• Title/Summary/Keyword: Reforming system

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Steam reforming of biomass tar over Ni/Ru-x/Al2O3 catalysts (Ni/Ru-x/Al2O3 촉매를 이용한 바이오매스 타르 개질)

  • Yoon, Sang Jun;Oh, Kun Woong;Park, Seo Yoon;Kim, Yong Gu;Seo, Myung Won;Ra, Ho Won;Lee, Jae-Goo
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.355-356
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    • 2014
  • Catalytic steam reforming of tar produced from biomass gasification was conducted using several Ni-based catalysts. K and Mn were used as a promoter over $Ni/Ru/Al_2O_3$ catalyst. The pellet and monolith type catalysts were prepared and applied to lab and bench-scale biomass gasification system. The $Ni/Ru-K/Al_2O_3$ catalyst shown higher performance than $Ni/Ru-Mn/Al_2O_3$ catalyst at low temperature range.

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A simulation of steady and dynamic states of methanol reforming reaction (메탄올 개질반응의 정상 및 동특성 모사)

  • 김경미;최영순;송형근
    • 제어로봇시스템학회:학술대회논문집
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    • 1989.10a
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    • pp.395-398
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    • 1989
  • A two dimensional pseudo-homogeneous model for the methanol reforming reaction was developed and its steady and dynamic states were studied by a computer simulation. The reactor tube diameter, the catalyst density in the fixed bed, the feed flow rate, the feed temperature and the external temperature were chosen to be adjusted to determine the length of the reactor. The dynamics of the reactor showed that the system was highly nonlinear and sensitive to the feed disturbances.

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Basic Performance Test of a Three Phase AC Arc Plasma Torch System for Plasma Gas Reforming (플라즈마 가스 개질 응용을 위한 3상 아크 플라즈마 토치 시스템 특성 실험)

  • DONG-HYUN LEE;DARIAN FIGUERA-MICHAL;HAE-WON PARK;NAM-KI LEE;SANG-YUN PAEK;SHIYOUNG YANG;JUN-HO SEO
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.1
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    • pp.8-16
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    • 2023
  • In this work, we report basic performance test results of a lab-scale three phase alternative current (AC) arc plasma torch system for plasma gas reforming applications. The suggested system primarily consists of three graphite electrodes inclined at 12.5° to the central axis, a 𝞥 150 mm cylindrical gas path and a three phase-60 Hz AC power supply. At air flow rate of 50 Lpm and arc currents of 100-175 A, test results revealed that plasma resistances were decreasing from 1.08 Ω to 0.53 Ω with the increase of plasma power from 9.3 kW to 13.8 kW, causing the decrease of power factor and increase of the line voltages. However, the injected air can be heated quickly up to the temperatures of >1,200℃ when injecting AC arc plasma powers of >10 kW.

Numerical analysis of the gas flow-rate uniformity in the anode flow channel of indirect internal reforming molten carbonate fuel cell (MCFC) under different pressure drop and temperature conditions (간접 내부 개질형 용융탄산염 연료전지 anode 채널에서의 압력 강하 및 온도 조건 변경에 따른 유량 균일도에 관한 수치 해석적 연구)

  • Cho, Jun-Hyun;Ha, Tae-Hun;Kim, Han-Sang;Min, Kyoung-Doug;Park, Jong-Hoon;Chang, In-Gab;Lee, Tae-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.127-130
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    • 2009
  • The uniform gas distribution between anode channels of the indirect internal reforming type molten carbonate fuel cell (MCFC) is crucial design parameter because of the electric performance and the durability problems. A three-dimensional computational fluid dynamics (CFD) analysis is performed to investigate flow characteristics in the anode channels and manifold under different pressure drop and channel temperature conditions. The combined meshes consists of hexadral meshes in the channels and polyhedral meshes in the manifold are adopted and chemical reactions inside the MCFC system are not included because of computational difficulties associated with the size and geometric complexity of the system. Results indicate that the uniformity in flow-rate is in the range of $\pm$ 0.048 % between the anode channels when the pressure drop of anode channel is about 150 Pa. A gas flow-rate uniformity decreases as the pressure drop of anode channels decreases and as the temperature difference between indirect internal reforming (IIR) channels and anode channels increases.

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A Study on the Development and the Practical Approach for Repair Method of RC Structures Subjected to the Chemical Attack (화학적 침식을 받은 콘크리트구조물의 보수기술 개발과 실용화연구)

  • Moon, Han-Young;Shin, Dong-Gu;Kwon, Young-Jin
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.2
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    • pp.155-162
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    • 2005
  • This paper presents an invetigation into the cause of deterioration of wet surrounding RC structures subjected to checmical attacks such as sewage. The antibacterial-reforming agent is developed after determining the permeability of the RC structure. After application of the anitbacterial-reforming agent through SEM, the permeability, compressive strength properties and the micro-structure of the concrete were evaluated for durability. In addition, the antibacterial-reforming agent was combined with a protective coating for the wet surrounding RC structure and evaluated for durability. The combined effect of the antibacterial-reforming agent and the protective coating were evaluated in field tests in both sewer system and tunnel sites.

A Study on Optimization of Reformer for kW Class SOFC System (kW급 SOFC 시스템용 개질기 최적화)

  • YI, YONG;PARK, SE JIN;KIM, MIN SOO;SHIN, JANG SIK;SHIN, SEOCK JAE
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.4
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    • pp.317-323
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    • 2018
  • Solid oxide fuel cell (SOFC) operates at high temperature, therefor has the advantage of higher power generation and using exhaust heat than other fuel cells. In particular, the reforming reaction can be performed inside the SOFC stack to reduce the cooling of the stack and the burden on the reformer reactor. In this study, the reformer structure, operating characteristics, and thermal efficiency were evaluated for the optimization design of a heat exchanger type reformer of a 1 kW SOFC system.

