• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.13 no.4
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• pp.262-270
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• 2001

This paper deals with a prediction method for the condensation of ternary refrigerant mixture inside a horizontal smooth tube. Based on some reliable assumptions, the governing equations for the local heat and mass transfer characteristics are derived, and the prediction for the condensation of ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a, including R407C, is carried out. The local values of vapor quality, thermodynamic states at bulk vapor, vapor-liquid interface and bulk liquid, mass flux etc. are obtained for a constant wall temperature and a constant wall heat flux conditions, and the effects of the composition of HFC32/HFC125/HFC134a on heat transfer characteristics are examined. The prediction result is also compared with experimental data for condensation of ternary refrigerant mixtures. The predicted wall temperature distribution has a similar trend with experimental data but the predicted local heat transfer coefficients are 20-30% higher than the experimental data.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.2
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• pp.262-269
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• 1999

The application of hydrocarbon refrigerant mixtures in a hermetic reciprocating compressor for dehumidifier is investigated. The selected refrigerants are R12, R134a, HC-Blend (R290/R600a), CX(R152a/R600a) and OS-l2a. Both theoretical and experimental investigations have been performed for the selected refrigerants. The test results of hydrocarbon refrigerants have been compared to traditional refrigerant(R12) and R134a. The results show that hydrocarbon refrigerant mixtures(HC-Blend, CX and OS-l2a) are very good alternatives in the refrigeration system for R12 and R134a.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.4 no.4
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• pp.360-369
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• 1992

A heat pump system is constructed to evaluate its performance and heat transfer characteristics with mixtures of R22/R142b as working fluids. The heat transfer in the evaporator and the overall performance are measured and analyzed in terms of the compositions and relevant variables. Possibility of capacity modulation by changing composition is observed without degradation of heat transfer coefficients and coefficient of performance. The cooling capacity is varied continuously within 200 percent based on minimum capacity at constant compressor speed. For similar cooling capacity, COP is improved by mixing two refrigerants and shows maximum value at 60％ mass fraction of R22. Average heat transfer coefficients of mixtures decrease in comparison with pure refrigerants at similar cooling capacity and mass flow rate. However, the overall heat transfer coefficients decrease moderately. A cycle simulation is performed in order to manifest the advantages of using refrigerant mixtures, considering experimentally observed heat transfer characteristics.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.7 no.2
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• pp.225-233
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• 1995

Experiments were performed to investigate the heat transfer characteristics of nonazeotropic mixture R-22+R-114 in a heat pump system. The ranges of parameter, such as heat flux, mass flow rate, and quality were $8,141{\sim}32,564W/m^2$, 24~58kg/h, and 0~1, respectively. The overall compositions of the mixtures were 50 and 100 per-cent of R-22 by weight for R-22+R-114 mixture. The results indicated that there were distinct different heat transfer phenomena between the pure substance and the mixture. In case of pure refrigerant the heat transfer rates for cooling were strongly dependent upon quality of the refrigerant. Overall evaporating heat transfer coefficients for the mixture were somewhat lower than pure R-22 values in the forced convective boiling region. For a given flow rate, the heat transfer coefficient at the circumferential tube wall(top, side, and bottom of the test tube) for R-22/R-114(50/50wt%)mixture, however, was higher than for pure R-22 at side and bottom of the tube. Furthermore, a prediction for the evaporating heat transfer coefficient of the mixtures was developed based on the method of Yoshida et.al.'s. The resulting correlation yielded a good agreement with the data for the refrigerant mixtures.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.32 no.4
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• pp.290-299
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• 2008

Evaporation heat transfer characteristics of $CO_2$/propane mixtures in horizontal smooth and micro-fin tubes have been investigated by experiment. The experiments were carried out for several test conditions of mass fluxes, heat fluxes, compositions of $CO_2$/propane refrigerant mixtures and tube geometries. Direct heating method was used for supplying heat to the refrigerant where the test tube was uniformly heated by electric current which was applied to the tube wall. Heat transfer coefficient data during evaporation process of $CO_2$/propane mixtures were measured for 5 m long smooth and micro-fin tubes with outer diameters of 5 mm, respectively. The tests were conducted at mass fluxes of 318 to 997 $kg/m^2s$, heat fluxes of 6 to 20 $kW/m^2$ and for several mixture compositions (100/0, 75/25, 50/50, 25/75, 100/0 by wt% of $CO_2$/propane). The differences of heat transfer characteristics between smooth and micro-fin tubes for various compositions of $CO_2$/propane refrigerant mixtures and the effect of mass flux, and heat flux on enhancement factor (EF) and penalty factor (PF) were presented.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.13 no.1
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• pp.1-8
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• 2001

