• 제목/요약/키워드: Refractory metal

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Carbon Containing Compositions

  • Mansurova, R.M.;Mansurov, Z.A.
    • Transactions on Electrical and Electronic Materials
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    • 제2권2호
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    • pp.5-15
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    • 2001
  • The experiment established optimal conditions for over-carbonization. With the use of the electron microscopy and X-ray phase analysis the regularities of carbon deposit formation in process of methane and propane pyrolysis on the zeolites, Kazakhstan natural clays, chrome and bauxite sludge containing metal oxides of iron subgroup, have been studied. In process of over-carbonization the trivalent iron was reduced to metal form. In addition, the carbon tubes of divers morphology had been impregnated with ultra-dispersed metal particles. The kinetic parameters of carbon formation in process of methane decomposition on the zeolite - CoO mixture surface were investigated by method of thermo-gravimetric analysis. The morphology and structure of formed carbon fibrils, with the metal particles fixed at their ends, have been investigated, the formation of branched carbon fibrils pattern, so called octopus, being found. Also, the walnut shells and grape kernel carbonization, their immobilization by the cells of selective absorption of heavy metal and sulfur dioxide ions have been studied. The example of metal-carbon composites used as adsorbents for wastewater purification, C$_3$- C$_4$ hydrocarbon cracking catalysts and refractory materials with improved properties have been considered.

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용탕 회전력 생성장치의 설계에 관한 연구 (A Study on the Design of a Rotational Force Generator for Molten Metal)

  • 이준호
    • 한국생산제조학회지
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    • 제21권3호
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    • pp.493-501
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    • 2012
  • A rotational force generator for molten metal is developed using a linear motor design technology. Also, the developed device is applied to reproduce aluminum scraps and easy to control the rotate, stop, and forward and reverse rotation of molten metal. In addition, the developed device improves the melting speed and reproduction rate about 250 (%) and 96-99 (%), respectively, compared to the conventional handmade methods. Because it generates almost no dusts, it can improve working environments in a factory. Also, it has no losses in energy because it directly melts scraps. The device generates small amounts of the loss in refractory materials and aluminum caused by its oxidation because the molten metal is continuously rotated in which the loss and oxidized aluminum are the problems in the conventional melting and holding furnaces. Thus, it is possible to extend the life of furnaces and to produce high quality aluminum products.

함철 폐기물의 용융환원 공정에 관한 분석연구 (An Analysis of Simulation Model for Smelting Reduction Process of Waste Containing Iron Oxide)

  • Dong-Joon Min
    • 자원리싸이클링
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    • 제5권4호
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    • pp.17-24
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    • 1996
  • The computer simulation model was established to verify the applicability of smelting reduction concept to treatment of industrial wastes which becomes issue on the enviromental and recycling view point. Computer simulation model provides as following results. The increase of post combustion ratio(PCR) and heat transfer efficiency of PC energy(HTE) is effective ways to save energy. But, in order to increase PCR, recovery efficiency of post combustion energy(HTE) have to be higher than 85% HTE considering refractory life and saving energy together. Coke is most useful fuel source because it shows lowest dependence of PCR and low hydrogen content. The quality of hot metal of current process would be expected to the similar level with that of blast furnace. The utilization of scrap and Al dross can be also possible to maximize the advantages of current process which is high temperature and chemical dilution with hot metal and slag. In case of scrap, energy consumption was slightly increases because of heating up energy of scrap. Consquently, current process concept provides the possibility of intergrating recycles of industrial wastes materials such as EAF slag, coke oven dust, life terminated acidic refractory, aluminium dross and scrap by smelting reduction process.

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대기용해 시 내화물 도가니의 종류가 가돌리늄(Gadolinium)을 함유한 듀플렉스 스테인레스 강의 미세조직에 미치는 영향 (The Effect of Refractory Crucible on Microstructure of Duplex Stainless Steel Cast with Gadolinium during Air Induction Melting)

  • 안지호;임재한;문병문
    • 한국주조공학회지
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    • 제35권5호
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    • pp.114-119
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    • 2015
  • This paper reports the effect of a refractory crucible type on the microstructure of duplex stainless steel (DSS) cast with the addition of gadolinium using air-induction melting. Grade 4A DSSs with 1 wt% of gadolinium (Gd) were fabricated in various crucibles including alumina ($Al_2O_3$), magnesia (MgO), calcia (CaO) coated with yttria ($Y_2O_3$) and graphite. The standard free energies of the formation of calcium and yttrium oxide were lower than those of gadolinium oxide and other crucible elements based oxide. The yield of Gd in DSS using $Al_2O_3$, MgO, CaO-coated $Y_2O_3$ and graphite was 5, 19, 83 and 96%, respectively. As Gd yield increased, the amount of Gd-based inclusions increased, the size of the inclusions were reduced, and the inclusions became evenly distributed.