The System Development of Externally Reforming MCFC CHP Proto Type (250 kW 발전용 용융탄산염 연료전지 기술 개발 (시스템 및 BOP 설계))

  • Lim, Hee-Chun;Ahn, Kyo-Sang;Kim, Do-Hyeong;Gang, Seung-Won;Kim, Beom-Ju
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.195-196
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    • 2007
  • This paper shortly describe the R&D results for developing of 250 kW externally reforming MCFC (Molten Carbonate Fuel Cell) CHP proto type. Conceptual Design and basic design were alredy completed and stack which was adapted new separator and components also prepared for operation and evaluation. In parallel with stack and system development, BOP such as PCS, blower, catalytic combustor and Reformer also designed and fabricated for evaluation. The system will be fabricated by the end of 2008 and operate and evaluate in 2009.

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Hydrogen Production for PEMFC Application in Plasma Reforming System (PEMFC용 플라즈마 개질 시스템의 수소 생산)

  • Yang, Yoon Cheol;Chun, Young Nam
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.1002-1007
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    • 2008
  • The purpose of this paper studied the optimal hydrogen production condition of plasma reforming system to operate the PEMFC. Plasma reforming reactor used with Ni catalyst reactor at the same time, So $H_2$ concentration increased. Also the WGS and PrOx reactor were designed to remove CO concentration under 10 ppm, because CO has effect on catalyst poisoning of PEMFC. The maximum $H_2$ production condition in plasma reforming system was S/C ratio 3.2, $CH_4$ flow rate 2.0 L/min, catalytic reactor temperature $700{\pm}5^{\circ}C$ and input power 900 W. At this time, the concentration of produced syngas was $H_2$ 70.2%, CO 7.5%, $CO_2$ 16.2%,$CH_4$ 1.8%. The hydrogen yield, hydrogen selectivity and $CH_4$ conversion rate were 56.8%, 38.1% and 92.2% respectively. The energy efficiency and specific energy requirement were 37.0%, 183.6 kJ/mol. In additional, The experiment of $CO_2/CH_4$ ratio proceeded. Also WGS reactor experiment was proceeding on optimum condition of plasma reactor and the exit concentration were $H_2$ 68%, CO 337 ppm, $CO_2$ 24.0%, $CH_4$ 2.2%, $C_2H_4$ 0.4%, $C_2H_6$ 4.1%. At this time, experiment result of PrOx reactor were $H_2$ 51.9%, CO 0%, $CO_2$ 17.3%.

Numerical Analysis of Integrated Fuel Processing System Considering Thermo-Chemical Energy Balance (열/화학적 에너지 평형을 고려한 통합 연료 개질 시스템의 수치적 연구)

  • Noh, Junghun;Jung, Hye-Mi;Jung, Un-Ho;Yoon, Wang-Lai;Um, Sukkee
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.111.1-111.1
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    • 2010
  • This paper focuses on a systematic configuration of steam reforming fuel processor, particularly designed for small and medium sized hydrogen production application. In a typical integration of the fuel processor, there exist significant temperature gradients over the entire system which has negative effect on both catalyst life-time and system performance. Also, the volumetric inefficiency should be avoided to obtain the possible compactness for the commercial purpose. In the present work, the computational analysis will be performed to gain the fundamental insight on the transport phenomena and chemical reactions in the reformer consisting of preheating, steam reforming (SR), and water gas shift (WGS) reaction beds in the flow direction. Also, the fuel processing system includes a top-fired burner providing necessary thermal energy for endothermic catalytic reactor. A fully two-dimensional numerical modeling for a integrated fuel processing system is introduced for in-depth analysis of the heat and mass transport phenomena based on surface kinetics and catalytic process. In the model, water gas shift reaction and decomposition reaction were assumed to be at equilibrium. A kinetic model was developed and then computational results were compared with the experimental data available in the literature. Finally, the case study was done by considering the key parameters, i.e. steam to carbon (S/C) ratio and temperature. The computer-aided models developed in this study can be greatly utilized for the design of advanced fast-paced compact fuel processors research.

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Comparative Performance Analysis of Small Pressurized Fuel Cell/Gas Turbine Hybrid Systems (소형 가압형 연료전지/가스터빈 하이브리드 시스템의 성능 비교해석)

  • Park, Sung-Ku;You, Byung-June;Kim, Tong-Seop;Sohn, Jeong-L.;Ahn, Kook-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.9
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    • pp.652-658
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    • 2008
  • Design performances of the fuel cell / gas turbine hybrid power generation systems based on two different fuel cells (PEMFC, SOFC) have been comparatively analyzed. In each system, the fuel cell operates at an elevated pressure corresponding to the compressed air pressure of the gas turbine. Both internally and externally reformed systems were analyzed for the SOFC hybrid system. Component design parameters of 10kW class small systems are assumed. For all hybrid systems, increasing the turbine inlet temperature increases the power portion of the gas turbine. With increasing the turbine inlet temperature, system efficiency decreases in the PEMFC system and the internally reformed SOFC system while that of the externally reformed SOFC system increases slightly. The internally reformed SOFC hybrid system is predicted to exhibit the best system efficiency.