This paper deals with refrigerant-oil mixtures in a dehumidifying cycle. Two different oils such as Alkylbenzene(AB) and Polyol-esters(POE) lubricants are used for R134a to investigate the effect of miscibility on oil returnability. It was found that R134a/AB mixture had more unstable interface between oil and refrigerant than R134a/POE mixture. However, overall flow patterns of both refrigerant-oil mixtures were almost same. The minimum height of oil measured in the compressor was as high as twice of the least permissible height of oil in the compressor required to insure its reliability. Thus, it is considered that immiscible oil, i. e., AB for R134a can be used without causing oil returnability problem.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.9
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• pp.816-823
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• 2005

This paper deals with the heat exchange performance prediction of a counter flow type double-tube condenser for natural refrigerant mixtures composed of Propane/n-Butane or Propane/i-Butane in a smooth tube and a micro-fin tube. The local characteristics of heat transfer, mass transfer and pressure drop are calculated using a prediction method developed by the authors. The total pressure drop and the overall heat transfer coefficient are also evaluated on various heat exchange conditions. The calculated results of the natural refrigerant mixtures are compared with HCFC22. In conclusion, natural refrigerant mixtures composed of Propane/n-Butane or Propane/i-Butane are appropriate candidates for alternative refrigerant from the viewpoint of heat transfer characteristics.

• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.6
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• pp.2189-2205
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• 1991

Thermodynamic properties of binary nonazeotropic refrigerant mixtures are estimated by using a modified Carnhan-Starling equation of state. In this study, pure component refrigerants such as R14, R23, R13, R13 B1, R22, R12, R134a, R152a, R142b, RC318, R114, R11, R123 and R113 are chosen and the thermodynamic properties of enthalpy and entropy are calculated in terms of relevant variables. The modified Carnahan-Starling equation of state is compared with the carnahan-Staring-De Santis equation of sate. Results show that the relative errors become slightly smaller with the equation of state proposed in this study. Correlations are obtained for the mixtures of which the vapor liquid equilibruim data are available to us in the literature. Those mixtures are R14/R23, R23/R12, R13/R12, R13/R11, R13B1/R22, R13B1/RC318, R12/RC138, R12/R114 and R12/R11. The binary interaction coefficients are found under the condition of minimizing the pressure deviations at the vapor liquid equiblibrium state and the estimation of the vapor liquid equilibrium for the refrigerant mixtures is done. Pressure-enthalpy and temperature-entropy diagrams are plotted for the refrigerant mixtures of specific composition.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.4 no.2
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• pp.123-136
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• 1992

A preliminary thermodynamic design model of two-evaporator refrigerator/freezer system is constructed. This system is based on Lorentz-Meutzner cycle using refrigerant mixtures. This model screens alternative refrigerant (R32, R125, R143a, R22, R134a, R152a, R124, R142b, R123) mixtures to select the best performance-giving refrigerant mixtures and its composition for the system. Also, it estimates the effects of cooling temperatures of intercoolers, evaporator's area ratio, cooling load ratio on the performance of the system. The COP of the system ranges from 1.4 to 1.6, which is superior to that of the single evaporator system charged with R12 by 13% to 29%. Among 15 mixtures, R22/R123, R143a/R123, R32/R142b, and R32/R124 (in the order of high COP) are most recommendable. For the case of R22/R123, R22 mass fraction more than 0.5(Load Ratio=1.0) or 0.7(Load Ratio=0.33) is recomended in order to replace R12 without reduction in volumetric capacity when keeping the compressor as the same one. COP has the highest value with X(R22)=0.7 and 0.8, respectively. For the case of R143a/R123, in the similar manner, mass fraction of R143a is more than 0.5 or 0.6 while best performance occurs at X(R143a)=0.8. Higher temperature intercooler is more important for the performance of the system than lower temperature intercooler. The area ratio of evaporators is roughly proportional to load ratio of the evaporators.

• International Journal of Air-Conditioning and Refrigeration
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• v.9 no.3
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• pp.1-9
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• 2001

In this study, condensation heat transfer coefficients (HTCs) of nonazeotropic refrigerant mixtures of HFC32/HFC 134a and HCFC123 at various compositions were measured on a horizontal smooth tube. All data were taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling of 3~8K. Test results showed that HTCs of tested mixtures were 11.0~85.0% lowed than the ideal values calculated by the mass fraction weighting of the HTCs of the pure components. Thermal resistance due to the diffusion vapor film was partly responsible for the significant reduction of HTCs with these nonazeotropic mixtures. The measured data were compared against thc predicted ones by Colburn and Drew's film model and a good agreement was observed within a deviation of 15%.