• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.5 s.236
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• pp.643-652
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• 2005

Saturated nucleate pool boiling experiments for binary mixtures, which are consisted of refrigerant R11 and R113, were performed with constant wall temperature condition. Results for binary mixtures were also compared with pure fluids. A microscale heater array and Wheatstone bridge circuits were used to maintain the constant temperature of the heating surface and to obtain heat flow rate measurements with high temporal and spatial resolutions. Bubble growth images were captured using a high speed CCD camera synchronized with the heat flow rate measurements. The departure time for binary mixtures was longer than that for pure fluids, and binary mixtures had a higher onset of nucleate boiling (ONB) temperature than pure fluids. In the asymptotic growth region, the bubble growth rate was proportional to a value between $t^{\frac{1}{6}}$ and $t^{\frac{1}{4}}$. The bubble growth behavior was analyzed to permit comparisons with binary mixtures and pure fluids at the same scale using dimensionless parameters. There was no discernable difference in the bubble growth behavior between binary mixtures and pure fluids for a given ONB temperature. And the departure radius and time were well predicted within a ${\pm}30{\%}$ error. The minimum heat transfer coefficient of binary mixtures occurred near the maximum ${\mid}y-x{\mid}$ value, and the average required heat flux during bubble growth did not depend on the mass fraction of R11 as more volatile component in binary mixtures. Finally, the results showed that for binary mixtures, a higher ONB temperature had the greatest effect on reducing the heat transfer coefficient.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.11
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• pp.859-866
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• 2006

This paper presents the vapor-liquid equilibrium (VLE) data measured for carbon dioxide and propane mixtures. Their mixtures were considered as promising alternative refrigerants due to good thermophysical properties and negligible environmental impact. The isothermal VLE data were measured at eight temperatures ranging from 253.15 to 323.15 K in the circulation type equipment with a view cell. The binary system was found to be a zeotropic mixture in the tested temperature range and could be correlated with sufficient accuracy by using the Peng-Robinson equation of state (PR EoS) with the van der Waals one fluid mixing rule. A comparison with published experimental VLE data has been carried out by means of the PR equation of state. In addition, the phase behaviors of carbon dioxide and propane mixtures were analyzed based on the measured VLE data.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.12
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• pp.1656-1667
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• 1997

Condensing heat transfer characteristics of hydrocarbon refrigerants are experimentally investigated. Single component hydrocarbon refrigerants (propane, isobutane, butane and propylene) and binary mixtures of propane/isobutane and propane/butane are considered as test fluids. Local condensing heat transfer coefficients of selected refrigerants are obtained from overall conductance measurement. Average heat transfer coefficients at different mass fluxes and heat transfer rates are shown and compared with those of R22. Pure hydrocarbon refrigerants have higher values of heat transfer coefficient than R22. It is also found that there is a heat transfer degradation for hydrocarbon mixtures due to composition variation during condensation. Measured condensing heat transfer coefficients are compared with predicted values by available correlations. An empirical correlation for pure and mixed hydrocarbon is developed, and it shows good agreement with experimental data.

• Proceedings of the SAREK Conference
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• 2004.11a
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• pp.97-97
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• 2004

• Proceedings of the SAREK Conference
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• 2003.07a
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• pp.29-29
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• 2003

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.28 no.5
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• pp.375-388
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• 1999

1974년 6월 Rowland와 Molina가 CFCs등의 화학물질이 성층권의 오존층을 파괴시킨다는 가설의 발표는 많은 환경론자들의 관심과 함께 논쟁의 대상이 되었다. 이 가설은 1985년 10월 Farman 등의 영국 남극조사팀에 의해 남극상공의 성층권 오존이 1970년대에 비해 약 40% 정도 감소된 것이 확인되면서 지구전체의 심각한 환경문제로 대두되었다.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.12
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• pp.955-963
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• 2006