주철금형주조용 도형재의 적용성 평가 (Evaluation on the Applicability of Refractory Coatings to Metal Mold for Cast Iron)

  • 서금희;김기영;문병문
    • 한국주조공학회지
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    • 제32권3호
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    • pp.144-149
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    • 2012
  • A series of refractory mold coatings were applied to cast iron specimens, and their resistances to wear and spalling were investigated. Tests were carried out with own made measures, and also a calculation was tried for the comparison of a part of results like spalling. Worn width by scrubbing the indenter on the coating layer increased significantly at high temperature. Temperature increasing rate across the specimen when the coating side was exposed to $1000^{\circ}C$ was in the range of $14.5{\sim}75.8^{\circ}C$/sec mm, and specimens with thicker coating layer showed lower temperature increase. Severe spalling of coated layer was observed after heating the specimen, and it was able to confirm by calculation using a commercial code.

$WN_x$ Self-Align Gate GaAs LDD MESFET의 제작 및 특성 (Fabrication and its characteristics of $WN_x$ self-align gate GaAs LDD MESFET)

  • 문재경;김해천;곽명현;강성원;임종원;이재진
    • 한국진공학회지
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    • 제8권4B호
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    • pp.536-540
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    • 1999
  • We have developed a refractory WNx self-aligned gate GaAs metal-semiconductor field-effect transistor(MESFET) using $SiO_2$ side-wall process. The MESFET hasa fully ion-implanted, planar, symmetric self-alignment structure, and it is quite suitable for integration. The uniform trans-conductance of 354nS/mm up to Vgs=+0.6V and the saturation current of 171mA/mm were obtained. As high as 43GHz of cut-off frequency hs been realized without any de-embedding of parasitic effects. The refractory WNx self-aligned gate GaAs MESFET technology is one of the most promising candidates for realizing linear power amplifier ICs and multifunction monolithic ICs for use in the digital mobile communication systems such as hand-held phone(HHP), personal communication system (PCS) and wireless local loop(WLL).

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알루미늄 용탕 보온로의 열해석 및 하부 구조물의 강도해석 (Analysis of Temperature of Molten Aluminium Holding Furnace and Stress of Substructure Frame)

  • 박상수;강충길;김병민
    • 한국정밀공학회지
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    • 제22권10호
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    • pp.129-136
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    • 2005
  • The demand on thermos furnace of Al molten metal has recently been getting higher and higher according to the increase in use of Al and Al alloys. This study considers the estimation of the thermal and mechanical stability in the thermos furnace for Al casting. It is executed through the analysis of heat transfer on the refractory material and heat stress on each steel shell. Also, the estimation of structural stability was appraised through the strength analysis of the lower structure. In result, the temperature of steel shell rose to 320.15K and its elastic deformation was about 1.5mm. The elastic deformation of the lower structure was about 0.66mm. As a result of it, the data obtain from the analysis in this study are regarded as stable value on considering that the size of the furnace is 2500mm.

NEW PROGRESS IN TiN-BASED PROTECTIVE COATINGS DEPOSITED BY ARC ION PLATING

  • Huang, R.F.;Wen, L.S.
    • 한국표면공학회지
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    • 제32권3호
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    • pp.265-275
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    • 1999
  • Titanium nitride and related overlayers produced by arc ion plating (AIP) are applied as commercial coatings in world-wide scale since the middle of 80s. Due to the achievements of low temperature deposition (LTD), they begin now to be used as wear and corrosion-resistant coatings for machine parts, besides applications on cemented carbide and high speed steel cutting tools. On the other side, TiN can be now applied successfully to brass, Al-alloy, ZnAl alloy articles as decorative coating through LTD. Various nitrides, carbonitrides, borides and other refractory compounds, such as (Ti, Al)N, TiCN, CrN, are used as the coatings for special heavy-duty working conditions instead of TiN since 90s. More and more multilayer coatings are applied now substituting single layer ones. Duplex processes are under development.

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