer coefficients for nonazeotropic refrigerant mixtures.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.14 no.6
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• pp.468-476
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• 2002

This paper deals with heat and mass transfer characteristics and performance evaluation of a counter flow double-tube condenser for a multi-component refrigerant mixture. The local heat and mass transfer characteristics of ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a are evaluated for a counter flow double-tube condenser cooled by water. Then, the local values of vapor quality, thermodynamic states at bulk vapor, vapor-liquid interface and bulk liquid, heat flux and condensation mass flux are obtained. The heat exchange performance for ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a on the total pressure drop and the heat transfer characteristics are also compared with those for R404A, R410A, R502, R22, R32, Rl23 and R134a.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.14 no.2
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• pp.161-167
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• 2002

In this study, external condensation heat transfer coefficients (HTCs) of two non-azeotropic refrigerant mixtures of HFC32/HFC134a and HF0134a/HCF0123 at various compositions were measured on both low fin and Turbo-C enhanced tubes of 19.0 mm outside diameter All data were taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling of 3- 8 K. Test results showed that HTCs of the tested mixtures on the enhanced tubes were much lower than the ideal values calculated by the mass fraction weighting of the pure compo- nents'HTCs. Also the reduction of HTCs due to the diffusion vapor film was much larger than that of a plain tube. Unlike HTCs of pure fluids, HTCs of the mixtures measured on enhanced tubes increased as the wall subcooling increased, which was due to the sudden break up of the vapor diffusion film with an increase in wall subcooling. Finally, heat transfer enhancement ratios for mixtures were found to be much lower than those of pure fluids.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.5
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• pp.1337-1348
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• 1990

Estimations of the thermodynamic properties are made for the selected binary non-azeotropic refrigerant mixtures including R13B1/R114, R22/R114, R12/R114, R152a/R114, R13B1/R152a and R13B1/R12 using the Peng-Robinson equation of state and mixing rules. In this study, we find that the binary interaction coefficients for the above mixtures have an effect upon the vapor-liquid equilibria and the thermodynamic properties. As the binary interaction coefficient becomes larger, the deviation from the idealized model, say, Raoult`s rule, is obvious. A correlation is proposed to relate the binary interaction coefficient to the difference between the dipole moments op each pure refrigerant. Vapor-liquid equilibrium are also accurately estimated using the binary interaction coefficient. Pressure-enthalpy and temperature-entropy relations are plotted for a certain composition ratio of each refrigerant mixture. Results show that the estimating method in this study can be applied to the investigation of the thermodynamic properties for the binary non-azeotropic refrigerant mixtures.

• Journal of Advanced Marine Engineering and Technology
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• v.20 no.3
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• pp.91-100
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• 1996

Experimental results for forced convection condensation of non-azeotropic refrigerant mixtures inside a horizontal smooth tube are presented. The mixtures of R-22+R-134a and pure refrigerants R-22 and R-134a are used as the test fluids and a double pipe heat exchanger of 7.5mm ID and 4800mm long inside tube is used. The range of parameters are 100-300kg/h of mass flow rate, 0-1.0 of quality, and 0, 33, 50, 67, and 100 weight percent of R-22 mass fraction in the mixtures. The heat flux, vapor pressure, vapor temperature and tube wall temperature were measured. Using the data, the local and average heat transfer coefficients for the condensation have been obtained. In the same given experimental conditions, the liquid heat transfer coefficients for NARMs were considerally lower than that of the pure refrigerant of R-22 and R-134a. Local heat transfer characteristics for NARMs were different from pure refrigerant R-22 and R-134a. In some regions, local heat transfer coefficients for NARMs were increased in the following order ; Bottom$\rightarrow$Top$\rightarrow$Side. The condensation heat transfer coefficients for NARMs increased with mass velocity, heat flux, and quality, but were considerably lower than that of pure refigerant R-22 and R-134a.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.4 no.1
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• pp.33-47
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• 1992

Experimental investigation on the performance of a heat pump system using refrigerant mixtures is done. The condenser and the evaporator are double pipe heat exchangers of counter flow type and the compressor is driven by a variable speed motor. The refrigerant mixture used in the experiment is R22/R142b. Experiments are performed by changing the compressor speed, composition on ratio of mixture, and the average temperatures of condenser and evaporator. The compressor work, heating capacity and the coefficient of performance are calculated. Results show that the heating capacity can be changed by varying the mass flow rate of refrigerant mixtures to meet the heating load. It is shown that the capacity control by changing the composition ratio is more effective than by changing the compressor speed. Under the condition where the external conditions are fixed and the heating loads are equal, the coefficient of performance has its maximum value near 50 : 50 mass fraction of the refrigerant mixture in this study.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.21 no.4
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• pp.243-251
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• 2009

Refrigerant mixtures provide an opportunity to adjust their properties to fit design criteria and a possibility to create new blends that can improve heat transfer characteristics. Therefore, mixture of $CO_2$ and propane is chosen which may be a promising refrigerant and has good environmental compatibility. This paper presents measured heat transfer coefficient data during evaporation process of $CO_2$/propane mixtures flowing upward in vertical smooth and. micro-fin tubes. Smooth and micro-fin tubes with outer diameters of 5 mm and length of 1.44in were selected as test tubes. The tests were conducted at mass fluxes of 212 to $656kg/m^{2}s$, inlet temperatures of -10 to $30^{\circ}C$, heat fluxes of 15 to $60\;kW/m^2$ and for several compositions (75/25, 50/50, 25/75 wt%). Among $CO_2$/propane refrigerant mixtures, the heat transfer characteristics are much better than that of any compositions when the composition is 75/25 (wt%).

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.3
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• pp.292-302
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• 1998

In this study, 14 refrigerant mixtures composed of R32, R125, R134a, R143a, R152a, and R1270(Propylene) were tested in a breadboard heat pump in an attempt to replace R22 used in most of the residential air conditioners and heat pumps. The heat pump was of 1 ton capacity and water was employed as the secondary heat transfer fluids. All tests were conducted under ARI test A condition. Ternary mixtures composed of R32, R125, and R134a were shown to have 4∼5% higher COP and capacity than R22 and hence they seem to be very promising candidates to replace R22. On the other hand, ternary mixtures containing R125, R134a, and R152a have lower COP and capacity than R22. R32/R134a binary mixtures show a 7% increase in COP and have the similar capacity to that of R22 and hence they are also good candidates to replace R22. Special care must be exercised when a suction line heat exchanger is used with these mixtures in air conditioners. Finally, the compressor discharge temperatures of all mixtures tested were lower than those of R22 by 15.g∼34.7t, which indicates that these mixtures would offer better system reliability and longer life time than R22.

• International Journal of Air-Conditioning and Refrigeration
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• v.9 no.1
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• pp.39-49
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• 2001

Investigation of the performance of an autocascade refrigeration system using the refrigerant mixtures of R744 (carbon dioxide) and R134a (1,1,1,2-tetrafluoroethane) has been carried out by simulation and experiment. Cycle simulation using a constant UA model in heat exchangers has been performed for R744/134a mixtures of the compositions ranging from 10/90 to 30/70 by weight. Variations of mass flow rate of refrigerant, compressor work, refrigeration capacity and COP with respect to mass fraction of R744/134a mixture were presented. Performance test has been executed in the autocascade refrigeration system by varying secondary fluid temperatures at evaporator and condenser inlets. Experimental results match quite well with those obtained from the simulation.