Nucleate pool boiling heat transfer coefficients (HTCs) were measured with one nonazeotropic mixture of Propane/Isobutane and two azeotropic mixtures of HFC134a/Isobutane and Propane/HFC134a. All data were taken at the liquid pool temperature of $7^{\circ}C$ on a horizontal plain tube with heat fluxes of $10kW/m^2\;to\;80kW/m^2$ with an interval of $10kW/m^2$ in the decreasing order of heat flux. The measurements were made through electrical heating by a cartridge heater. The nonazeotropic mixture of Propane/Isobutane showed a reduction of HTCs as much as 41% from the ideal values. The azeotropic mixtures of HFC134a/Isobutane and Propane/HFC134a showed a reduction of HTCs as much as 44% from the ideal values at compositions other than azeotropic compositions. At azeotropic compositions, however, the HTCs were even higher than the ideal values due to the increase in the vapor pressure. For all mixtures, the reduction in heat transfer was greater with a larger gliding temperature difference. Stephan and $K{\ddot{o}}rner's$ and Jung et al's correlations predicted the HTCs of mixtures with a mean deviation of 11%. The largest mean deviation occurred at the azeotropic compositions of HFC134a/Isobutane and Propane/HFC134a.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.4
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• pp.312-319
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• 2006

In this study, performance of 2 pure hydrocarbons and 7 mixtures was measured in an attempt to substitute HCFC22 used in air-conditioners and heat pumps. The mixtures were composed of R1270 (propylene), R290 (propane), HFC152a, and RE170 (Dimethyl ether, DME). The pure and mixed refrigerants tested have GWPs of $3{\sim}58$ as compared to that of $CO_2$ and the mixtures are all near-azeotropic showing the gliding temperature difference (GTD) of less than $0.6^{\circ}C$. Thermodynamic cycle analysis was carried out to determine the optimum compositions and actual tests were performed in a laboratory heat pump test bench at the evaporation and condensation temperatures of 7.5 and $45.1^{\circ}C$ respectively. Test results show that the coefficient of performance (COP) of these mixtures is up to 5.7% higher than that of HCFC22. While propane showed 11.5% reduction in capacity, most of the fluids tested had the similar capacity to that of HCFC22. Compressor discharge temperatures were reduced by $11{\sim}17^{\circ}C$ with these fluids. There was no problem with mineral oil since the mixtures were mainly composed of hydrocarbons. The amount of charge was reduced up to 55% as compared to HCFC22. Overall, these fluids provide good performance with reasonable energy savings without any environmental problem and thus can be used as long term alternatives for. residential air-conditioning and heat pumping application.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.5 no.2
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• pp.141-155
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• 1993

Thermodynamic properties of R-32 are calculated and its refrigeration performance is evaluated for the purpose the feasibility study of replacing R-22 with R-32. (1) Refrigeration effect of R-32 is superior to that of R-22 because heat of evaporation of R 32 is about 50% higher than that of R-22. However, COP of R-32 system is 10-30% lower than that of R-22 system. It is mainly attributed to the vapor pressore of R-32 being about 62% higher than R-22. (2) Since the pressure ratio and the specific heat ratio of R-32 system is higher than those of R -22, compressor discharging temperature rises as high as to $130-150^{\circ}C$. It may cause mechanical failure of compressor due to the breakdown of lubricant. Compressor should be improved to lower the temperature if R-32 is to replace R-22. (3) Averaged two-phase heat transfer coefficient of R-32 is about 10-20% higher than that of R-22. It may assume better heat exchanger effectiveness but not guarantee the better COP of R-32 system than R-22. (4) The high vapor pressure is the first reason to drop R-32 out of the line of R-22 alternative refrigerant. So, refrigerant mixtures based on R-32 are recommended to adjust the vapor pressure first and keep superior volumetric capacity of R-32.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.7 no.2
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• pp.234-248
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• 1995

A super-heat pump system composed of a suction line heat exchanger, low and high stage economizers, and a screw compressor is simulated to examine the energy performance and design options. CFC12, HCFC22, HFC134a, HCFC22/HCFC142b, HFC32/HFC134a, and HFC125/HFC134a are used as working fluids for comparison. The results indicate that the proposed system charged with appropriate mixtures is up to 33.4% more energy efficient than the normal system with CFC12. The performance of the super-heat pump system charged with mixtures was influenced by such factors as the temperature matching, heat source temperature difference, low stage economizer, and high stage economizer. The fluids with a larger liquid specific heat such as HFC134a would have more benefits when a suction line heat exchanger is installed. 40%HCFC22/60%HCFC142b mixture seems to be a good candidate to replace CFC12. On the other hand, 25%HFC32/75% HFC134a would be a good long term candidate to replace HCFC22.