• Title/Summary/Keyword: Refractory Bricks

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The Influence of Sintering Atmosphere on the Reduction Behaviour of Refractory Bricks and the Basic Properties of $UO_{2}$ Pellet

  • Lee, Seung-Jae;Kim, Kyu-Tae;Chung, Bum-Jin
    • The Korean Journal of Ceramics
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    • v.4 no.4
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    • pp.279-285
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    • 1998
  • The $UO_2$ pellets are usually sintered under hydrogen gas atmosphere. Hydrogen gas may cause unexpected early failure of the refractory bricks in the sintering furnace. In this work, nitrogen was mixed with hydrogen to investigate the effect of nitrogen gas on a failure machanism of the refractory bricks and on the microstructure of the $UO_2$ pellet. The hydrogen-nitrogen mixed gas experiments show that the larger nitrogen the mixed gas contains, the less the refractory materials are reduced by hydrogen. The weight loss measurements at $1400^{\circ}C$ for fire clay and chamotte refractories containing high content of $SiO_2$ indicate that the weight loss rate for the mixed gas is about half of that for the hydrogen gas. Based on the thermochemical analyses, it is proposed that the weight loss is caused by hydrogen-induced reduction of free $SiO_2$ and/or $SiO_2$ bonded to $Al_2O_3$ in the fire clay and chamotte refractories. However, the retardation of the hydrogen-induced $SiO_2$ reduction rate under the mixed gas atmosphere may be due to the reduction of the surface reaction rate between hydrogen gas and refractory materials in proportion to volume fraction of nitrogen gas in the mixed gas. On the other hand, the mixed gas experiments show that the test data for $UO_2$ pellet still meet the related specification values, even if there exists a slight difference in the pellet microstructural parameters between the cases of the mixed gas and the hydrogen gas.

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Analyzing Refractory Bricks of Ladles using Infrared Images (열화상 영상을 이용한 래들의 내화물 열화도 분석)

  • Lee, Sang Jun;Jeon, Yong-Ju;Kim, Sang Woo
    • Journal of Institute of Control, Robotics and Systems
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    • v.21 no.4
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    • pp.291-300
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    • 2015
  • In the steel manufacturing process heat-endurance deterioration of a ladle used to cause a big accident. In this paper, an infrared imaging system and image analyzing procedure are proposed for inspecting refractory bricks of a ladle. The proposed algorithm contains following three parts: two-stage image selection procedure, reference point detection, and analysis of heat-endurance deterioration. Experiments were conducted with real data from a steel plant and detailed configuration of infrared imaging system was presented.

Development of $Al_2O_3-SiC-C$ Refractory for Hot Metal Pretreatment (용선예비처리용 $Al_2O_3-SiC-C$계 내화물 개발)

  • 김의호;이석한;이석향;서병길;박정민;이재옥
    • Journal of the Korean Ceramic Society
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    • v.23 no.5
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    • pp.86-92
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    • 1986
  • As there is a growing trend to make high quality steel improving production efficiency and utilizing slag as resources the technologies of hot metal pretreatment have been progressed to meet these demands. Although mill scale $Na_2CO_3$ and CaO used as fluxes proved to be excellent agents then can severely corrode refractories such as chamotte and high alumina for torpedo or open ladle car. Thus it was considered necessary to develop new refractories which can endure suchy conditions. Desulfurization fluxes vastly used in POSCO are $CaCO_3$ and CaO Recent trials have been made by testing phenol resin bonded $Al_2O_3-SiC-C$ bricks in torpedo ladle car for hot metal pretreatment. The results showed that the life of this brick became about 1.2 times longer than that of foreign products. And the crushing strength M.O.R corrosion resistance and oxidation resistance were tested.

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A study on Quantitative Supply of Sewage Sludge for Co-Incineration of Municipal Solid Waste and Sewage Sludge(II) - Based on Actual Incineration Plant (하수슬러지와 생활폐기물 혼합소각시 하수슬러지 정량공급에 관한 연구(II) - 실증플랜트 중심으로)

  • Cho, Jae-Beom;Kim, Woo-Gu;Jang, Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.12
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    • pp.960-966
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    • 2013
  • In this study, operation data from an actual plant in M city were analyzed to evaluate effects of water supply into sewage sludge on the co-incineration of municipal solid waste (MSW) and sewage sludge. Design capacity of the stoker incinerator is 50 m3/day. Maximum portion of sewage sludge in the total waste input was 20%. According to this research, moisture content increase up to 85% of sewage sludge could be possible by water supply on MSW input to the incinerator. Therefore, stable operation of incinerator could be achieved. As water was added into sewage sludge up to 85%, input quantity of sewage sludge to frequency (Hz) was similar to theoretical input. Also, it is concluded that stable management of incinerator without leachate combustion and damages of refractory bricks and castable could be achieved by the reduction of low heating value.

Safety Evaluation of Molten Steel Carrier by Using Instrument Indentation Technique (계장화압입시험법을 이용한 용강운반용 구조물의 안전성 평가)

  • Lee, Jeong-Ki;Kim, Yi-Gon;Yoo, Dae-Wha;Kim, Kwang-Ho;Lee, Kyeong-Ro;Kim, Chung-Youb
    • Journal of the Korean Society for Nondestructive Testing
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    • v.34 no.1
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    • pp.53-59
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    • 2014
  • Because a molten steel carrier is used in high-temperature and corrosive environments, erosion and corrosion decrease the thickness of the structure and expand the vent hole for emitting gas generated from refractory bricks. This increases the stress throughout the structure and introduces a significant stress concentration around the vent hole. In addition, the high-temperature environment degrades mechanical properties such as the yield and tensile strengths. These problems seriously affect the safety of the structure. In this study, the safety of a 10-year-old structure was evaluated by analyzing the stress distribution and measuring the mechanical properties of the structure. The mechanical properties were directly measured on the structure surface using the instrument indentation technique.

Effect of Hydration on Swelling Properties and Shear Strength Behavior of MgO-sand Mixture (수화 반응에 따른 MgO-모래 혼합물의 팽창 특성 및 전단 거동 변화)

  • Lee, Jihwan;Yoon, Boyoung;Choo, Hyunwook;Lee, Woojin;Lee, Changho
    • Journal of the Korean Geotechnical Society
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    • v.36 no.11
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    • pp.97-106
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    • 2020
  • Swelling properties and shear strength behavior of MgO-Sand mixtures with hydration procese of MgO are compared according to different MgO contents (WMgO/WTotal=0, 30, 50, 70, 100%) in this study. The specimens are prepared by mixing with crushed MgO refractory bricks and silica sand. After hydration, the particle size and the specific gravity of MgO were decreases. Through microstructure observation and X-ray diffraction analysis, it is confirmed that MgO changes from the cubic structure of Periclase to the hexagonal cubic structure of Brucite after hydration. As the MgO content increases, both swelling rate and swelling pressure of the mixtures increase. WMgO/WTotal=30% specimen shows relatively low swelling pressure and swelling rate because produced Mg(OH)2 mainly fills the pores between sand particles. However, in the case of MgO more than 50%, swelling pressure and swelling rate increase significantly because Mg(OH)2 fills the pores of sand particles at first and then either pushes out sand particles or Mg(OH)2 particles after filling the pores. As a result of the direct shear test, before hydration, the mixtures show a dilative behavior on high MgO contents and a contractive behavior on low MgO contents. However, after hydration, the behavior of all mixtures changes to contractive behavior. The threshold fraction of fine (i.e., Mg(OH)2) contents of the hydrated MgO-Sand mixtures reveals approximately 60% compared with normalized shear strength.